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31.
A numerical scheme is developed in order to simulate fluid flow in three dimensional (3‐D) microstructures. The governing equations for steady incompressible flow are solved using the semi‐implicit method for pressure‐linked equations (SIMPLE) finite difference scheme within a non‐staggered grid system that represents the 3‐D microstructure. This system allows solving the governing equations using only one computational cell. The numerical scheme is verified through simulating fluid flow in idealized 3‐D microstructures with known closed form solutions for permeability. The numerical factors affecting the solution in terms of convergence and accuracy are also discussed. These factors include the resolution of the analysed microstructure and the truncation criterion. Fluid flow in 2‐D X‐ray computed tomography (CT) images of real porous media microstructure is also simulated using this numerical model. These real microstructures include field cores of asphalt mixes, laboratory linear kneading compactor (LKC) specimens, and laboratory Superpave gyratory compactor (SGC) specimens. The numerical results for the permeability of the real microstructures are compared with the results from closed form solutions. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
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Methyl-galactosides were oxidized at room temperature by galactose oxidase in a one-step reaction and afforded methyl-galactoaldehyde in excellent yield and high purity. The resulting galactoaldehyde as a useful intermediate can be directly used in glycopeptide synthesis.  相似文献   
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Transverse secondary circulations involving surface convergence, observed in a well-mixed estuary in North Wales, are made visible by the collection of surface material along an axial line which extends continuously for many kilometres through the estuary. The circulation and axial convergence, however, are seen only during the flood phase of the tide and no similar behaviour has been observed during the ebb phase.Convergent circulations in the estuary are associated with small but steady transverse density gradients in the cross-section, produced by non-uniform advection of the longitudinal gradient through the channel. A diagnostic model, using measured mean distributions of cross-sectional density, indicates surface transverse velocities (~0.1 ms?1) similar to those observed in the estuary. The model further predicts appreciable transverse divergent currents at a fractional depth of 0.75: a prediction which has been tested in the estuary using a vertical array of accurately resolving current direction indicators.  相似文献   
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A formula for the thickness of a shear band formed in saturated soils under a simple shear or a combined stress state has been proposed. It is shown that the shear band thickness is dependent on the pore pressure properties of the material and the dilatancy rate, but is independent of the details of the combined stress state. This is in accordance with some separate experimental observations. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
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Summary. A method of synthetic seismogram computation for teleseismic SV -waves is developed in order to treat quantitatively SV -waves in problems of body wave source inversion and source—receiver structure studies. The method employs WKBJ theory for a generalized ray in a vertically inhomogeneous half-space and the propagator matrix technique for waves in near-surface homogeneous layers. Wavenumber integration is done along the real axis of the wavenumber plane and anelasticity is included by using complex velocity in all regions of the earth model. The near-surface source structure is taken into account in the computation for the case of the shallow source by allowing a point source to be located in the homogeneous layers. Source and receiver area structures are also allowed to differ. A general moment tensor point source is considered.  相似文献   
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Surface morphology and related issues for nuclei of three comets: Halley, Borrelly and Wild 2, are considered in the paper. Joint consideration of publications and results of our analysis of the comets’ images led to conclusions, partly new, partly repeating conclusions published by other researchers. It was found that typical for all three nuclei is the presence of rather flat areas: floors of craters and other depressions, mesas and terraces. This implies that flattening surfaces or planation is a process typical for the comet nuclei. Planation seems to work through the sublimation-driven slope collapse and retreat. This requires effective sublimation so this process should work only when a comet is close to the Sun and if on the nucleus there are starting slopes, steep and high enough to support the “long-distance” avalanching of the collapsing material. If the surface had no starting slopes, then instead of planation, the formation of pitted-and-hilly surfaces should occur. An example of this could be the mottled terrain of the Borelly nucleus. Both ways of the sublimational evolution on the nucleus surface should lead to accumulation of cometary regolith. The thickness of the degassed regolith is not known, but it is obvious that in surface depressions, including the flat-floor ones, it should be larger compared with nondepression areas. This may have implications for the in situ study of comets by the Deep Impact and Rosetta missions.Our morphological analysis puts constraints on the applicability of the popular “rubble-pile comet nucleus” hypothesis (Weissman, 1986. Are cometery nuclei primordial rubble piles? Nature 320, 242-244.). We believe that the rubble pile hypothesis can be applicable to the blocky Halley nucleus. The Borelly and Wild 2 nuclei also could be rubble piles. But in these cases the “rubbles” have to be either smaller than 30-50 m (a requirement to keep lineament geometry close to ideal), or larger than 1-2 km (a requirement to form the rather extended smooth, flat surfaces of mesa tops and crater floors). Another option is that the Borelly and Wild 2 nuclei are not rubble piles.In relation to surface morphology we suggest that three end-member types of the comet nuclei may exist: (1) impact cratered “pristine” bodies, (2) non-cratered fragments of catastrophic disruption, and (3) highly Sun-ablated bodies. In this threefold classification, the Wild 2 nucleus is partially ablated primarily cratered body. Borrelly is significantly ablated and could be either primarily cratered or not-cratered fragment. Halley is certainly partially ablated but with the available images it is difficult to say if remnants of impact craters do exist on it.Recently published observations and early results of analysis of the Tempel 1 nucleus images taken by Deep Impact mission are in agreement with our conclusions on the processes responsible for the Halley, Borrelly and Wild 2 nuclei morphologies. In particular, we have now more grounds to suggest that decrease in crater numbers and increase of the role of smooth flat surfaces in the sequence Wild 2?Tempel 1?Borelli reflects a progress in the sublimational degradation of the nucleus surface during comet passages close to the Sun.  相似文献   
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Reconnaissance seismic shot in 1971/72 showed a number of well defined seismic anomalies within the East Sengkang Basin which were interpreted as buried reefs. Subsequent fieldwork revealed that Upper Miocene reefs outcropped along the southern margin of the basin. A drilling programme in 1975 and 1976 proved the presence of shallow, gas-bearing, Upper Miocene reefs in the northern part of the basin. Seismic acquisition and drilling during 1981 confirmed the economic significance of these discoveries, with four separate accumulations containing about 750 × 109 cubic feet of dry gas in place at an average depth of 700 m. Kampung Baru is the largest field and contains over half the total, both reservoir quality and gas deliverability are excellent. Deposition in the East Sengkang Basin probably started during the Early Miocene. A sequence of Lower Miocene mudstones and limestones unconformably overlies acoustic basement which consists of Eocene volcanics. During the tectonically active Middle Miocene, deposition was interrupted by two periods of deformation and erosion. Carbonate deposition became established in the Late Miocene with widespread development of platform limestones throughout the East Sengkang Basin. Thick pinnacle reef complexes developed in the areas where reef growth could keep pace with the relative rise in sea level. Most reef growth ceased at the end of the Miocene and subsequent renewed clastic sedimentation covered the irregular limestone surface. Late Pliocene regression culminated in the Holocene with erosion. The Walanae fault zone, part of a major regional sinistral strike-slip system, separates the East and West Sengkang Basins. Both normal and reverse faulting are inferred from seismic data and post Late Pliocene reverse faulting is seen in outcrop.  相似文献   
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