The influence of momentum advection on the Baltic Sea dynamics

Contribution of momentum advection to the formation of the low frequency fields of the Baltic Sea levels and currents is estimated using numerical experiments with a hydrodynamic model and statistical analysis of the experimental results. It is found that momentum advection has a significant influence on the formation of the mean level and its seasonal and synoptic variability in Neva Bay of the Gulf of Finland. The results show that nonlinear effects associated with advective accelerations can essentially contribute to the Neva River flood formation.     

SL-AV atmospheric model version using σ-<Emphasis Type="Italic">p</Emphasis> hybrid vertical coordinates

The SL-AV atmospheric model version using hybrid vertical coordinates combies the advantages of sigma and isobaric coordinates. The formulation and discretization of model equations maintain the equivalency of the new model version to the basic sigma version in the special case, when hybrid coordinates coincide with sigma coordinates. The SL-AV model version with hybrid vertical coordinate is verified with medium-range weather forecasts. The decrease in the errors of predicted geopotential height and wind as compared to the sigma model version is demonstrated. The use of hybrid coordinates also leads to a certain increase in forecast skill scores for some meteorological parameters characterizing aviation significant weather.     

Projected impact of deep ocean carbon dioxide discharge on atmospheric CO2 concentrations

An evaluation of oceanic containment strategies for anthropogenic carbon dioxide is presented. Energy conservation is also addressed through an input hydrocarbon-fuel consumption function. The effectiveness of the proposed countermeasures is determined from atmospheric CO₂ concentration predictions. A previous box model with a diffusive deep ocean is adapted and applied to the concept of fractional CO₂ injection in 500 m deep waters. Next, the contributions of oceanic calcium carbonate sediment dissolution, and of deep seawater renewal, are included. Numerical results show that for CO₂ direct removal measures to be effective, large fractions of anthropogenic carbon dioxide have to be processed. This point favors fuel pre-processing concepts. The global model also indicates that energy conservation, i.e. a hydrocarbon-fuel consumption slowdown, remains the most effective way to mitigate the greenhouse effect, because it offers mankind a substantial time delay to implement new energy production alternatives.     

Computation of maximum water temperature in the Beloyarskoe Reservoir

Presented is a three-dimensional model for computing hydrothermodynamic processes in the Beloyarskoe Reservoir used as a basin-cooler of the Beloyarskaya nuclear power plant. In view of the designing of new power units for the station and due to the absence of reliable reservoir-analogs in the region under consideration, the computation is carried out of the distribution of maximum water temperature in the reservoir for natural conditions. The results of these computations are subsequently used as background parameters for designing a system of technical water supply of NPP and for the ecological feasibility report.     

Analysis of objective functions used in urban runoff models

The objective functions used in parameter estimation in urban runoff models are compared by using a method proposed by Diskin and Simon¹ and the urban runoff model ILLUDAS. Two sets of objective functions, the first one used by Diskin and Simon in their study and a second one which includes other objective functions are used. Rainfall-runoff data from urban watersheds in the US are used in the study. The results indicate that the least squares criterion is the best among those studied.     

Petrologic evolution of Krakatau (Indonesia): Implications for a future activity

Krakatau Volcano is located along a N35E volcanic lineament running through the Sunda straits (Indonesia). Its last activity has been characterized by successive phases, each beginning with the construction of a cone, and ending with its destruction and the formation of a caldera. The two last (pre- and post-1883) cycles are well known, but the more ancient ones are not so clearly defined.Lavas of Krakatau belong to an andesitic series, in which fractional crystallization plays the most important role. The petrologic evolution is characterized by a cyclicity in good agreement with the structural evolution: the succession is regular: basalts, basic andesites, acid andesites, dacites. A gap between acid and basic andesites occurs in each cycle. The destructive stages correspond to the occurrence of dacitic terms.The Anak cycle was characterized from 1927 to 1979 by basalts and basic andesites; the 1981 eruption involved a more differentiated magma (close to dacitic). Detailed study of the petrologic evolution since 1883 emphasizes the predominant role of fractional crystallization. This process occurred during a very short period, between 1979 and 1981. Separation of labradorite, augite, olivine and magnetite from parental basic andesite may generate the dacitic descendant, in a shallow reservoir (P_H2O estimated about 0.5 kbar). Implications for a future activity are considered.     

Investigation of submicron volcanic aerosol-particles by photoelectron emission

Volcanic aerosol emissions have been studied for the first time by in situ photoelectric charging. Explorative studies on Mt Etna reveal large concentrations of particles below 1000 nm with the spectrum peaking in the size range of 100–1000 nm diameter. Although a large fraction of the particles is already charged upon emission, the net electrical charge carried by the aerosol turned out to be close to zero.Particles with high photoelectric yield vary greatly in their relative abundance and seem to occur mainly at active points of the volcano.     

