Probing the surfaces of interstellar dust grains: the adsorption of CO at bare grain surfaces

A solid-state feature was detected at around 2175 cm⁻¹ towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm⁻¹ (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm⁻¹ (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be  ∼4 × 10⁻¹⁹ cm  molecule⁻¹. The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H₂O ice, which is, at most, half of the abundance (relative to H₂O ice) of CO residing in H₂O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium.     

Disintegration of dust aggregates in interstellar shocks and the lifetime of dust grains in the ISM

We have studied to influence of grain porosity on the dust destruction mechanism in interstellar shocks. Our results show, that fluffy aggregates of dust grains can be broken up easily in shocks.     

The infrared emission bands. II. A spatial and spectral study of the Orion Bar

We have studied the spectral and spatial distribution across the Orion Bar of the 3-14 micrometers emission, including hydrogen Brackett alpha and 12.8 micrometers [Ne II] emission lines and several "dust" emission features. The data indicate that the "dust" consists of three components; (1) "classical" dust with a temperature of approximately 60 K accounting for emission longward of 20 micrometers, (2) amorphous carbon particles or polycyclic aromatic hydrocarbon (PAH) clusters (approximately 400 C atoms) which produce broad emission features in the 6-9 and 11-13 micrometers bands, and (3) free PAHs which emit in sharper bands (most strongly at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometers). The 3.3 and 11.3 micrometers features, which are due to C-H modes, are well correlated spatially, while the 7.7 micrometers band, due to C=C modes, has a different distribution than the 3.3 and 11.3 micrometers bands. We conclude that the sharp emission bands arise in the photodissociation transition region between the H II region and the molecular cloud and are not present in the H II region. The broad continuum feature extending from 11-13 micrometers is strong in both regions. Previous broad-band observations of the 10 and 20 micrometers flux distributions, which show that the 10 micrometers radiation extends farther into the neutral gas to the south than the 20 micrometers radiation, suggest that some of the 10 micrometers flux is supplied via a nonthermal mechanism, such as fluorescence.     

Theoretical studies of the infrared emission from circumstellar dust shells: the infrared characteristics of circumstellar silicates and the mass-loss rate of oxygen-rich late-type giants

We have modeled the infrared emission of spherically symmetric, circumstellar dust shells with the aim of deriving the infrared absorption properties of circumstellar silicate grains and the mass-loss rates of the central stars. As a basis for our numerical studies, a simple semianalytical formula has been derived that illustrates the essential characteristics of the infrared emission of such dust shells. A numerical radiative transfer program has been developed and applied to dust shells around oxygen-rich late-type giants. Free parameters in such models include the absorption properties and density distribution of the dust. An approximate, analytical expression is derived for the density distribution of circumstellar dust driven outward by radiation pressure from a central source. A large grid of models has been calculated to study the influence of the free parameters on the emergent spectrum. These results form the basis for a comparison with near-infrared observations. Observational studies have revealed a correlation between the near-infrared color temperature, Tc, and the strength of the 10 micrometers emission or absorption feature, A10. This relationship, which essentially measures the near-infrared optical depth in terms of the 10 micrometers optical depth, is discussed. Theoretical A10-Tc relations have been calculated and compared to the observations. The results show that this relation is a sensitive way to determine the ratio of the near-infrared to 10 micrometers absorption efficiency of circumstellar silicates. These results as well as previous studies show that the near-infrared absorption efficiency of circumstellar silicate grains is much higher than expected from terrestrial minerals. We suggest that this enhanced absorption is due to the presence of ferrous iron (Fe2+) color centers dissolved in the circumstellar silicates. By using the derived value for the ratio of the near-infrared to 10 micrometers absorption efficiency, the observed A10-Tc relation can be calibrated in terms of the total dust column density of the circumstellar shell and thus the mass-loss rate of late-type giants can easily be derived. Detailed models have been made of the infrared emission of three well-studied Miras: R Cas, IRC 10011, and OH 26.5+0.6, with the emphasis on the shape of the 10 micrometers emission or absorption feature. The results show that the intrinsic shape of the 10 micrometers resonance varies from a very broad feature in R Cas to a relatively narrower feature in OH 26.5+0.6, with IRC 10011 somewhere in between. Possible origins of this variation are discussed. The mass-loss rates from these objects are calculated to be 3 x 10(-7), 2 x 10(-5), and 2 x 10(-4) M Sun yr-1 for R Cas, IRC 10011, and OH 26.5+0.6, respectively. These results are compared to other determinations in the literature.     

The evolution of polycyclic aromatic hydrocarbons under simulated inner asteroid conditions

Large polycyclic aromatic hydrocarbons (PAHs) are an important component of the interstellar medium. PAHs have been identified in the soluble and insoluble matter of carbonaceous chondrites (CCs). Here, we study the evolution of PAHs under conditions relevant to the interiors of asteroids and compare our results to PAHs observed in CCs. We have performed long‐term and short‐term hydrothermal experiments, in which we exposed PAH‐mineral mixture analogs of meteorites to temperature conditions representative of those predicted for asteroids interiors. Our results show that small PAHs with melting points within the aqueous alteration temperature of CCs form carbonaceous spherules in the presence of water. In this work, we describe the microstructure and morphology of these spherules. We discuss the similarities and differences compared to globules isolated from CCs.     

Airborne and groundbased spectrophotometry of comet P/Halley from 5-13 micrometers

Spectrophotometry from 5-10 micrometers (delta lambda/lambda approximately 0.02) of comet Halley was obtained from the Kuiper Airborne Observatory on 1985 December 12.1 and 1986 April 8.6 and 10.5, UT. 8-13 micrometers data were obtained on 17.2 December 1985 from the Nickel Telescope at Lick Observatory. The spectra show a strong broad emission band at 10 micrometers and a weak feature at 6.8 micrometers. We do not confirm the strong 7.5 micrometers emission feature observed by the Vega 1 spacecraft. The 10 micrometers band, identified with silicate materials, has substructure indicative of crystalline material. The band can be fitted by combining spectra data from a sample of interplanetary dust particles. The primary component of the silicate emission is due to olivine. The 6.8 micrometers emission feature can be due either to carbonates or the C-H deformation mode in organic molecules. The lack of other emission bands is used to place limits on the types of organic molecules responsible for the emission observed by others at 3.4 micrometers. Color temperatures significantly higher than the equilibrium blackbody temperature indicate that small particles are abundant in the coma. Significant spatial and temporal variations in the spectrum have been observed and show trends similar to those observed by the spacecraft and from the ground. Temporal variability of the silicate emission relative to the 5-8 micrometers continuum suggests that there are at least two physically separated components of the dust.