Galveston Bay: Temporal changes in the concentrations of trace organic contaminants in national status and trends oysters (1986–1994)

The temporal distributions for six classes of trace organic contaminants (chlordanes, DDTs, dieldrin, PAHs, PCBs, and butyltins) in oysters from six Galveston Bay sites from National Oceanic and Atmospheric Administration’s National Status and Trends (NS&T) Mussel Watch Program are compared with other NS&T sites from the Gulf of Mexico as well as all NS&T sites of the United States (East Coast, West Coast, and Gulf of Mexico). Decreases in the median for the Gulf-wide concentration of chlordanes, dieldrin, and butyltins occurred during 1986–1994. The Gulfwide median concentrations of DDTs, PAHs, and PCBs exhibited a strong cyclic distribution with time. For Galveston Bay oysters, “high” concentration is defined as the concentration greater than the median plus one standard deviation for all Gulf of Mexico sites. The percentage of sites having high concentrations during 1986–1994 for Galveston Bay oysters are 49% for dieldrin, 45% for butyltins, 40% for chlordanes, 38% for PCBs, 30% for PAHs, and 21% for DDTs. For PCBs, 43% of Galveston Bay oyster samples analyzed over the first 9 yr have concentrations high enough for potential biological effects to be observed in oysters. The percentages in other agents were chlordanes (22%), butyltins (22%), dieldrin (5%), and PAHs (4%). National Academy of Science-proposed regulatory limits for oysters were exceeded in only 2% of Galveston Bay samples for DDTs and 1% for PCBs. All other contaminants were below proposed NAS limits.     

Preliminary studies on methane fluxes in Hainan mangrove communities

INTRODUCTIONChrbondioxideandInehanearethetwomostabundantabosphericcarbonspedes.Methane'sconcenhati0nintheboposphereinonsesO.7-l.l%peryearraasmussenandKhaili,l98l,BlakeandRowand,l988,Scheeetal.,l989).Ihauseofmethne'sforpaCtontheearth'sclirnateandthechernistryoftheatInosphere,thebudgetofabosphericmethanehasmivedconsiderableattchti0n.Wetlandsareestirnataltobeoneofthelamptsoimofabosphericmethane,aocountingforab0ut4O%to5O%0ftheglobalInehanesoonannually(Cforneand0reInland,l988,WhitingandC…     

Vegetation analysis of a typical mangrove swamp—Lai Chi Wo coast of Hong Kong

A vegetation analysis reveals that the Lai Chi Wo mangrove swamp in Hong Kong has 10 mangrove species comprising 76.9% of the total number of mangrove species in Hong Kong. This swamp is a mixed community dominated byAegiceras corniculatum, Heritiera littoralis, Excoecaria agallocha, Kandelia candel, Bruguiera gymnorrhiza, with importance values of 37.88, 28.19, 14.33, 11.33 and 8.27 respectively. The community’s mangrove species diversity and evenness, as based on the Shannon-Wiener Function, were 1.44 and 62.01%, which were lower than those of the south su-tropical evergreen broad-leaf forest community but its ecological dominance (0.26) was higher. The correlation information field (CIF) method, a useful analytical method for complex forest community, was adopted in the present mangrove analysis. The species correlation information was:Aegiceras corniculatum (0.268)>Heritiera littoralis (0.250)>Kandelia candel (0.220)>Excoecaria agallocha (0.169)>Bruguiera gymnorrhiza (0.101). The correlation information of the mangrove community was 1.008. This work was financially supported by the Agriculture and Fisheries Department of The Hong Kong Government and The Hong Kong University of Science & Technology.     

The influence of river variability on the circulation,chemistry, and microbiology of the Delaware Estuary

Gravitational circulation of the Delaware Estuary is dominated by a single river, the Delaware River. The seasonal variation in river discharge is large. Consequently, the water column varies between vertically homogenous conditions found during most of the year and strongly stratified conditions found during the high flow of the spring freshet. Both the variation in river discharge and the extent of stratification affect chemical distributions and biological processes in the estuary. With a simple advection-diffusion model, we show that the apparent nonconservative behavior of nitrate in the Delaware Estuary can result from varying endmember concentration and varying river discharge. In addition, we illustrate the relationship between water column stratification, phytoplankton production, and concurrent bacterial activity. Finally, as an indirect chemical response to phytoplankton growth during high river discharge, we show strongly nonconservative patterns for ammonium, phosphate, and silicate in the estuary.     

Sediment accumulation at a fringe marsh during transgression,Oyster, Virginia

A variety of processes and sources account for the total accumulation of sediment on a fringe marsh. The rates of accretion across Brockenberry fringe marsh at the south end of the Delmarva Peninsula, Virginia, were determined by Pb-210 radiogeochronology. Rates are governed by the surface elevation with respect to midtide elevation, the rate of sea-level rise, and outwash from the mainland. Only some portions of the fringe marsh are able to keep pace with sea-level rise and thus migrate up the mainland slope during transgression.     

