The Application of Petroleum Hydrocarbon Fingerprint Characterization in Site Investigation and Remediation

Tremendous resources have been and continue to be spent investigating and remediating petroleum hydrocarbon compounds (PHCs) in soil and ground water. Investigating and planning a remedial strategy for sites affected by PHCs is often a challenging task because of the complex chemical nature of the PHCs. the complex regulatory environment related to PHC cleanup, and the use of analytical methods that provide quantitation but not identification of PHCs. From a technical standpoint, the PHC impacting soil and/or ground water is frequently inadequately characterised, both in identification as well as in is general properties (solubility, toxicity). From a regulatory standpoint, promulgated or recommended total petroleum hydrocarbon (TPH) cleanup levels generally relate to assumed properties of specific unweathered products and are inconsistent among different agencies and regions. This produces a prime situation for unwillingly spending more resources on investigation or remediation than may be necessary, especially when the PHC in the subsurface has different properties from unweathered products such as gasoline or diesel.
Accurately identifying the PHC and its nature, a process known as fingerprint characterization, is critical to the determination of appropriate regulatory goals and design of cost-effective remedial approaches. This paper presents several case studies in which fingerprint characterization made a significant difference in the project outcome. In each instance the nature of the organic material was better understood, the regulatory cleanup levels were negotiated based on the nature of the material, and a remedial approach was implemented that differed significantly from and was generally less costly than what would have been required without fingerprint characterization data.     

Observations of vertical ground accelerations exceeding gravity during the 1997 Umbria-Marche (central Italy) earthquakes

We found extensive evidence that the vertical ground accelerations produced during the largest shock (M = 6.0) of the 1997 Umbria-Marche earthquake sequence exceeded 1g in two areas close to the heavily-damaged villages of Annifo and Colle Croce. This evidence comes from the striking observation of thousands of freshly fractured and broken rocks and stones in these areas. Some of the broken stones lie isolated on soft detritic soil while others had been previously piled up, probably a long time agoto clear the fields for farming. The freshness of the cuts and fractures and the consistency of the observations for thousands of rocks and stones in these areas indicate that these rocks were thrown upwards during the earthquake, with breakage occurring at the time of impact. Ground motion calculations consistent with the static deformation inferred from GPS and interferometry data, show that the broken stones and rocks are found in the zone where the strongest shaking took place during the earthquake and that most of the shaking there was vertical.     

Spheroidal pyroxenite aggregates in the Bushveld Complex — a special case of silicate liquid immiscibility

Spherical aggregates of orthopyroxene are reported from some parts of the Bushveld Complex in a variety of host rocks.Detailed mapping has shown that these spherical aggregates, comprising pyroxenite spheroids in a quartz-norite matrix, are contact phenomena and not stratigraphic markers. Orthopyroxene, biotite and amphibole are enriched in spheroids relative to matrix; their mineral chemistry showing a fairly constant orthopyroxene and plagioclase composition through the spheroids and into the matrix, indicating in-situ formation.Bulk chemistry shows spheroid to matrix tie-lines orthogonal to those generally accepted for silicate liquid immiscibility, but other chemical information is consistent with the occurrence of immiscibility.The formation of the aggregates may be related to the industrial process of spherical agglomeration, by which spheroids are formed by the introduction of an immiscible “bridging liquid” to the melt — probably derived from the floor rocks in this case. The mechanism accounts for the field relationships, petrography and chemistry of the aggregate-matrix system. The petrology of the process equates with a special case of silicate liquid immiscibility induced by local contamination and ageing of the original magma.A similar “bridging liquid” mechanism could also account for the formation of the so-called “boulder bed” beneath the Merensky Reef.     

Maximum response of asymmetric structures subject to A multicomponent earthquake

A simple and general technique to obtain a six-component earthquake input motion of a rigid foundation using three-linear-components earthquake record is presented. Using the multicomponent input, the maximum structural response to an arbitrarily oriented earthquake is derived. The method is applied to determine the response spectrum for a two-d.o.f. laterally and torsionally coupled linear system. The effects of foundation geometry, structural properties and apparent wave velocity on the structural response are investigated. It is found that increasing the foundation size reduces the peak values of the input motion; this reduction is more pronounced for a square foundation than for a circular one.     

Species Composition and Some Ecological Notes on Diatom Communities of a Lotic Environment in Tarhunãh,Libya Artenzusammensetzung und einige ökologische Notizen über Diatomeengesellschaften eines lotischen Biotops in Tarhunãh/Libyen

Libya occupies a large part of the Sahara Desert, and is a predominantly arid country with extremely scarce freshwaters. Despite aridity, a distinct higher rainfall zone exists along its mediterranean coastal belt. A lotic environment (perennial stream) in Ain-Scersciara, Tarhunãh in northwest Libya was studied for the species composition of diatom communities and their ecological characteristics. The waters are generally alkaline (pH = 7.5) and of hard-water (conductivity = 2008 μS/cm) type. The epiphytic diatom growth on benthic filamentous algae was high (32 taxa) with Amphora veneta as a very common taxon. Gomphonema parvulum var. micropus was an important taxon found in scrapings from the leaves of macrophytes and stony substratum. Nitzschia and Navicula showed high species richness (9 taxa in each) followed by Gomphonema (6 taxa). The ecological attributes of the majority of taxa show an oligohalobe status and alkaliphilous indicator.     

SAMPLING AND MINIMUM PHASE FROM BOTH A CONTINUOUS AND DISCRETE POINT OF VIEW*

Examples show that the sampling operation–i.e., the change from the continuous time domain to the discrete time domain–does not necessarily preserve the minimum-phase property. Further examples can be constructed to show that the resampling operation on the discrete time domain does not necessarily preserve the minimum-phase property. Finally it can be shown that the minimum-phase property can be either created or destroyed by sampling or resampling.