Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Simulation of Hydrophysical Processes in Coastal Regions of the Sea

In the present work, we generalize the results of our investigations in the field of simulation of hydrophysical and ecological processes in coastal regions of various seas and some closed basins. The developed and applied mathematical models and the results of numerical experiments are briefly analyzed.     

A Functional Analysis of the Benthic Macrofauna of the São Sebastião Channel (Southeastern Brazil)

Abstract.  The major problem in coastal areas of developing countries is disturbance caused by anthropogenic influence. This disturbance can be quantified by analysing the distribution and composition of marine communities using uni- and multivariate techniques and the biotic index. A study of benthic macrofauna was carried out along the São Sebastião Channel, northern coast of São Paulo State, Brazil, in an area with a submarine outfall, a petroleum terminal and a commercial harbour. Sampling was undertaken seasonally, by means of a van Veen grab (0.1 m²) at 15 oceanographic stations, from November 1993 to August 1994. A total of 392 species were identified (129 Polychaeta, 127 Mollusca, 98 Crustacea, 28 Echinodermata and 10 other phyla). The sedimentary pattern recorded for the São Sebastião Channel is very heterogeneous, influenced mainly by strong wind-driven currents, and differs from nearby shelf areas. The study area could be divided into three regions based on sediment texture and fauna: one region dominated by medium and coarse sand with low values of organic carbon; a second area where pelitic fractions were dominant with high values of organic carbon and nitrogen; and a third region characterised by fine and very fine sand, presenting intermediate organic carbon values. No temporal significant variation in abundance and species composition was found, except in autumn. The use of the 'marine Biotic Coefficient' showed the same ecological trend as the faunal abundance and demonstrated that the central continental region of the channel is affected by human activities.     

Experimental investigation of forces and geometry of a net cage in uniform flow

A scale model of a flexible circular net with different weights attached to the bottom was tested in a flume tank. Global forces and net deformation were measured for different steady current velocities. Three different sizes of bottom weights were used in the tests. The results from these tests are presented and discussed with the emphasis on the dependency between the forces and the geometry. Comparison is also made to empirical based formulas for calculation of drag and lift forces on net structures. Findings show that i) the forces on, and deformation of a flexible net structure are mutually highly dependent on each other; ii) estimates of global forces on a flexible net structure calculated using simple drag formulas derived from stiff net panel experiments give large errors when compared to experimental measurements; iii) numerical models taking into account the dependency between force and deformation should be used to obtain accurate estimates of forces on flexible net structures; and iv) the forces on a flexible net structure are dependent on Reynolds number, and their dependency are similar to that of a regular cylinder.     

The dynamic behaviour of a river-dominated tidal inlet, River Murray, Australia

Australia's largest river, the River Murray, discharges to the southern ocean through a coastal lagoon and river-dominated tidal inlet. Increased water extractions upstream for irrigation have led to significantly reduced flows at the mouth and, as a result, the area is undergoing rapid change, particularly with regard to the rate at which sediment is being transported into the lagoon. Based on detailed and accurate bathymetric surveys it has been possible to estimate that the rate of lagoon in-filling is of the order of 100,000 m³ per year for the period June 2000 to May 2003, although the actual rate shows significant year to year variability. Dredging of the lagoon commenced in 2000 in an attempt to reverse the trend.In an effort to understand the behaviour of the inlet a one-dimensional numerical model of the inlet has been developed. The model extends the original of van de Kreeke by including a dynamic inlet throat area based on predicted river flows and a sediment transport module to predict the resulting net sediment transport. Comparisons with water level data collected on both the ocean and lagoon sides of the mouth have shown that the model is able to predict the attenuation and lag of the tidal signal reasonably well. The sediment transport model was based on predicted sediment concentrations in the surf zone and was found to predict the rate of sediment in-filling to an acceptable level of accuracy. It is envisaged that the model will be a useful management tool, especially since it is possible to manipulate river discharges to the mouth.     

Path following control system for a tanker ship model

A two-dimensional path following control system for autonomous marine surface vessels is presented. The guidance system is obtained through a way-point guidance scheme based on line-of-sight projection algorithm and the speed controller is achieved through state feedback linearization. A new approach concerning the calculation of a dynamic line-of-sight vector norm is presented which main idea is to improve the speed of the convergence of the vehicle to the desired path. The results obtained are compared with the traditional line-of-sight scheme. It is intended that the complete system will be tested and implemented in a model of the “Esso Osaka” tanker. The results of simulations are presented here showing the effectiveness of the system aiming in to be robust enough to perform tests either in tanks or lakes.     

Time domain modelling of the transient asymmetric flooding of Ro-Ro ships

This work aims at contributing to improve knowledge on transient asymmetric flooding through theoretical and experimental research. First, a time domain theoretical model of ship motions and flooding is described. Results from experimental work are presented evidencing that transient asymmetric flooding may cause the capsizing of a Ro-Ro shaped barge. The theoretical model is used to predict the capsize of the Ro-Ro shaped barge. Reasonable agreement between experimental and theoretical results was found. Finally, a review of the European Gateway accident is given and the theoretical model is applied to the study of this type of accident. The conclusion is that this theoretical model, together with an accurate modelling of the flooding of machinery compartments, reproduces successfully the capsizing of the European Gateway due to transient asymmetric flooding. Therefore, the internal arrangement of Ro-Ro ships should be carefully studied at the design stage in order to avoid this phenomenon.