Evaluation of groundwater quality and contamination around fluorite mineralization,Kaman region,Central Anatolia,Turkey

Groundwater can be exposed to pollution and therefore the quality will be affected in areas of fluorite mineralization. Distribution of fluorite mineralization in the area, its formation type and hydrogeological characteristics of these rocks are a factor of the pollution parameters in groundwater. Syenite, nephelinesyenite and micro gabbro type alkaline rocks are exposed in the Kaman region. Hydrothermal fluorite mineralization is formed in fractures and fissures of the syenite and nepheline-syenites in the study area. The fluoride values of these rocks vary between 480–11990 ppm. These high fluoride concentrations in the rocks result in fluoride contamination in groundwater.     

Spatial Variation of the Precipitation Chemistry in the Thrace Region of Turkey

Pollutants affect not only the environment in which they originate since they are also transported by air currents to other locations. For this reason, air pollution is a global problem for all countries and the air and water quality need to be monitored carefully. More information on precipitation chemistry is required to determine the source of pollution as well as its effects on the ecosystems. In this study, precipitation chemistry has been analyzed for the first time by using simple bulk collectors located at four different sites in Northwest Turkey for a period of two years. About 650 sequential rainwater samples were collected and analyzed for pH, electrical conductivity, anions such as , , Cl^?, and cations such as Na⁺, K⁺, Mg²⁺, Ca²⁺, and . The selected sites were under the effect of different environmental factors. Our results showed that the highest and concentrations were measured in the Northwest of the research area. Additionally, it has been found that Ca²⁺ ions are abundant within all rainwater samples.     

Dolomite characteristics and diagenetic model of the Calcari Grigi Group (Asiago Plateau,Southern Alps – Italy): an example of multiphase dolomitization

A multidisciplinary study, conducted over the carbonate platform deposits of the Liassic Calcari Grigi Group (Southern Alps), highlighted how the use of outcrop analogues can contribute to better define the distribution of dolomitic bodies related to fault networks, to characterize the petrophysical properties of the dolomitic sequence and unravel a complex diagenetic history. This study was carried out in the Asiago Plateau (southernmost part of the eastern Southern Alps, northern Italy) which provides excellent outcrops of the Jurassic Calcari Grigi Group. The dolomitization of the Jurassic sequence is variable in terms of stratigraphic extension and geographic distribution. In the studied localities the dolomitization is generally limited to the Mount Zugna Formation and is characterized by an undulatory front, with ‘sub‐vertical dolomitic chimneys’ along the major faults. Within this unit, and often associated with faults, stacked high‐porosity and permeability bed‐parallel dolomitic bodies are developed that show excellent petrophysical properties. The dolomitic intervals are characterized by pervasive unimodal and patchy polymodal dolomite crystals. Thin section, cathodoluminescence, isotopic and fluid inclusion analyses were used to constrain the paragenetic evolution of the sequence which is similar in all the studied localities. The first dolomitization stage is marked by zoned dolomite crystals with a dull luminescent core. The porosity is thought to have increased after this stage, with dark blue luminescent dolomite accompanied by the corrosion of older crystals. The appearance of saddle dolomite marks the onset of the porosity reduction stage, ending with the infilling of vugs and the remaining open pores with calcite cement. The diagenetic evolution locally stopped at the saddle dolomite stage with the complete occlusion of the remaining pores. Paragenetic and fluid‐inclusion data suggest an evolutionary trend of increasing temperatures and decreasing salinity toward brackish fluids responsible for dolomite and calcite precipitation. The integration of the available data seem to indicate that the diagenetic evolution of the study area is related to: (i) the interplay between evolving fluids (from marine to brackish); (ii) the burial of the sequence (increasing temperature); and (iii) the evolution of the hydrogeological system (fault and fracture network, fluid mixing). This complex paragenetic evolution is strongly linked to the evolution of the porosity framework that evolved from a good, widespread network in the early stages of the burial history to a confined system in the later stages due to reduction of porosity by the deposition of late calcite and dolomite cements.     

How does the Red Sea outflow water interact with Gulf of Aden Eddies?

