Rare earth element distribution in some hydrothermal minerals: evidence for crystallographic control

Rare earth element (REE) abundances were measured by neutron activation analysis in anhydrite (CaSO₄), barite (BaSO₄), siderite (FeCO₃) and galena (PbS). A simple crystal-chemical model qualitatively describes the relative affinities for REE substitution in anhydrite, barite, and siderite. When normalized to ‘crustal’ abundances (as an approximation to the hydrothermal fluid REE pattern), log REE abundance is a surprisingly linear function of (ionic radius of major cation—ionic radius of REE)² for the three hydrothermal minerals, individually and collectively. An important exception, however, is Eu, which is anomalously enriched in barite and depleted in siderite relative to REE of neighboring atomic number and trivalent ionic radius. In principle, REE analyses of suitable pairs of co-existing hydrothermal minerals, combined with appropriate experimental data, could yield both the REE content and the temperature of the parental hydrothermal fluid.The REE have only very weak chalcophilic tendencies, and this is reflected by the very low abundances in galena—La, 0.6 ppb; Sm, 0.06 ppb; the remainder are below detection limits.     

Stratigraphic relations and habitat of the Bende fish teeth,southeastern Nigeria

The age and habitat of the Bende fish fossils have remained a matter of controversy with interpretations ranging between the Paleocene Imo Formation and the Eocene Ameki Formation. Outcrop-based sequence stratigraphic analysis presented in this work shows that the Imo and Ameki Formations together include three laterally extensive estuarine central basin/offshore mud rock units that are associated with the 59.7, 58.1, and the 56.8 ma maximum flooding surfaces, respectively. Field evidence and stratigraphic analysis show that the Bende fossil bones are hosted by the mud rock unit containing the 58.1 ma maximum flooding surface, while the Ameke bone fossils are contained within the condensed section associated with the 56.8 ma maximum flooding surface. Apart from highlighting the relevance of sequence stratigraphy in paleobiological interpretations, this study shows that the Bende fish fauna which Arua first assigned to the Eocene Ameki Formation indeed belongs to the Paleocene Imo Formation.     

Spatial and temporal variability of mesozooplankton and tintinnid ciliates in a seasonally hypersaline estuary

The zooplankton community of Mission Bay, San Diego, California, was monitored over two years, to study spatial and temporal patterns and the response of zooplankton species composition to environmental variation. Data were collected every two weeks from six stations and included hydrographic parameters, dissolved nutrient concentrations, and phytoplankton and zooplankton species composition. Hydrography varied seasonally, along a spatial gradient from the mouth to the back of the bay, and between the two years around the influence of rainfall. Spatially, Mission Bay could be divided into three regions during this study based on hydrography and zooplankton species composition. Zooplankton species composition followed a predictable seasonal progression, with different groups of species being characteristic to particular times of the year. Variability in zooplankton species composition was also evident between years, as certain species were more common in one or the other year of the study. Spatial patterns were more consistent than temporal ones, and related to distance from the mouth of the bay during much of the year and distance from freshwater inlets during the relatively short rainy season. Multivariate analysis revealed that variation in zooplankton species composition was best related to measured abiotic factors (temperature, salinity, rainfall, and tidal velocity).     

Morphology and structure of the Galapagos Rise

Geophysical data collected on three U.S. Naval Oceanographic Office cruises to the Galapagos Rise are presented. These data allow definition of the morphology and structure of the Galapagos Rise.A postulated “hot spot” beneath the Galapagos platform is suggested as the cause of: (1) decreased seismicity along the spreading center for a 400 km E—W distance from the islands; (2) distinctive petro-chemistry of tholeiites from the islands and adjacent oceanic crust generated by the Galapagos Rise; (3) high-amplitude magnetic anomalies in a 1,000 km E—W band including and just north of the Galapagos platform; and (4) morphologic shape and the regionally elevated sea floor of the Galapagos Rise as it approaches the insular platform.     

Settling velocities of particulate systems, 3. Power series expansion for the drag coefficient of a sphere and prediction of the settling velocity

The following equation has been previously developed for the drag coefficient of a sphere.

$\text{C}{}_{\mathrm{D}}\text{= C}{}_0\text{[1 + (σ}{}_0\text{/Re}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)]}{}^2$

In this work the authors propose a power series expansion for C₀ in terms of the Reynolds number:

$\text{C}{}_0\text{= 0 284153}\text{Σ}\text{α=0}\text{n}\text{B}{}_{\mathrm{\alpha }}\text{Re}{}^{\mathrm{\alpha }}$

A fifth-order polynomial permits obtaining the drag coefficient and the settling velocity of a sphere, up to a Reynolds number of 3 × 10⁵, with an average relative error of about 2%.     

