False waves in wave records

A methodology to define discrete waves from free sea surface elevation time series is presented. The method allows an objective discrimination of false waves among small waves, avoiding the use of arbitrary criteria associated with zero-up-crossing, zero-down-crossing, or other definitions. The method uses the Hilbert Transform and the representation of the time series in the complex plane. A discrete wave corresponds to a 2π phase-advance in the complex plane. The waves between zero crossings which do not show 2π phase advance are considered false waves. Wave rider buoy records, measured off the west coast of Portugal, were employed in assessing some of the statistical implications of this methodology.     

Nature and composition of shore-zone sediments between Jeddah and Yanbu, eastern Red Sea

The shore-zone sediments between Jeddah and Yanbu, west coast of Saudi Arabia, are composed mostly of skeletal carbonate sands. The nearshore sediments containing benthic foraminifera, algal fragments and molluscs are multimodal, the mean grain size varying between 0.76 and 2.35 ø. The beach sediments, except samples dominated by cerithid gastropods in some localities, are relatively finer than the nearshore sediments. Although the beaches to a great extent comprise sand-sized material, fine lime muds and coarse clastic gravels occur in certain areas. The dune sediments comprising mostly algal grains and ooids are very fine with 50 percent of the material in the 0.25–0.18 mm size grade. Except a general northward decrease in mean grain size, regional trends in the textural parameters of the sediments between Jeddah and Yanbu are not quite apparent. Lateral variations in the textural characteristics suggest a landward migration of the sediments in the shore zone under the influence of northerly and northwesterly winds. The carbon and oxygen (δ ¹³C + 4.80 to 4.84‰ PDB) (δ ¹³O − 0.04 to + 0.53‰ PDB) isotopic ratios of the lime muds occurring in certain shallow margins in the shore-zone, which are much higher than those of the green algae, indicate that the fine carbonates are at least in part inorganic in origin.

Like the shallow-water carbonates in tropical seas, aragonite and high Mg-calcite are the dominant carbonate minerals in the shore-zone sediments. There is a landward increase in aragonite contents caused by the landward migration of fine material from the nearshore. The dominant clay mineral in the nearshore sediments is kaolinite with subordinate swelling chlorite and little illite. Kaolinite is contributed by the coastal regions under the sub-tropical humid climate. Swelling chlorite is considered to have been formed in the nearshore by mechanical mixture of chlorite and montmorillonite derived from the metamorphic and igneous terrains of the Tertiary mountains bordering the coastal plain.     

Long-term recovery of a Louisiana brackish marsh plant community from oil-spill impact: vegetation response and mitigating effects of marsh surface elevation

Oil spills can have significant, short-term, negative impacts on coastal marshes, but the long-term effects and eventual recovery are not well documented, particularly in brackish marshes. The goals of this investigation were to: (1) document the long-term recovery of a Louisiana brackish marsh plant community impacted by a 1985 oil spill; (2) separate the effect of the oil spill on marsh deterioration from ambient rates of marsh deterioration; and (3) assess the relative importance of residual oil in the sediment and decreased marsh surface elevation in the failure of certain areas to recover. A total of 68 permanent plots previously established in 1985 were re-surveyed for plant and soil recovery in the fall of 1989. Although substantial (and near total) vegetative recovery was evident by significant increases in live and total vegetative cover, many of the plots that were initially heavily impacted by oil still displayed elevated levels of total saturated hydrocarbons in the soil. August 1990 measurements of plant photosynthetic response and edaphic variables revealed no significant differences between control plots and plots heavily impacted by oil that displayed vegetative regrowth. Rates of wetland land loss in the oiled marsh during an 8-year period that bracketed the time of the spill were within the historical range measured for this site and similar to the land loss rates of adjacent reference marshes. Results from a manipulative field transplant experiment indicated that the long-term failure of certain small areas to revegetate was primarily due to a decrease of marsh surface elevation (increased flooding stress), not a residual oil effect.     

Thermodynamic characterization of the partitioning of iron between soluble and colloidal species in the Atlantic Ocean

Recent electrochemical measurements have shown that iron (Fe) speciation in seawater is dominated by complexation with strong organic ligands throughout the water column and have provided important thermodynamic information about these compounds. Independent work has shown that iron exists in both soluble and colloidal fractions in the Atlantic Ocean. Here we have combined these approaches in samples collected from a variety of regimes within the Atlantic Ocean. We measured the partitioning of Fe between soluble (< 0.02 μm) and colloidal (0.02 to 0.4 μm) size classes and characterized the concentrations and conditional stability constants of Fe ligands within these size classes. Results suggest that equilibrium partitioning of Fe between soluble and colloidal ligands is partially responsible for the distribution of Fe between soluble and colloidal size classes. However, a significant fraction of the colloidal Fe was inert to ligand exchange as soluble Fe concentrations were generally lower than values predicted by a simple equilibrium partitioning model.In surface waters, strong ligands with conditional stability constants of 10¹³ relative to total inorganic Fe appeared to dominate speciation in both the soluble and colloidal fractions. In deep waters these ligands were absent, and instead we found ligands with stability constants 12–15 fold smaller that were predominantly in the soluble pool. Nevertheless, significant levels of colloidal Fe were found in these samples, which we inferred must be inert to coordination exchange.     

Species, tissue and gender-related organochlorine bioaccumulation in white-sided dolphins, pilot whales and their common prey in the northwest Atlantic

Organochlorine concentrations were measured in white-sided dolphins, pilot whales, and their prey from the Gulf of Maine and used to identify species, tissue, and gender differences, and trophic transfer trends, in bioaccumulation. Polychlorinated biphenyl concentrations ([PCB]) in dolphin blubber (13 +/- 7.1 micrograms/g fresh wt.) were twice those in pilot whales, but pesticide concentrations (20 +/- 13 micrograms/g fresh) were similar between species. 4,4'-DDE, trans-non-achlor, Cl6(153) and Cl6(138) concentrations were highest. Skin tissues had more recalcitrant organochlorines than the internal organs. Male dolphins bioaccumulated higher concentrations of nonmetabolizable PCBs and hexachlorocyclohexane (HCH) isomers, whereas pilot whales had no gender-related differences in bioaccumulation. Pilot whales, mackerel, and herring had proportionately higher concentrations of DDTs, whereas [PCB] were higher in dolphins and squid. Although these odontocetes feed at the same trophic level and store a similar suite of contaminants, dolphins bioaccumulated higher and potentially hazardous 4,4'-DDE and PCB concentrations from food in their more geographically restricted range.