As the Red Sea overflow water (RSOW) enters the Gulf of Aden (GOA), it interacts with a sequence of nearly barotropic, mesoscale eddies originating in the Indian Ocean. To investigate how these eddies impact the dispersal and eastward transport of the RSOW toward the Indian Ocean, a high resolution 3D regional model is employed to explore systematically the interaction between the RSOW and mesoscale eddies. Two types of experiments are conducted. In the first set, we simulate the behavior of RSOW in the presence of an idealized cyclone and an idealized anticyclone. The second type of simulation involves nesting of the regional model (ROMS) within a data-assimilating global model (HYCOM), in which a sequence of mesoscale eddies entering the Gulf of Aden is realistically captured. This simulation is integrated for one year, and includes a simple representation of the seasonality of the RSOW.Bower et al. (2002) suggest that the Red Sea overflow might be a western boundary undercurrent. Consistent with these expectations, the idealized simulations show that the preferred pathway of the RSOW in the absence of eddies is along the coast of Somalia (southern continental shelf) as a western boundary undercurrent. Simultaneously, a cyclonic circulation is generated in the far western GOA due to vortex stretching by the descending outflow. The presence of a cyclone in the western GOA increases the peak RSOW transport, but the cyclone itself rapidly loses its coherence after interacting with the rough topography in the western GOA. The presence of an anticyclone tends to block the preferred boundary pathway and inhibits the eastward transport of the RSOW. The eddies also result in substantially increased mixing of the RSOW in the western GOA.On the basis of the more realistic ROMS experiment, it is found that the modeled RSOW leaves the western part of the Gulf of Aden in short episodic bursts with transports that are an order of magnitude greater than that associated with the quasi-steady RSOW inflow into GOA. Such enhancement in RSOW transport is shown to be induced by cyclonic eddies that cause a rapid discharge of RSOW from the western part of the GOA. We conclude that mesoscale eddies play a key role in the transport and mixing of the RSOW within GOA.     

Cratering and penetration experiments in aluminum and teflon: Implications for space‐exposed surfaces

Abstract– Whether a target is penetrated or not during hypervelocity impact depends strongly on typical impactor dimensions (D_p) relative to the absolute target thickness (T). We have therefore conducted impact experiments in aluminum₁₁₀₀ and Teflon^FEP targets that systematically varied D_p/T (=D*), ranging from genuine cratering events in thick targets (D_p << T) to the nondisruptive passage of the impactor through very thin films (D_p >> T). The objectives were to (1) delineate the transition from cratering to penetration events, (2) characterize the diameter of the penetration hole (D_h) as a function of D*, and (3) determine the threshold target thickness that yields D_h = D_p. We employed spherical soda‐lime glass (SLG) projectiles of D_p = 50–3175 μm at impact velocities (V) from 1 to 7 km s^?1, and varied target thicknesses from microns to centimeters. The transition from cratering to penetration processes in thick targets forms a continuum in all morphologic aspects. The entrance side of the target resembles that of a standard crater even when the back of the target suffers substantial, physical perforations via spallation and plastic deformation. We thus suggest that the cratering‐to‐penetration transition does not occur when the target becomes physically perforated (i.e., at the “ballistic limit”), but when the shock pulse duration in the projectile (t_p) is identical to that in the target (t_t), i.e., t_p = t_t. This condition is readily calculated from equation‐of‐state data. As a consequence, in reconstructing impactor dimensions from observations of space‐exposed substrates, we recommend that crater size (D_c) be used for the case of t_p < t_t, and that penetration hole diameter (D_h) be used when t_p > t_t. The morphologic evolution of the penetration hole and its size also forms a continuum that strongly depends on both the scaled parameter D* and on V, but it is independent of the absolute scale. The condition of D_h = D_p is approached at D* > 50. The dependence of D_h on T and V, however, is very systematic. This has led to new and detailed calibration curves, permitting the reconstruction of D_p from the measurement of either crater diameter or penetration‐hole size in Al₁₁₀₀ and Teflon^FEP targets of arbitrary thickness. We also placed witness plates behind penetrated targets to intercept the down‐range debris plume, which is generally a mixture of both target and impactor fragments and melts. These witness plates also reveal that the debris plume systematically and diagnostically depends on D*. Thick targets shed spall debris only, and target thickness must be less than crater depth (T_c) to allow projectile material on the witness plate. Concentric plume patterns, accented by characteristic “hole saw” rings, characterize penetrated Al‐targets at D* = 1–10, but they give way to distinctly radial geometries at D* = 10–20. Most of the target debris occupies the periphery of the plume, while the projectile fragments or melts reside in its central parts. The periphery of the plume is also typically more fine‐grained than its center. At D* > 50, the exit plume is dominated by solid projectile fragments that progressively coagulate and overlap with each other, giving rise to compound craters. The latter have irregular crater interiors on account of the heterogeneous mass distribution of a collisionally produced, aggregate impactor. Similarly, complex craters are observed on LDEF and Stardust and they are produced by aggregate cosmic‐dust particles containing large, dense components within a relatively low‐density, fine‐grained matrix. The witness‐plate observations can also be used to address the enigmatic clustering of impact sites observed on Stardust’s aerogel and aluminum surfaces. We suggest that this clustering is difficult to produce by the collision of particles from comet Wild 2 with the Stardust spacecraft, and that it is more likely due to particle disaggregation in the comet’s coma.     

October 23, 2011 Turkey/Van–Ercis earthquake: structural damages in the residential buildings

On October 23, 2011, a magnitude of Mw 7.2 earthquake struck the Van province in eastern Turkey which caused approximately 600 life loss and 4,000 injured people. Although the recorded peak ground accelerations were relatively low (0.15–0.2 g) compared with that of other recent destructive Turkish earthquakes and the code-based design response spectrum, a large number of reinforced concrete buildings with 4–6 stories and non-engineered masonry buildings were either heavily damaged or collapsed in the region. Based on the post-earthquake technical inspections, the goal of this paper is to introduce major reasons for structural damages in the disaster area and to discuss these failures along with the approaches given in the design code which is renewed after August 17, 1999 Marmara Earthquake. Some remarkable lessons learned from earthquake-induced failures and damages specific to building construction techniques are presented in this paper.     

