Petroleum composition in the Cuu Long Basin (Mekong Basin) offshore southern Vietnam

The Cuu Long Basin (Mekong Basin) is a rift basin off southern Vietnam, and the most important petroleum producing basin in the country. However, information on petroleum type and characteristics has hitherto been largely unavailable to the public. This paper presents petroleum geochemical data on nine oil samples from four different producing fields in the Cuu Long Basin: the Dragon (Rong), Black Lion (Sutu-Den), Sunrise (Rang ?ong) and White Tiger (Bach Ho) Fields. The oils are highly paraffinic with bimodal normal alkane distributions and show moderate pristane to phytane ratios and a conspicuous hyperbolic decrease in abundance with increasing carbon number of hopane homologues from C₃₀ to C₃₅. The TPP-index of Holba et al. (Holba, A.G., Dzou, L.I., Wood, G.D., Ellis, L., Adam, P., Schaeffer, P., Albrecht, P., Greene, T., Hughes, W.B., 2003. Application of tetracyclic polyprenoids as indicators of input from fresh–brackish water environments. Organic Geochemistry 34, 441–469) is equal to 1 in all samples which in combination with tricyclic triperpane T26/T25 ratios >1 and the n-alkane and hopane distributions mentioned above provide a strong indication of an origin from lacustrine source rocks. This is supported by the absence of marine C₃₀ desmethyl steranes (i.e. 24-n-propylcholestanes) and marine diatom-derived norcholestanes. Based on the overall biological marker distributions, the lakes probably belonged to the overfilled or balanced-fill types defined by Bohacs et al. (Bohacs, K.M., Carroll, A.R., Neal, J.E., Mankiewicz, P.J., 2000. Lake-basin type, source potential, and hydrocarbon character. An integrated sequence-stratigraphic–geochemical framework. AAPG Studies in Geology 46, 3–34). The oils were generated from source rocks at early- to mid-oil-window maturity, presumably Oligocene lacustrine shales that are present in the syn-rift succession. Oils from individual fields may, however, be distinguished by a combination of biological marker parameters, such as the oleanane index, the gammacerane index, the relative abundance of tricyclic terpanes, the proportions of diasteranes and 28-norspergulane, complemented by other parameters. The oils of the Cuu Long Basin show an overall similarity to the B-10 oil from the Song Hong Basin off northern Vietnam, but are markedly different from the seepage oils known from Dam Thi Nai on the coast of central Vietnam.     

Stochastic evaluation of fluvial to marginal marine sealing facies

Hydrocarbon top seal analyses are particularly difficult in fluvial and marginal marine settings. Although these settings often contain beds comprised of a low-permeability, clay-rich lithology associated with high quality seals, their presence does not guarantee an effective seal because individual beds within the stratal unit may be laterally discontinuous. Lateral facies changes, truncation of fine-grained beds, or the presence of crevasse splays may provide cross-stratal migration pathways, reducing the effective sealing capacity to a magnitude less than the closure height.     

The thermal structure of the Dvurechenskii mud volcano and its implications for gas hydrate stability and eruption dynamics

The sediment temperature distribution at mud volcanoes provides insights into their activity and into the occurrence of gas hydrates. If ambient pressure and temperature conditions are close to the limits of the gas hydrate stability field, the sediment temperature distribution not only limits the occurrence of gas hydrates, but is itself influenced by heat production and consumption related to the formation and dissociation of gas hydrates. Located in the Sorokin Trough in the northern Black Sea, the Dvurechenskii mud volcano (DMV) was in the focus of detailed investigations during the M72/2 and M73/3a cruises of the German R/V Meteor and the ROV Quest 4000 m in February and March 2007. A large number of in-situ sediment temperature measurements were conducted from the ROV and with a sensor-equipped gravity corer. Gas hydrates were sampled in pressurized cores using a dynamic autoclave piston corer (DAPC). The thermal structure of the DMV suggests a regime of fluid flow at rates decreasing from the summit towards the edges of the mud volcano, accompanied by intermittent mud expulsion at the summit. Modeled gas hydrate dissociation temperatures reveal that the gas hydrates at the DMV are very close to the stability limits. Changes in heat flow due to variable seepage rates probably do not result in changes in sediment temperature but are compensated by gas hydrate dissociation and formation.     

