Seasonal and Diurnal Variation of Surface Ozone and a Preliminary Analysis of Exceedance of its Critical Levels at a Semi-arid Site in India

The mixing ratios of surface O₃ were measured at St. John's College, Agra, an urban and traffic influenced area for the period of 2000–2002. The monthly averaged O₃ mixing ratios ranged between 8 to 40 ppb with an annual average of 21 ppb. Strong diurnal and seasonal variations in O₃ mixing ratios were observed throughout the year except for monsoon season. The mixing ratios of O₃ follow the surface temperature cycle and solar radiation (r = 0.72 and r = 0.65 with temperature and solar radiation, respectively). Concentrations were higher with winds associated with NE and NW direction indicating the impact of pollution sources on surface O₃ concentration. Exceedance of ozone critical level was calculated using the AOT 40 index and found to be 840 ppb.h and 2430 ppb.h for summer and winter seasons, respectively. The present O₃ exposures are lower than the critical level of O₃ and suggest that the present level of O₃ does not have any impact on reduction in crop yields.     

The ACPI Climate Change Simulations

The Parallel Climate Model (PCM) has been used in the Accelerated ClimatePrediction Initiative (ACPI) Program to simulate the global climateresponse to projected CO₂, sulfate, and other greenhouse gasforcingunder a business-as-usual emissions scenario during the 21st century. In these runs, the oceans were initialized to 1995 conditions by a group from the Scripps Institution of Oceanography and other institutions. An ensemble of three model runs was then carried out to the year 2099 using the projected forcing. Atmospheric data fromthese runs were saved at 6-hourly intervals (hourly for certain criticalfields) to support the ACPI objective of accurately modeling hydrologicalcycles over the western U.S. It is shown that the initialization to1995 conditions partly removes the un-forced oceanic temperature and salinity drifts that occurred in the standard 20th century integration. The ACPI runs show a global surface temperature increase of 3–8 °C over northern high-latitudes by the end of the 21st century, and 1–2 °C over the oceans. This is generally within ±0.1°Cof model runs without the 1995 ocean initialization. The exception is in theAntarctic circumpolar ocean where surface air temperature is cooler in theACPI run; however the ensemble scatter is large in this region. Althoughthe difference in climate at the end of the 21st century is minimalbetween the ACPI runs and traditionally spun up runs, it might be largerfor CGCMs with higher climate sensitivity or larger ocean drifts. Ourresults suggest that the effect of small errors in the oceans (such asthose associated with climate drifts) on CGCM-simulated climate changesfor the next 50–100 years may be negligible.     

PART II: Comparison of Theoretical and Experimental Estimations of Site Effects

— To check the reliability and the quality of the theoretically estimated ground responses obtained from the 2-D simulation by the application of the hybrid method in PART-I, we compare some of them with those obtained at the same sites from observed data using the Standard Spectral Ratio (SSR). The comparison validates our synthetic modeling and shows that in cases of complex geometries, the use of at least 2-D numerical simulations is required in order to reliably evaluate site effects and thus facilitate the microzonation of the city of Thessaloniki.     

Analysis of Chironomid Remains from Lake Sediments in Paleoecological Reconstruction

The results of methodological studies of paleoecological reconstruction of environmental characteristics are considered. The studies are based on the analysis of chironomid remains from the sediments of lake ecosystems. The investigation is focused on the methodical basis of analysis and the perspectives and range of its application to long-term environmental changes of natural and anthropogenic origin. It is shown that the development of this method in future studies will require a balanced combination of neo- and paleoecological approaches.     

Quality Appraisal of Surface Waters on Fennoscandian Territory

Widely applied bioindication methods are analyzed based on the survey data of 1980–1996 for over 400 lakes and 300 watercourses in the northeastern Fennoscandia known to experience anthropogenic impact (toxification, acidification, eutrophication, and thermofication). Representative results of hydrobiological analysis of the quality of surface waters in areas with mixed toxic pollution (or anthropogenic acidification) may be obtained if methods are applied, different from the bioindication methods that are now accepted as standard for Russia, along with methods of biotesting natural waters. The saprotoxibity index, Kola biotic index, acidification estimation scale, biotesting methods were developed and adapted to regional conditions.     

Functioning of the White Sea Ecosystem: Studying the Transformations of Organogenic Substances Using a Mathematical Model

Long-term observational data on hydrology, hydrochemistry, and hydrobiology are generalized and used for systems analysis of the biohydrochemical transformation processes of organic and biogenic substances in a marine environment. An ecological model with the systematized data is used to assess the annual dynamics of concentrations of organic and mineral N, P, and Si compounds and dissolved organic C and O₂ in eight water areas within the White Sea at specified conditions of water mass transport, river runoff, and water exchange with the Barents Sea. Variations in the biomasses of the major transformers of organic and biogenic substances (heterotrophic bacteria, phyto- and zooplankton, and microphytes) and their biological production were also evaluated. These characteristics serve as indicators of the state of the water environment, the presence of nutrients in it, and their import from outside.     

Copper (II) Speciation in a Freshwater Ecosystem

Results of chemico-biological experiments in a natural water body with the use of model systems with Cu (II) introduced in them at different proportions of its chemical forms (natural and simulated) in the solution. The model forms used in the experiments were Cu complexes with benzyl- and hexadecylmalonic acids, simulating low-molecular dissolved organic substances. The experimental conditions were chosen based on a preliminary calculation using WATEQ–4f program. The complexes of Cu with hexadecylmalonic acid are found to be absorbed by suspensions and removed into bottom sediment more actively than other Cu forms. The toxicity of introduced Cu for the phyto- and zooplanktonic communities is found to depend on the concentration of Cu²⁺ aqua-ions in the solution, in the presence of which the higher concentrations of complexes with malonic acids do not exert their toxic effect.     

Environmental Condition of Water Bodies in the Territory of an Oil–Gas Condensate Field (the Pechora Delta)

Chemical characteristics of the surface water and algae in lakes in the Seduiyakha River basin are presented. Specific features of components of limnetic ecosystems under the influence of anthropogenic factors in the territory of an oil–gas condensate field are shown. Ambiguous response of algal communities to changes in the aquatic environment is revealed.     

HVSR prospecting in multi-layered environments: An example from the Tyrnavos Basin (Greece)

The Tyrnavos Basin (Central Greece) is an E-W trending graben bordered by two major antithetic sets of right-stepping dip-slip normal faults that began forming during Middle Pleistocene as a consequence of the N-S extension which affected the whole Aegean Region. This Quaternary structure is superimposed on the Pliocene-Early Pleistocene NW-SE trending Larissa Basin, approximately 700–800 m deep. Seismic activity is instrumentally well documented within and surrounding the investigated area. Based on structural, morphotectonic and palaeoseismological data, several structures previously characterised as active faults have been investigated by applying the HVSR method. This method is commonly used to map the thickness of sedimentary layers in a basin based on the variation of the fundamental 1-D frequency. The polyphased structural evolution and the consequently complex geological setting do not allow for the contouring of a unique continuous surface. We therefore developed a new interpretation technique for statistically significant HVSR peaks, in order to obtain 2-D sections that can be interpreted in a seismic-like fashion. We applied this technique across the major active faults bordering the basin. The results confirm their occurrence at depth and document the important vertical component of displacement.