Spatial distribution of climatic conditions from the Middle Eocene to Late Miocene based on palynoflora in Central,Eastern and Western Anatolia

The continental climatic evolution of Anatolia has been reconstructed quantitatively for the last 45 million years using the coexistence approach. Although there were some regional effects, the Anatolian Cenozoic continental climate record correlated with the European climatic condition and the global oxygen isotope record from marine environments. From middle Eocene to late Miocene, continental warming in Anatolia was pronounced for inferred winter temperature and mean annual temperature as in Europe. Generally, the palaeoclimatic property of Anatolia resembles the European climatic changing and marine temperature changing based on the oxygen isotope record; however, climatic values of the terrestrial area in Anatolia are higher from Lutetian to Aquitanian and these values are lower than European values from Aquitanian to Tortonian. Correspondingly, Cenozoic climatic cooling in Anatolia is directly associated with an increase of seasonality, palaeogeographic position and terrestrial condition. Furthermore, mean annual precipitation values of Anatolia remained relatively stable during the Eocene–Oligocene; however, these values indicated changing throughout middle–late Miocene. Moreover, in this study, decline of abundance and variables for the mangrove and back mangrove palaeocommunities during the last 45 million years is recorded because of the decreasing of humidity, temperature and increasing of terrestrial condition.     

Complex basin evolution in the Gökova Gulf region: implications on the Late Cenozoic tectonics of southwest Turkey

Southwestern Turkey experienced a transition from crustal shortening to extension during Late Cenozoic, and evidence of this was recorded in four distinct basin types in the Mu?la–Gökova Gulf region. During the Oligocene–Early Miocene, the upper slices of the southerly moving Lycian Nappes turned into north-dipping normal faults due to the acceleration of gravity. The Kale–Tavas Basin developed as a piggyback basin along the fault plane on hanging wall blocks of these normal faults. During Middle Miocene, a shift had occurred from local extension to N–S compression/transpression, during which sediments in the Eskihisar–T?naz Basins were deposited in pull-apart regions of the Menderes Massif cover units, where nappe slices were already eroded. During the Late Miocene–Pliocene, a hiatus occurred from previous compressional/transpressional tectonism along intermountain basins and Yata?an Basin fills were deposited on Menderes Massif, Lycian Nappes, and on top of Oligo–Miocene sediments. Plio-Quaternary marked the activation of N–S extension and the development of the E–W-trending Mu?la–Gökova Grabens, co-genetic equivalents of which are common throughout western Anatolia. Thus, the tectonic evolution of the western Anotolia during late Cenozoic was shifting from compressional to extensional with a relaxation period, suggesting a non-uniform evolution.     

Relationship between Late Pleistocene sea‐level variations,carbonate platform morphology and aragonite production (Maldives,Indian Ocean)

A piston core from the Maldives carbonate platform was investigated for carbonate mineralogy, grain‐size distributions, calcium carbonate content and organic carbon. The sedimentary record was linked to Late Pleistocene sea‐level variations, using an age model based on oxygen isotopes obtained from planktonic foramanifera, nannofossil biostratigraphy and ¹⁴C age determinations. The correlation between the sedimentary record and Late Pleistocene sea‐level showed that variations in aragonite and mud during the past 150 000 years were clearly related to flooding and sea floor exposure of the main lagoons of the atolls of the Maldives carbonate platform. Platform flooding events were characterized by strongly increased deposition of aragonite and mud within the Inner Sea of the Maldives. Exposure events, in contrast, can be recognized by rapid decreases in the values of both proxy records. The results show that sediments on the Maldives carbonate platform contain a continuous record of Pleistocene sea‐level variations. These sediments may, therefore, contribute to a better understanding of regional and even global sea‐level changes, and yield new insights into the interplay between ocean currents and carbonate platform morphology.     

The Influence of Weathering on the Engineering Properties of Dunites

Weathering processes cause important changes in the engineering properties of rocks. In this study, dunites in the Bursa region in western Turkey were investigated and the changes in engineering properties due to weathering were evaluated. The studies were initiated with field observations including measurement of the characteristics of discontinuities such as spacing, aperture, fill material, roughness, and Schmidt hammer rebound value. Subsequently, laboratory studies were conducted in two stages. The first stage comprised mineralogical, petrographic, and chemical analyses. The second stage included physicomechanical tests to determine specific gravity, unit weights, water absorption, effective porosity, uniaxial compressive strength, P-wave velocity, and slake-durability index. According to these evaluations, the changes in engineering properties were determined to be mostly related to serpentinization at every stage of weathering. The most suitable parameters for characterizing the degree of weathering of the studied dunites are loss-on-ignition values, specific gravity, unit weight, water absorption, and effective porosity.