On the interpretation of the “inverse phase effect” for CO2 equivalent widths on Venus

Computations of the equivalent widths of absorption lines as a function of planetary phase angle are made for a homogeneous cloud with particles having the properties (shape, refractive index, and size distribution) deduced from polarimetry of Venus. The computed equivalent widths show an “inverse phase effect” comparable to that which is observed for CO₂ lines on Venus. This result verifies a recent suggestion of Regas et al. that the existence of an inverse phase effect does not by itself imply the presence of multiple layers of scattering particles in the atmosphere of Venus.     

The coronal disturbance of 1972, August 12

Using the observed data for metric and hectometric type III radio bursts, the dependence of burst characteristics on the solar longitude has been examined over a wide frequency range. It is found that there exists an east-west asymmetry for the extension of metric type III bursts into hectometric wavelength range. In particular, hectometric bursts are rarely observed for solar flares associated with metric bursts eastward solar longitude 60°E. Furthermore, for eastern longitudes, the low frequency radio observations show a large dispersion in drift time interval.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

安徽巢湖地区下三叠统综合层序

印度阶一奥伦尼克阶界线的全球层型候选剖面之一位于安徽巢湖地区;巢湖地区的下三叠统也是国际上同期地层中生物地层序列最有代表性、多重地层学手段应用齐备、研究效果最好的地层序列之一。根据巢湖地区3条代表性下三叠统剖面的岩石地层、生物地层和碳同位素地层的最新研究成果归纳出本区早三叠世综合地层序列,作为区域地层对比研究的标准．巢湖的下三叠统明确包含8个牙形石带和6个菊石带。它们具有区域甚至全球对比意义;巢湖地区早三叠世碳同位素δ^13Ccarb的演变呈现2个显著的漂移周期,这种有特色的碳同位素漂移,不仅具有地层学价值,而且可能对于三叠纪初的生物复苏和生态系演变具有指导意义．在综合地层序列基础上,将3条剖面的古地磁学研究成果链接,形成了巢湖地区完整的早三叠世磁性地层序列,包括5个主要的正向极性带和5个反向极性带,这也是目前在本区乃至华南获得的最完整的早三叠世磁极性序列之一．这些为该区域乃至全球相关地层研究树立了一个基本格架。     

Ries crater and suevite revisited—Observations and modeling Part I: Observations

We report results of an interdisciplinary project devoted to the 26 km‐diameter Ries crater and to the genesis of suevite. Recent laboratory analyses of “crater suevite” occurring within the central crater basin and of “outer suevite” on top of the continuous ejecta blanket, as well as data accumulated during the past 50 years, are interpreted within the boundary conditions imposed by a comprehensive new effort to model the crater formation and its ejecta deposits by computer code calculations (Artemieva et al. 2013). The properties of suevite are considered on all scales from megascopic to submicroscopic in the context of its geological setting. In a new approach, we reconstruct the minimum/maximum volumes of all allochthonous impact formations (108/116 km³), of suevite (14/22 km³), and the total volume of impact melt (4.9/8.0 km³) produced by the Ries impact event prior to erosion. These volumes are reasonably compatible with corresponding values obtained by numerical modeling. Taking all data on modal composition, texture, chemistry, and shock metamorphism of suevite, and the results of modeling into account, we arrive at a new empirical model implying five main consecutive phases of crater formation and ejecta emplacement. Numerical modeling indicates that only a very small fraction of suevite can be derived from the “primary ejecta plume,” which is possibly represented by the fine‐grained basal layer of outer suevite. The main mass of suevite was deposited from a “secondary plume” induced by an explosive reaction (“fuel‐coolant interaction”) of impact melt with water and volatile‐rich sedimentary rocks within a clast‐laden temporary melt pool. Both melt pool and plume appear to be heterogeneous in space and time. Outer suevite appears to be derived from an early formed, melt‐rich and clast‐poor plume region rich in strongly shocked components (melt ? clasts) and originating from an upper, more marginal zone of the melt pool. Crater suevite is obviously deposited from later formed, clast‐rich and melt‐poor plumes dominated by unshocked and weakly shocked clasts and derived from a deeper, central zone of the melt pool. Genetically, we distinguish between “primary suevite” which includes dike suevite, the lower sublayer of crater suevite, and possibly a basal layer of outer suevite, and “secondary suevite” represented by the massive upper sublayer of crater suevite and the main mass of outer suevite.     

The fall and rise of metropolitan government in Copenhagen

In this paper it is argued that the re-establishment of a metropolitan government in the Greater Copenhagen Area in 2000 (Greater Copenhagen Authority) is not to be seen as a return to the kind of regional, coordinative authority (Greater Copenhagen Council) that was abolished in the Thatcherite climate of the 1980s. Throughout the 1980s and 1990s new forms of urban governance, entrepreneurialism and a higher national priority to the capital region were introduced, which changed the conditions under which the new metropolitan government is operating. This `contextualization' of the analysis of the two generations of metropolitan government points to the fact that typologies of metropolitan government, such as the one put forward by Sharpe (1995), often lacks analytical cogency. This revised version was published online in August 2006 with corrections to the Cover Date.     

