Age and geochemical constraints for partial melting of granulites in Estonia

Summary The rocks of the crystalline basement of the East European Craton in southern Estonia show effects of partial melting under granulite facies conditions. Zircons extracted from partial melting products (tonalite from the Tapa Zone – 1824 ± 26, tonalite from the South Estonian Zone – 1788 ± 16 Ma and charnockite from the Tapa Zone – 1761 ± 11 Ma) yield U–Pb crystallisation ages that span over approximately 80 Ma, suggesting a prolonged high-grade metamorphism or several separate events. U–Pb zircon age of one sample of charnockite is concordant with the Nd model age of partial melting of its host mafic granulite facies gneiss (intercept at 1.76 Ga). Linear geochemical trends and similar initial Nd isotopic compositions of mafic granulites and charnockites suggest their possible genetic relationship. From our new and previously published data it follows that the peak granulite metamorphic conditions and formation of tonalites and charnockites (850 °C and 6 kbar) in the Estonian basement occurred at 1788–1778 Ma. Then, the rocks cooled down, passing through the garnet closure temperature of approximately 650–700 °C at 1728 ± 24 Ma. The age of metamorphism of the Estonian granulites is lower than the metamorphic ages known from southern Finland, but it is similar to the age of metamorphism reported from the Belarus-Baltic Granulite Belt in Latvia.     

Monitoring of the temperature–moisture regime in St. Martin’s Cathedral tower in Bratislava

Buildings are often composed of materials with a porous structure. Moisture in the masonry has a destructive impact caused by cycles of drying–wetting and freezing–thawing. A new sensor principle for monitoring moisture in the masonry is presented herein. This sensor utilizes changes in the thermal conductivity of porous structures when they are filled with moist air, water, or ice depending on the existing thermodynamic conditions. Herein, the “hot-ball” method is used to measure the thermal conductivity. The moisture sensor is prepared for porous material corresponding to the parent material, whether it is rock, brick, or concrete. This parent sample is taken from a borehole drilled into the wall. Methodology for moisture sensor calibration is also presented. Sensors were placed in the masonry walls of St. Martin’s Cathedral tower in the North, South, and West orientations. The sensors were placed in the plaster and bricks at depths up to 60 mm in the wall surface, just below the window sill. The temperature–moisture regime was monitored from August 19th, 2011 to March 30th, 2012. Changes in temperature and moisture were then correlated with meteorological data.     

Hydrothermal synthesis of kaolinite illustrated by X-ray diffractograms and scanning electron micrographs,part II

Summary The hydrothermal synthesis of kaolinite from various alumina and silica starting materials reacted at 200°C in aqueous solutions of oxalic acid and H₂SO₄ with the corresponding saturated water vapour pressure, in periods of time from 10 to 25 days, has been followed by X-ray diffraction measurements, scanning electron microscopy, and energy dispersive analysis of the products. The temperature and time periods of reactions were chosen on the basis of previously collected data on the effects of H₄EDTA, a complex-forming agent, and of H₂SO₄, an inorganic acid, on the rate of formation of kaolinite. Aluminium-complexing acids increase the rate of formation or decrease the temperature of formation of kaolinite as shown by evidence from X-ray diffraction patterns. The influence of the starting materials as sources of aluminum, amorphous aluminum hydroxides, pseudoboehmite, allophane or gibbsite, has also been examined by X-ray diffraction, scanning electron microscopy, and by energy dispersive analysis. Scanning electron micrographs indicated that silica is a more mobile phase than alumina, based on the progressive formation of a thin coating on gibbsite during early reaction, then by growth of clusters of platy crystals of kaolin, and finally by production of pellets of stacked crystal flakes. Where gibbsite was used in the reaction mixture, boehmite was commonly observed as an intermediate phase.With 16 Figures     

Die Stellung des Amphibols in der Mineralparagenese westmährischer Skarngesteine

Summary The iron-ore skarns of the core of the Bohemian Massif is an old petrographic unit which is already doeply metamorphosed under conditions of an abyssal metamorphism. The paragenetical analysis as well as the chemical study of their mineral assemblages makes it clear that the amphibole occuring in subordinate quantities in these skarns is not a relic mineral (having not originated during the premetamorphic skarnization period). It appeared only in the course of the regional metamorphism in connection with the migmatization processes which took place in the rocks adjoining the skarn bodies and in connection with the injections of pegmatites traversing the skarn rocks.