Dissolved inorganic and organic selenium in the Orca Basin

The vertical distributions of Se (IV), Se (VI) and dissolved organic Se have been determined in the oxic and non-sulfide-bearing anoxic zones of the Orca Basin. In the oxic waters, the concentration of Se (IV) increases with depth gradually from 0.25 nmole/kg at the surface to a maximum of 0.46 nmole/kg at 750 m and then decreases with depth to a relatively constant concentration of 0.39 nmole/ kg below 1,230 m. The concentration of Se (VI) is rather uniform in the top 250 m at about 0.24 nmole/ kg. Below 250 m it increases with depth to 0.50 nmole/kg at 1.230 m, and it stays relatively constant below this depth. The concentration of organic Se increases from 0.50 nmole/kg at the surface to 1.39 nmole/kg at 78 m. A pronounced broad maximum of organic Se exists between 78 and 250 m. The concentration decreases with depth below 250 m, dropping sharply between 250 and 380 m and more gradually at greater depths. It becomes undetectable at 1,230 m. Organic Se is the dominant species above 250 m. Se (IV) is the most abundant between 250 and 1,000 m while Se (VI) becomes the dominant species below 1,000 m. The distributions of these three species can be explained by the biological uptake of Se in the surface waters and the multi-step regeneration of Se from biogenic particles at greater depths. In suboxic waters at the oxic-anoxic interface, the concentration of Se (IV) increases while that of Se (VI) decreases reflecting a change in redox conditions in the environment. In the anoxic brine, the concentration of Se (IV) is around 0.25 nmole/kg while Se (VI) is undetectable. The concentration of organic Se increases sharply in the suboxic waters and reaches 2.6 nmole/kg in the anoxic brines probably as a result of the decomposition of organic matter and/or a diffusive flux from the underlying sediment.     

Development of shear localization in simulated quartz gouge: Effect of cumulative slip and gouge particle size

Frictional sliding experiments were conducted on two types of simulated quartz gouge (with median particle diameters 5 m and 25 m, respectively) at confining pressures ranging from 50 MPa to 190 MPa in a conventional triaxial configuration. To investigate the operative micromechanical processes, deformation texture developed in the gouge layer was studied in samples which had accumulated different amounts of frictional slip and undergone different stability modes of sliding. The spatial patterning of shear localization was characterized by a quantitative measurement of the shear band density and orientation. Shear localization in the ultrafine quartz gouge initiated very early before the onset of frictional sliding. Various modes of shear localization were evident, but within the gouge zoneR ₁-shears were predominant. The density of shear localization increased with cumulative slip, whereas the angle subtended at the rock-gouge interface decreased. Destabilization of the sliding behavior in the ultrafine quartz gouge corresponded to the extension ofR ₁-shears and formation of boundaryY-shear segments, whereas stabilization with cumulative slip was related to the coalescence ofY-shear segments to form a throughgoing boundary shear. In the coarse quartz gouge, the sliding behavior was relatively stable, probably because shear localization was inhibited by distributed comminution. Two different models were formulated to analyze the stress field within the gouge zone, with fundamentally different predictions on the orientations of the principal stresses. If the rock-gouge interface is assumed to be bonded without any displacement discontinuity, then the maximum principal stress in the gouge zone is predicted to subtend an angle greater than 45° at the interface. If no assumption on displacement or strain continuity is made and if the gouge has yielded as a Coulomb material, then the maximum principal stress in the gouge zone is predicted to subtend an angle less than 45°. If the apparent friction coefficient increases with overall slip (i.e., slip-hardening), then the Riedel shear angle progressively decreases with increasing shear strain within the gouge layer, possibly attaining a zero value which corresponds to a boundaryY-shear. Our quantitative data on shear localization orientation are in reasonable agreement with this second model, which implies the coefficient of internal friction to be about 0.75 for the ultrafine quartz gouge and 0.8 for the coarse gouge. The wide range of orientations for Riedel shear localization observed in natural faults suggests that the orientations of principal stresses vary as much as in an experimental gouge zone.     

Effects of reaction kinetics and fluid drainage on the development of pore pressure excess in a dehydrating system

Fluid is released by dehydration reactions during prograde metamorphism. If the Claperyron slope for the dehydrating reaction is positive, then there is a net decrease in the total solid volume, which implies an irreversible increase in porosity. If the dilation of the pore space is insufficient to provide storage for all the released fluid, then pore pressure excess is generated, and if it becomes sufficiently high, it may lead to brittle fracturing. The time scale for pressure generation and the pore pressure excess can be maintained over long duration hinge on the interplay of reaction kinetics and fluid drainage. Motivated by experimental and microstructural observations, a hydrological model is developed that incorporates dehydration kinetics and its pressure dependence. Analytic solutions were derived for the undrained development of pore pressure. Whether lithostatic pressure may be exceeded hinges on magnitude of the overstep in temperature and corresponding equilibrium pressure. The time scale for development of pore pressure depends on the trade-off between poroelasticity and the pressure sensitivity of reaction rate. A finite difference model was also developed to simulate the progressive development of pore pressure excess, dehydration and porosity development. The model captures the experimental observation in gypsum of a reaction front that progressively propagates from the drained end toward the undrained end of a laboratory sample. It is also in reasonable agreement with experimental data on fluid drainage and porosity production.