The origin of high δ<Superscript>18</Superscript>O zircons: marbles,megacrysts, and metamorphism

The oxygen isotope ratios (δ¹⁸O) of most igneous zircons range from 5 to 8‰, with 99% of published values from 1345 rocks below 10‰. Metamorphic zircons from quartzite, metapelite, metabasite, and eclogite record δ¹⁸O values from 5 to 17‰, with 99% below 15‰. However, zircons with anomalously high δ¹⁸O, up to 23‰, have been reported in detrital suites; source rocks for these unusual zircons have not been identified. We report data for zircons from Sri Lanka and Myanmar that constrain a metamorphic petrogenesis for anomalously high δ¹⁸O in zircon. A suite of 28 large detrital zircon megacrysts from Mogok (Myanmar) analyzed by laser fluorination yields δ¹⁸O from 9.4 to 25.5‰. The U–Pb standard, CZ3, a large detrital zircon megacryst from Sri Lanka, yields δ¹⁸O = 15.4 ± 0.1‰ (2 SE) by ion microprobe. A euhedral unzoned zircon in a thin section of Sri Lanka granulite facies calcite marble yields δ¹⁸O = 19.4‰ by ion microprobe and confirms a metamorphic petrogenesis of zircon in marble. Small oxygen isotope fractionations between zircon and most minerals require a high δ¹⁸O source for the high δ¹⁸O zircons. Predicted equilibrium values of Δ¹⁸O(calcite-zircon) = 2–3‰ from 800 to 600°C show that metamorphic zircon crystallizing in a high δ¹⁸O marble will have high δ¹⁸O. The high δ¹⁸O zircons (>15‰) from both Sri Lanka and Mogok overlap the values of primary marine carbonates, and marbles are known detrital gemstone sources in both localities. The high δ¹⁸O zircons are thus metamorphic; the 15–25‰ zircon values are consistent with a marble origin in a rock-dominated system (i.e., low fluid_(external)/rock); the lower δ¹⁸O zircon values (9–15‰) are consistent with an origin in an external fluid-dominated system, such as skarn derived from marble, although many non-metasomatized marbles also fall in this range of δ¹⁸O. High δ¹⁸O (>15‰) and the absence of zoning can thus be used as a tracer to identify a marble source for high δ¹⁸O detrital zircons; this recognition can aid provenance studies in complex metamorphic terranes where age determinations alone may not allow discrimination of coeval source rocks. Metamorphic zircon megacrysts have not been reported previously and appear to be associated with high-grade marble. Identification of high δ¹⁸O zircons can also aid geochronology studies that seek to date high-grade metamorphic events due to the ability to distinguish metamorphic from detrital zircons in marble.     

Sedimentological evaluation of general circulation model simulations for the “greenhouse” Earth: Cretaceous and Jurassic case studies

Conceptual climate models, based on the workings of the present-day climate system, provided a first-order approach to ancient climate systems. They are potentially very subjective in character. Their main drawback was that they involved the relocation of continents beneath a stable atmospheric circulation modelled upon that of the present. General circulation models (GCMs) use the laws of physics and an understanding of past geography to simulate climatic responses. They are objective in character. However, they require super computers to handle vast numbers of calculations. Nonetheless it is now possible to compare results from different GCMs for a range of times and over a wide range of parameterisations. GCMs are currently producing simulated climate predictions which compare favourably with the distributions of climatically sensitive facies (e.g. coals, evaporites and palaeosols). They have been used effectively in the prediction of oceanic upwelling sites and the distribution of petroleum source-rocks and phosphorites. Parameterisation is the main weakness in GCMs (e.g. sea-surface temperature, orography, cloud behaviour). Sensitivity experiments can be run on GCMs which simulate the effects of Milankovitch forcing and thus provide insights into possible patterns of climate change both globally and locally (i.e. provide predictions that can be evaluated against the rock record). Future use of GCMs could be in the forward modelling of sequence stratigraphic evolution and in the prediction of the diagenetic characteristics of reservoir units in frontier exploration areas. The sedimentary record provides the only way that GCMs may themselves be evaluated and this is important because these same GCMs are being used currently to predict possible changes in future climate.     