Protecting small cetaceans from coastal development: Impact assessment and mitigation experience in Hong Kong

Since the early 1990s, there has been an active program in Hong Kong to manage and protect local populations of small cetaceans from the effects of massive development in the area. This paper reviews the progress that has been made. Only two species regularly occur there: the Indo-Pacific humpback dolphin and the finless porpoise. Because most development has occurred in the western waters of Hong Kong, where generally only the humpback dolphin occurs, most of the work has been conducted on that species. Development of large infrastructure projects (such as airports, bridges, expressways, power plants, fuel facilities, and container ports) in Hong Kong often results in land reclamation, dredging and dumping of spoils, pipe and cable laying, percussive and bored piling work, underwater blasting, large increases in vessel traffic, and other impacts. Several mitigation measures have been used with varying levels of success, including bubble curtains/jackets, exclusion zones, ramping up of piling hammers, acoustic decoupling of noisy equipment, vessel speed limits, no-dumping policies, and silt curtains. Baseline, construction-phase, and operational-phase cetacean monitoring is often conducted to evaluate the success of conservation measures put into place. The Environmental Impact Assessment process in Hong Kong has involved cetaceans to a degree perhaps higher than anywhere else in the world, and much can be learned from studying the successes and failures of this situation.     

Fundamental study for morphodynamic modelling: Sand mounds in oscillatory flows

Experiments on sand mounds in oscillatory flow, undertaken in controlled, large-scale laboratory conditions, have produced well-defined data sets for model comparison. Three bathymetries with different levels of submergence, including a surface-piercing case, were tested. The maximum slope was about 1:5.5. Sediment transport is due to bed load with ripple formation. The principal time-dependent bulk parameters are the vertical distance of the centre of gravity above the base and the volume of the mound. A semi-implicit finite-volume depth-averaged hydrodynamic model is used to drive morphodynamics, using van Rijn's sediment flux model generalized to take account of bed slope, and some justification is given for depth-averaged modeling in these conditions. Starting the model runs with the conditions at the end of the first cycle avoided initial atypical physical behaviour. In general good predictions were obtained with an angle of repose reduced from the standard value of about 30° for stationary beds to 15°. For these situations, morphodynamics was largely unaffected by a hydrodynamic roughness height in the range 2.5D₅₀ to 51D₅₀, with larger values accounting for ripple roughness. The reduced angle of repose may be physically expected with mobile beds but this specific value is only expected to be suited to this form of bed motion. In one case an exaggerated ripple formed near the top of the mound reducing agreement with experiment. For the submerged case with normal ripple structure excellent predictions were obtained. For the initially surface-piercing mound, the time of submergence was better predicted with a 30° angle of repose, presumably due to the prominent influence of the near stationary bed near the wet/dry interface, although long term predictions were better predicted with 15°. The occurrence of vortex shedding in the first cycle modeled was in agreement with experimental observation.     

Abundance,distribution, and feeding patterns of juvenile coho salmon (Oncorhynchus kisutch) in the Juan de Fuca Eddy

The Juan de Fuca Eddy is a seasonal, counter-clockwise gyre off the mouth of the Strait of Juan de Fuca between Washington, USA and British Columbia, Canada that may provide favorable feeding habitat for juvenile coho salmon (Oncorhynchus kisutch) during their early marine existence. In late September 2002, physical and biological sampling was conducted along two transects of the eddy region. Surface rope trawling was conducted to capture juvenile salmon and other nekton, along with bongo and neuston net tows to examine potential mesozooplanktonic salmon prey. Presence of the Juan de Fuca Eddy was confirmed with vertical water profiles. In addition, nutrient and chlorophyll a concentrations collected from 3-m depth were within the range observed in previous studies within the eddy region. In the mesozooplankton community, euphausiids, chaetognaths, and decapod megalopae were common. In the diet of juvenile coho salmon, euphausiids and decapod megalopae were dominant by percent number, and larval and juvenile fish were dominant by percent weight. Feeding intensity (percent body weight) based on stomach contents was variable, but not significantly different among stations. To compare the Juan de Fuca Eddy region with an upwelling area, we sampled along a transect off La Push (LP), Washington, USA which is south of the eddy. The eddy region was found to be less productive than the LP transect. Nutrients were lower, chlorophyll a concentrations were higher, and zooplankton abundance was generally higher along the LP transect than in the eddy region. In addition, more juvenile coho salmon were captured from the LP transect than the eddy region. Prey items in stomachs of salmon from the LP transect were heterogeneous compared to those from the eddy region. Feeding intensity along the LP transect was slightly lower and more variable than in the eddy region, and differences in feeding intensity among LP stations were significant. In addition, feeding intensities among stations nested within regions were significantly different.     