Iron oxidation state in lower mantle mineral assemblages: II. Inclusions in diamonds from Kankan, Guinea

Inclusions of ferropericlase and former (Mg,Fe)(Si,Al)O₃ perovskite in diamonds from Kankan, Guinea believed to originate in the lower mantle were studied using Mössbauer spectroscopy to determine Fe³⁺/ΣFe. Fe³⁺ concentration in the (Mg,Fe)(Si,Al)O₃ inclusion is consistent with empirical relations relating Fe³⁺/ΣFe to Al concentration, supporting the inference that it crystallised in the perovskite structure at lower mantle conditions. In ferropericlase there is a nearly linear variation of trivalent cation abundance with monovalent cation abundance, suggesting a substitution of the form Na_0.5M_0.5³⁺O (M=Fe³⁺, Cr³⁺, Al³⁺). Excess positive charge is likely balanced by cation vacancies, where their abundance is observed to increase with increasing iron concentration, consistent with high-pressure experiments. The abundance of cation vacancies is related to oxygen fugacity, where ferropericlase inclusions from Kankan and São Luiz (Brazil) are inferred to have formed at conditions more oxidising than Fe-(Mg,Fe)O equilibrium, but more reducing than Re-ReO₂ equilibrium. Fe²⁺/Mg partition coefficients between (Mg,Fe)(Si,Al)O₃ and ferropericlase were calculated for inclusions co-existing in the same diamond using Mössbauer data and empirical relations based on high-pressure experimental work. Most values are consistent with high-pressure experiments, suggesting that these inclusions equilibrated at lower mantle conditions. The measured ferropericlase Fe³⁺ concentrations are consistent with diamond formation in a region of redox gradients, possibly arising from the subduction of oxidised material into reduced lower mantle. Reduction of carbonate to form ferropericlase and diamond is consistent with a slight shift of Kankan δ¹³C values to isotopically heavy compositions compared to the worldwide dataset, and could supply the oxygen necessary to satisfy the high Fe³⁺ concentration in (Mg,Fe)(Si,Al)O₃ perovskite, as well as account for the high proportion of ferropericlase in the lower mantle paragenesis. The heterogeneity of lower mantle diamond sources indicates that the composition of lower mantle diamonds do not necessarily reflect those of the bulk mantle.     

Use of Rhodamine water tracer in the marshland upwelling system

Rhodamine water tracer (RWT) was used to characterize the migration of waste water within the saline subsurface of a marshland upwelling system (MUS), which is an alternative on-site waste water treatment system for coastal areas. Field tracer studies were performed to investigate the fresh waste water plume movement within the saline ground water. Pore velocities were calculated using first detection times and ranged from 0.68 to 10.7 x 10(-4) cm/sec for the loamy sandy soil matrix present at the site. Use of RWT in the field also allowed determination of main and preferential flowpaths. One- and two-dimensional laboratory experiments were performed using silica sand to investigate the interactions of the organically rich waste water with RWT within the zone surrounding the point of injection (one-dimensional) and the impact of background salinity on plume movement (two-dimensional). The results from these studies were used to help explain the field data. One-dimensional breakthrough curves revealed retardation factors for the RWT in the waste water mixture of 1.73 to 1.90. These results were similar to other researchers, indicating little interaction between the waste water and RWT. Variations in pore water salinity (5, 15, 25, and 35 ppt) were found to have a significant effect on pore water velocities of the fresh water plume (two-dimensional), indicating the need to incorporate background salinities into the design process for MUS.     

Effects of trace metal and exposure to air on serotonin and dopamine levels in tissues of the mussel Perna perna

We evaluated levels of serotonin (5HT) and dopamine (DOPA) in muscle and digestive glands of the mussel, Perna perna, collected at different times of day; exposed to air for 24 h, followed by re-submersion; and after exposure to different metals. Mussels collected at different periods of day showed little oscillation in 5HT and DOPA levels. Mussels exposed to metals showed significant changes in 5HT and DOPA levels in digestive gland and muscle, as did mussels exposed to air. Our data suggest that analyses of 5HT and DOPA in tissues of mussels could serve as a tool to evaluate the presence and effects of heavy metal contamination in mussels. Care in data interpretation is required, however, since other environmental factors such as exposure of mussels to air (i.e. at low tides) can also cause changes in DOPA and 5HT levels. Additional research is necessary to separate such natural environmental effects from effects of contaminants.