Reevaluation of the lake-sediment chronology in the Dead Sea basin, Israel, based on new Th/U dates

The Dead Sea is surrounded by chemical and detrital sediments that were deposited in its larger precursor lakes, Lake Samra and Lake Lisan. The sedimentary history of these lakes was recon-structed by means of ²³⁰Th/²³⁴U ages of 30 samples, mostly of argonite laminae, from 8 columnar sections up to 110 km apart. The general validity of the ages was demonstrated by subjecting them to tests of internal isotopic consistency, agreement with stratigraphic order, and concordance with ¹⁴C ages. In the south, only the part of the Samra Formation older than 170,000 yr is exposed, while the aragonite-detritus rhythmites found in the central and northern region are generally younger than 120,000 yr. The Lisan Formation started accumulating about 63,000 yr B.P., with the clay and aragonite beds in the south-central area reflecting a rise in water level to at least −280 m. The upper part of the Lisan Formation, the aragonite-rich White Cliff Member, started accumulating about 36,000 yr B.P. The lake probably reached its highest level sometime after this, based on the ages of Lisan sediments preserved in the southernmost reaches of the basin.     

Ab initio study of MgSiO3 C2/c enstatite

We have used a newly developed ab initio constant-pressure molecular dynamics with variable cell shape technique to investigate the zero temperature behaviour of high pressure clinoenstatite (MgSiO₃-C2/c) from 0 up to 30 GPa. The optimum structure at 8 GPa, as well as structural trends under pressure, compare very well with experimental data. At this pressure, we find noticeable “fluctuations” in the chain configuration which suggests the structure is on the verge of a mechanical instability. Two distinct compressive behaviours then appear: one below and another above 8 GPa. This phenomenon may be related to the observed transition to a lower symmetry P2₁/c phase which involves a reconfiguration of the silicate chains, and suggests that the C2/c structure at low pressures found here, may be an artifact of the dynamical algorithm which preserves space group in the absence of symmetry breaking fluctuations. Comparison with calculations in other magnesium silicate phases, indicates that the size and shape of the silicate units (isolated and/or linked tetrahedra and octahedra) are generally well described by the local density approximation; however, the weaker linkages provided by the O-Mg-O bonds, are not as well described. This trend suggests that, as in the recently studied case of H₂O-ice, the structural properties of more inhomogeneous systems, like enstatite, may be improved by using gradientcorrected density functionals.     

Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.     

Petrogenesis of the Greenhills Complex,Southland, New Zealand: magmatic differentiation and cumulate formation at the roots of a Permian island-arc volcano

A Permian (~265 Ma) intrusive complex which formed as a magmatic feeder reservoir to an immature island-arc volcano is fortuitously exposed in southern New Zealand. Known as the Greenhills Complex, this intrusion was emplaced at shallow crustal levels and consists of two layered bodies which were later intruded by a variety of dykes. Cumulates, which include dunite, olivine clinopyroxenite, olivine gabbro, and hornblende gabbro-norite, are related products of parent-magma fractionation. Both primary (magmatic) and secondary platinum-group minerals occur within dunite at one locality. Using the composition of cumulus minerals, mafic dykes and melt inclusions, we have determined that the parent magmas of the complex were hydrous, low-K island-arc tholeiites of ankaramitic affinities. Progressive magmatic differentiation of this parent magma generated fractionated melt of high-alumina basalt composition which is now preserved only as dykes which cut the Complex. Field evidence and cumulus mineral profiles reveal that the magma chambers experienced turbulent magmatic conditions during cumulate-rock formation. Recharge of the chambers by primitive magma is likely to have coincided with eruption of residual melt at the surface. Similar processes are inferred to account for volcanic-rock compositions in other parts of this arc terrane and in modern island-arc systems.     

Transformations of mercury, iron, and sulfur during the reductive dissolution of iron oxyhydroxide by sulfide