Effects of large organic material on channel form and fluvial processes

Stream channel development in forested areas is profoundly influenced by large organic debris (logs, limbs and rootwads greater than 10 cm in diameter) in the channels. In low gradient meandering streams large organic debris enters the channel through bank erosion, mass wasting, blowdown, and collapse of trees due to ice loading. In small streams large organic debris may locally influence channel morphology and sediment transport processes because the stream may not have the competency to redistribute the debris. In larger streams flowing water may move large organic debris, concentrating it into distinct accumulations (debris jams). Organic debris may greatly affect channel form and process by: increasing or decreasing stability of stream banks; influencing development of midchannel bars and short braided reaches; and facilitating, with other favourable circumstances, development of meander cutoffs. In steep gradient mountain streams organic debris may enter the channel by all the processes mentioned for low gradient streams. In addition, considerable debris may also enter the channel by way of debris avalanches or debris torrents. In small to intermediate size mountain streams with steep valley walls and little or no floodplain or flat valley floor, the effects of large organic debris on the fluvial processes and channel form may be very significant. Debris jams may locally accelerate or retard channel bed and bank erosion and/or deposition; create sites for significant sediment storage; and produce a stepped channel profile, herein referred to as ‘organic stepping’, which provides for variable channel morphology and flow conditions. The effect of live or dead trees anchored by rootwads into the stream bank may not only greatly retard bank erosion but also influence channel width and the development of small scour holes along the channel beneath tree roots. Once trees fall into the stream, their influence on the channel form and process may be quite different than when they were defending the banks, and, depending on the size of the debris, size of the stream, and many other factors, their effects range from insignificant to very important.     

Recent volcanism at Schonchin and Cinder Buttes,northern California

Recent volcanism on the northern flank of the Medicine Lake Highland consists of a series of basalt to andesite spatter and cinder cones and their associated flows. Two particular structures, Cinder Butte and Schonchin Butte, have erupted materials that are very similar in terms of age, volume, modal mineralogy, and many major and trace elements. Significant differences with respect to TiO₂, K₂O, P₂O₅, Sr, Ba, Zr, and LREE can be related to possible changes in the mineralogy within the source region of these volcanic rocks. Apatite and priderite are the two minor constituents that best satisfy the constraints set by the mineral and chemical data. An inhomogeneous upper mantle or lower crust beneath the Medicine Lake Highland is indicated.     

The Mafic and Ultramafic Lavas of the Belingwe Greenstone Belt, Rhodesia

The Belingwe Greenstone Belt (2.8 x 10⁹ yrs old) contains a7 km succession of mafic and ultramafic lavas and high-levelintrusions which overlie a thin sedimentary formation, itselfunconformable on a granitic basement. The lavas range in compositionfrom andesites (4 per cent MgO) to peridotitic komatiites (32per cent MgO). The mineralogy and textures of the most magnesianlavas demonstrate that they were extruded in a completely liquidstate. If the source mantle had an MgO content around 40 percent, then partial melts in the range 35 per cent to 55 percent would be required to produce the most magnesian liquidsobserved. Chemical constraints on the petrogenesis of the ultramafic lavasallow estimates of source mantle composition. In particular,if the source had an MgO content around 40 per cent, then theoverall source composition would be similar to that of garnetIherzolite nodules in kimberlites. The calculated REE contentsof the source are close to chondritic. If all the ultramaficlavas were derived from the same source then the variation inliquid composition may have been controlled by orthopyroxeneas well as olivine during partial melting at depth. The evolutionof the less magnesian komatiites, basalts, and andesites canbe explained by lower degrees of partial melting of a commonsource, and by high-level fractionation of parent liquids similarto those extruded as ultramafic lavas. Physical constraints on the origin of the lavas imply derivationfrom a depth of 150 km or more, at temperatures of 1600–2000°C.     

Geochemistry of redeposited and undisturbed ancient weathering zones in the Baikal Region

The distribution of major and trace elements was explored in the metamorphised weathering zones of the northern (Purpol Formation) and western (Anai and Angin formations) Baikal region. The alumina-rich schists of the Purpol and Anai formations intercalated with quartzites have a model age of 2.8–3.0 Ga and are redeposited products of the weathering of granitized basement inliers of the Siberian craton. Their trace element characteristics with high contents of Th, U, Nb, and REE and low Ta and Sr reflect the composition of predominant rocks in the Archean basement. Undisturbed weathering zones over the alkaline and calc-alkaline island-arc basalts of the Angin Formation are, in general, similar to modern laterites and redeposited residues with respect to the enrichment in hydrolyzate elements but are assigned to iron-rich laterites and distinguished by high contents of Fe, Ti, Nb, Ta, Zr, and Hf, which were inherited from their parent rocks. Their occurrence suggests subaerial eruptions of alkali basalts in the proximal part of the Angin-Talanchan island arc.