Combined Effects of Tectonic and Landslide-Generated Tsunami Runup at Seward, Alaska During the M W 9.2 1964 Earthquake

We apply a recently developed and validated numerical model of tsunami propagation and runup to study the inundation of Resurrection Bay and the town of Seward by the 1964 Alaska tsunami. Seward was hit by both tectonic and landslide-generated tsunami waves during the $M_{\rm W}$ 9.2 1964 megathrust earthquake. The earthquake triggered a series of submarine mass failures around the fjord, which resulted in landsliding of part of the coastline into the water, along with the loss of the port facilities. These submarine mass failures generated local waves in the bay within 5?min of the beginning of strong ground motion. Recent studies estimate the total volume of underwater slide material that moved in Resurrection Bay to be about 211?million m³ (Haeussler et?al. in Submarine mass movements and their consequences, pp 269?C278, 2007). The first tectonic tsunami wave arrived in Resurrection Bay about 30?min after the main shock and was about the same height as the local landslide-generated waves. Our previous numerical study, which focused only on the local landslide-generated waves in Resurrection Bay, demonstrated that they were produced by a number of different slope failures, and estimated relative contributions of different submarine slide complexes into tsunami amplitudes (Suleimani et?al. in Pure Appl Geophys 166:131?C152, 2009). This work extends the previous study by calculating tsunami inundation in Resurrection Bay caused by the combined impact of landslide-generated waves and the tectonic tsunami, and comparing the composite inundation area with observations. To simulate landslide tsunami runup in Seward, we use a viscous slide model of Jiang and LeBlond (J Phys Oceanogr 24(3):559?C572, 1994) coupled with nonlinear shallow water equations. The input data set includes a high resolution multibeam bathymetry and LIDAR topography grid of Resurrection Bay, and an initial thickness of slide material based on pre- and post-earthquake bathymetry difference maps. For simulation of tectonic tsunami runup, we derive the 1964 coseismic deformations from detailed slip distribution in the rupture area, and use them as an initial condition for propagation of the tectonic tsunami. The numerical model employs nonlinear shallow water equations formulated for depth-averaged water fluxes, and calculates a temporal position of the shoreline using a free-surface moving boundary algorithm. We find that the calculated tsunami runup in Seward caused first by local submarine landslide-generated waves, and later by a tectonic tsunami, is in good agreement with observations of the inundation zone. The analysis of inundation caused by two different tsunami sources improves our understanding of their relative contributions, and supports tsunami risk mitigation in south-central Alaska. The record of the 1964 earthquake, tsunami, and submarine landslides, combined with the high-resolution topography and bathymetry of Resurrection Bay make it an ideal location for studying tectonic tsunamis in coastal regions susceptible to underwater landslides.     

Anthropogenic contributions to atmospheric Hg, Pb and As accumulation recorded by peat cores from southern Greenland and Denmark dated using the C “bomb pulse curve”

Mercury concentrations are clearly elevated in the surface and sub-surface layers of peat cores collected from a minerotrophic (“groundwater-fed”) fen in southern Greenland (GL) and an ombrotrophic (“rainwater-fed”) bog in Denmark (DK). Using ¹⁴C to precisely date samples since ca. AD 1950 using the “atmospheric bomb pulse,” the chronology of Hg accumulation in GL is remarkably similar to the bog in DK where Hg was supplied only by atmospheric deposition: this suggests not only that Hg has been supplied to the surface layers of the minerotrophic core (GL) primarily by atmospheric inputs, but also that the peat cores have preserved a consistent record of the changing rates of atmospheric Hg accumulation. The lowest Hg fluxes in the GL core (0.3 to 0.5 μg/m²/yr) were found in peats dating from AD 550 to AD 975, compared to the maximum of 164 μg/m²/yr in AD 1953. Atmospheric Hg accumulation rates have since declined, with the value for 1995 (14 μg/m²/yr) comparable to the value for 1995 obtained by published studies of atmospheric transport modelling (12 μg/m²/yr).The greatest rates of atmospheric Hg accumulation in the DK core are also found in the sample dating from AD 1953 and are comparable in magnitude (184 μg/m²/yr) to the GL core; again, the fluxes have since gone into strong decline. The accumulation rates recorded by the peat core for AD 1994 (14 μg/m²/yr) are also comparable to the value for 1995 obtained by atmospheric transport modelling (18 μg/m²/yr). Comparing the Pb/Ti and As/Ti ratios of the DK samples with the corresponding crustal ratios (or “natural background values” for preanthropogenic peat) shows that the samples dating from 1953 also contain the maximum concentration of “excess” Pb and As. The synchroneity of the enrichments of all three elements (Hg, Pb, and As) suggests a common source, with coal-burning the most likely candidate. Independent support for this interpretation was obtained from the Pb isotope data (²⁰⁶Pb/²⁰⁷Pb = 1.1481 ± 0.0002 in the leached fraction and 1.1505 ± 0.0002 in the residual fraction) which is too radiogenic to be explained in terms of gasoline lead alone, but compares well with values for U.K. coals. In contrast, the lowest values for ²⁰⁶Pb/²⁰⁷Pb in the DK profile (1.1370 ± 0.0003 in the leached fraction and 1.1408 ± 0.0003 in the residual fraction) are found in the sample dating from AD 1979: this shows that the maximum contribution of leaded gasoline occurred approximately 25 yr after the zenith in total anthropogenic Pb deposition.