Methylmercury can accumulate in fish to concentrations unhealthy for humans and other predatory mammals. Most sources of mercury (Hg) emit inorganic species to the environment. Therefore, ecological harm occurs when inorganic Hg is converted to methylmercury. Sulfate- and iron-reducing bacteria (SRB and FeRB) methylate Hg, but the effects of processes involving oxidized and reduced forms of sulfur and iron on the reactivity of Hg, including the propensity of inorganic Hg to be methylated, are poorly understood. Under abiotic conditions, using a laboratory flow reactor, bisulfide (HS⁻) was added at 40 to 250 μM h⁻¹ to 5 g L⁻¹ goethite (α-FeOOH) suspensions to which Hg(II) was adsorbed (30-100 nmol m⁻²) at pH 7.5. Dissolved Hg initially decreased from 10³ or 10⁴ nM (depending on initial conditions) to 10⁻¹ nM, during which the concentration of Hg(II) adsorbed to goethite decreased by 80% and metacinnabar (β-HgS_(s)) formed, based on identification using Hg L_III-edge extended X-ray absorption fine structure (EXAFS) spectroscopic analysis. The apparent coordination of oxygens surrounding Hg(II), measured with EXAFS spectroscopy, increased during one flow experiment, suggesting desorption of monodentate-bound Hg(II) while bidentate-bound Hg(II) persisted on the goethite surface. Further sulfidation increased dissolved Hg concentrations by one to two orders of magnitude (0.5 to 10 nM or 30 nM), suggesting that byproducts of bisulfide oxidation and Fe(III) reduction, primarily polysulfide and potentially Fe(II), enhanced the dissolution of β-HgS_(s) and/or desorption of Hg(II). Rapid accumulation of Fe(II) in the solid phase (up to 40 μmol g⁻¹) coincided with faster elevation of dissolved Hg concentrations. Fe(II) served as a proxy for elemental sulfur [S(0)], as S(0) was the dominant bisulfide oxidation product coupled to Fe(III) reduction, based on sulfur K-edge X-ray absorption near edge structure (XANES) spectroscopy. In one experiment, dissolved Hg concentrations tracked those of all sulfide species [S(-II)]. These results suggest that S(-II) reacted with S(0) to form polysulfide, which then caused the dissolution of β-HgS_(s). A secondary Fe-bearing phase resembling poorly formed green rust was observed in sulfidized solids with scanning electron microscopy, although there was no clear evidence that either surface-bound or mineralized Fe(II) strongly affected Hg speciation. Examination of interrelated processes involving S(-II) and Fe(III) revealed new modes of Hg solubilization previously not considered in Hg reactivity models.     

Assessing spatial and attribute errors in large national datasets for population distribution models: a case study of Philadelphia county schools

Geospatial technologies and digital data have developed and disseminated rapidly in conjunction with increasing computing efficiency and Internet availability. The ability to store and transmit large datasets has encouraged the development of national infrastructure datasets in geospatial formats. National datasets are used by numerous agencies for analysis and modeling purposes because these datasets are standardized and considered to be of acceptable accuracy for national scale applications. At Oak Ridge National Laboratory a population model has been developed that incorporates national schools data as one of the model inputs. This paper evaluates spatial and attribute inaccuracies present within two national school datasets, Tele Atlas North America and National Center of Education Statistics (NCES). Schools are an important component of the population model, because they are spatially dense clusters of vulnerable populations. It is therefore essential to validate the quality of school input data. Schools were also chosen since a validated schools dataset was produced in geospatial format for Philadelphia County; thereby enabling a comparison between a local dataset and the national datasets. Analyses found the national datasets are not standardized and incomplete, containing 76 to 90 percent of existing schools. The temporal accuracy of updating annual enrollment values resulted in 89 percent inaccuracy for 2003. Spatial rectification was required for 87 percent of NCES points, of which 58 percent of the errors were attributed to the geocoding process. Lastly, it was found that by combining the two national datasets, the resultant dataset provided a more useful and accurate solution.     

Significance of infiltrated clays within the Lower Permian Yellow Sands of north-east England

The Permian Yellow Sands are preserved as nine aeolian ridges in north-east England. The sands are soft and friable and locally contain large amounts of interstitial detrital clays, which are interpreted as the product of early mechanical clay infiltration. Features within the sands considered to be due to mechanical clay infiltration include grain coatings, meniscus and geopetal fabrics. The infiltrated clays mask crystal nucleation sites on grain surfaces and often amalgamate into lenses or form continuous clay-rich layers. Calcite and quartz cement growth has consequently been limited and often confined to the coarser, generally clay-free horizons. The meniscus and geopetal fabrics were formed early during accretion of the dunes and helped to bind and stabilize the sediment, which restricted reworking during the Zechstein transgression to the uppermost few decimeters.     

A review of definitions of the Himalayan Main Central Thrust

International Journal of Earth Sciences - Most workers regard the Main Central Thrust (MCT) as one of the key high strain zones in the Himalaya because it accommodated at least 90&nbsp;km of...