Evaluation of policy options for the live reef food fish trade in the province of Palawan,Western Philippines

The live reef food fish (LRFF) trade has an estimated annual retail value of US$1 billion in the Asia-Pacific region and at least US$30 million in the Philippines. Palawan Province is the trade's center accounting for as much as 55% of the commodity's total export. Concern about the LRFF trade has caused the Palawan Provincial government to take action to regulate the trade. Four key policy options to address the short-term policy objective of developing a sustainable LRFF industry through the reduction of threats associated with destructive fishing and overfishing were proposed. These four policy options and associated analyses were presented to stakeholders at three separate policy consultations. The stakeholders reached a consensus that a regulated LRFF trade was the most sensible option. As a result, the Provincial Government of Palawan took action to enact “The Palawan Live Reef Fish Ordinance of 2006”, which provides for the sustainable and integrated regulation of the LRFF industry. This provincial ordinance will assist in crafting a national policy for the LRFF trade and may also be useful in revising the 1998 Philippine Fisheries Code. The key challenge is how to translate the ordinance provisions into effective on-the-ground actions.     

Momentum and gravity effects during the constant velocity water entry of wedge-shaped sections

Computational fluid dynamics analysis was used to investigate the added mass momentum, flow momentum and gravity effects during the constant velocity water entry of wedge-shaped sections with deadrise angles from 5° to 45°. It is shown that the added mass continues to increase for a time after chine immersion and that added mass can be estimated in terms of a constant added mass coefficient and an effective wetted width. A momentum theory is presented in which the water entry force is explained as the sum of the rate of change of added mass momentum, which becomes zero at immersion to chine depth ratios greater than about three, and the rate of change of flow momentum, which continues at deep immersions. The effect of gravity on the water entry force is given as the hydrostatic force together with the force necessary to create the potential energy in the water pile up. Hydrodynamic forces are not significantly changed by the effect of gravity on the flow fields.     

Assessment of the influence of air invasions from the upper troposphere on the CO total column amount in the St. Petersburg region

The influence of air invasions from the upper troposphere on the CO total column amount is studied on the basis of spectroscopic measurements of the CO total column amount, backward trajectories of air-mass motions (the HYSPLIT model), and meteorological data. It is shown that the observed invasions of substratospheric and upper-troposphere air masses determine the minimum CO total column amount in late January-late March. The invasion of air masses from the upper troposphere can result in a decrease in the CO total column amount to 30% (of its mean values). Using January 31, 2000, as an example, we show the influence of the invasion of Arctic air masses from the upper troposphere on the CO total column amount in the St. Petersburg region: the results of measurements of the CO total column amount in the St. Petersburg region and at the Kiruna polar station (NDACC) are in agreement to within 1% if the vertical transport of air masses is taken into account. Thus, for a correct combined analysis of measurement data on the CO total column amount for different observation stations, it is necessary to use data on air-mass trajectories.     

Latitudinal dependence of variations in stratospheric NO<Subscript>2</Subscript> content

Diurnal and annual variations in the NO₂ total content (TC), the effect of its decrease owing to the products of the eruption of Mt. Pinatubo, its variations during an 11-year cycle of solar activity, and its linear trends are analyzed on the basis of data obtained from the ground-based spectrometric measurements of the NO₂ TC in stratospheric vertical columns over the stations of the Network for the Detection of Atmospheric Composition Change. Latitudinal dependence of the indicated variations and trends is revealed. The annual estimates of the linear trends of the NO₂ TC are found to be mostly positive for the middle and low latitudes of the Southern Hemisphere and negative for the middle and low latitudes of the Northern Hemisphere. The maximum values of the positive and negative trends amount to ～10% per ten years. In the high and polar latitudes of both hemispheres, the annual trend estimates are statistically insignificant. Seasonal estimates of the trends may differ from their annual estimates. The trends and solar-activity effect in the NO₂ TC, which were estimated by using the two-dimensional model SOCRATES, as well as the analytical estimates of a zonal mean trend of the NO₂ TC, on the whole, significantly differ from the estimates obtained from the measurements.