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Urban landslide monitoring by combined use of multiple methodologies - a case study on Sv. Anton town,Slovakia

ABSTRACT

We employed integrated methods to assess the landslide movement in Sv. Anton town in the Western Carpathians Neogene Volcanic Field (Central Slovakia). The integrated diagnostics required study of the landslide kinematic activity by a combination of Global Navigation Satellite Systems (GNSS) and Electrical Resistivity Tomography (ERT) imaging from November 2013 to March 2015. A topographic model with 2-cm accuracy was constructed from Unmanned Aerial Vehicles (UAV) photogrammetry. Continuous spatial datasets of movement and displacement field vectors were interpolated from the measured movements over the entire study period. Although deformation studies in Slovakia have a long-term tradition, complex interdisciplinary studies in urbanized areas are still lacking. This inspired our main objectives: to identify landslide kinematics and to reconstruct and define the rates of annual landslide movement obtained from geodetic measurement at the monitoring points. Our results demonstrate how landslide integrated diagnostics contribute to the detection of slope instability, with a maximum velocity of 60.82 mm/yr during the summer period. The precipitation effects are consistent with the Sv. Anton landslide displacement acceleration, and the following increases in total monthly precipitations are staggering compared to long-term monthly averages: July precipitation increased by 175.3%, August by 203.3%, and September by 198.1%.     

Thermochronological insights into the structural contact between the Tian Shan and Pamirs,Tajikistan

Multi‐method thermochronology along the Vakhsh‐Surkhob fault zone reveals the thermotectonic history of the South Tian Shan–Pamirs boundary. Apatite U/Pb analyses yield a consistent age of 251 ± 2 Ma, corresponding to cooling below ~550–350°C, related to the final closure of the Palaeo‐Asian Ocean and contemporaneous magmatism in the South Tian Shan. Zircon (U–Th–Sm)/He ages constrain cooling below ~180°C to the end of the Triassic (~200 Ma), likely related either to deformation induced by the Qiangtang collision or to the closure of the Rushan Ocean. Apatite fission track thermochronology reveals two low‐temperature (<120°C) thermal events at ~25 Ma and ~10 Ma, which may be correlated with tectonic activity at the distant southern Eurasian margin. The late Miocene cooling is confirmed by apatite (U–Th–Sm)/He data and marks the onset of mountain building within the South Tian Shan that is ongoing today.     

Assessment and control of organic and other contaminants associated with the Stardust sample return from comet 81P/Wild 2

Abstract– Numerous potential sources of organic contaminants could have greatly complicated the interpretation of the organic portions of the samples returned from comet 81P/Wild 2 by the Stardust spacecraft. Measures were taken to control and assess potential organic (and other) contaminants during the design, construction, and flight of the spacecraft, and during and after recovery of the sample return capsule. Studies of controls and the returned samples suggest that many of these potential sources did not contribute any significant material to the collectors. In particular, contamination from soils at the recovery site and materials associated with the ablation of the heatshield do not appear to be significant problems. The largest source of concern is associated with the C present in the original aerogel. The relative abundance of this carbon can vary between aerogel tiles and even within individual tiles. This C was fortunately not distributed among a complex mixture of organics, but was instead largely present in a few simple forms (mostly as Si‐CH₃ groups). In most cases, the signature of returned cometary organics can be readily distinguished from contaminants through their different compositions, nonterrestrial isotopic ratios, and/or association with other cometary materials. However, some conversion of the carbon indigenous to the flight aerogel appears to have happened during particle impact, and some open issues remain regarding how this C may be processed into new forms during the hypervelocity impact collection of the comet dust.     

Different ways of landslide geometry interpretation in a process of statistical landslide susceptibility and hazard assessment: Horná Súča (western Slovakia) case study

The article draws a comparison between different ways of landslide geometry interpretation in the scope of the statistical landslide hazard and risk assessment processing. The landslides are included as a major input variable, which are compared with all of the input parametric factors. Based on the above comparison the input data are classified and the final map of landslide susceptibility is constructed. Methodology of multivariate conditional analysis has been used for the construction of final maps. Unique condition units was developed by combination of geological map (lithological units) and slope angle map. Lithological units were derived from geological map and subsequently reclassified into 22 classes. Slope angle map was calculated from digital elevation model (contour map at a scale 1:10,000) and reclassified into nine classes. As a case study, a wide area of Horná Súča (western Slovakia) strongly affected by landsliding (predominantly made of Flysch) has been chosen. Spatial data in the form of parametric maps, as well as final statistical data set were processed in GIS GRASS environment. Four different approaches are used for landslides interpretation: (1) area of landslide body including accumulation zone, (2) area of depletion zone, (3) lines of elongated main scarps, (4) lines of main scarp upper edge. For each approach, a zoning map of landslide susceptibility was compiled and these were compared with each other. Depending on the interpretation approach, the final susceptibility zones are markedly different (in tens of percent).