A new oxygen-deficient perovskite phase Ca(Fe<Subscript>0.4</Subscript>Si<Subscript>0.6</Subscript>)O<Subscript>2.8</Subscript> and phase relations along the join CaSiO<Subscript>3</Subscript>–CaFeO<Subscript>2.5</Subscript> at transition zone conditions

A new oxygen-deficient perovskite with the composition Ca(Fe_0.4Si_0.6)O_2.8 has been synthesised at high-pressure and -temperature conditions relevant to the Earths transition zone using a multianvil apparatus. In contrast to pure CaSiO₃ perovskite, this new phase is quenchable under ambient conditions. The diffraction pattern revealed strong intensities for pseudocubic reflections, but the true lattice is C-centred monoclinic with a=9.2486 Å, b=5.2596 Å, c=21.890 Å and =97.94°. This lattice is only slightly distorted from rhombohedral symmetry. Electron-diffraction and high-resolution TEM images show that a well-ordered ten-layer superstructure is developed along the monoclinic c* direction, which corresponds to the pseudocubic [111] direction. This unique type of superstructure likely consists of an oxygen-deficient double layer with tetrahedrally coordinated silicon, alternating with eight octahedral layers of perovskite structure, which are one half each occupied by silicon and iron as indicated by Mössbauer and Si K electron energy loss spectroscopy. The maximum iron solubility in CaSiO₃ perovskite is determined at 16 GPa to be 4 at% on the silicon site and it increases significantly above 20 GPa. The phase relations have been analysed along the join CaSiO₃–CaFeO_2.5, which revealed that no further defect perovskites are stable. An analogous phase exists in the aluminous system, with Ca(Al_0.4Si_0.6)O_2.8 stoichiometry and diffraction patterns similar to that of Ca(Fe_0.4Si_0.6)O_2.8. In addition, we discovered another defect perovskite with Ca(Al_0.5Si_0.5)O_2.75 stoichiometry and an eight-layer superstructure most likely consisting of a tetrahedral double layer alternating with six octahedral layers. The potential occurrence of all three defect perovskites in the Earths interior is discussed.     

Assessment of slope stability in Ankara clay: a case study along E90 highway

Some slope instability problems exist in Ankara clay along E90 highway. The purpose of this paper is to determine the mineralogical and geotechnical properties of soils, and to investigate the causes and mechanisms of three rotational landslides along a section of the highway. In order to accomplish these tasks, field studies, laboratory testing, back analyses, and limit equilibrium and finite difference analyses were performed. The landslides are formed within a soil consisting of clay and silt with a little sand and gravel. Slope stability analyses indicate that long-term stability of already failed slopes is critical. The failures are progressive, showing strain softening behavior with full saturation. Broken irrigation pipes existing near the landslides are found to be the main cause of sliding. Maintenance of the pipes, surface drainage, removal and replacement of the failed (slided) material are considered to be economical and practical solutions for the remediation of the slides.     

Presence and tectonic significance of Cretaceous rudist species in the so-called Permo-Carboniferous Göktepe Formation,central Menderes metamorphic massif,western Turkey

A schist sequence of the central Menderes Massif, in which lenses of fossiliferous marbles are found, is observed in the southern flank of the Aydn Mountain, north of Kök (Aydn), around Erikavak village. These rocks have been considered as Permo-Carboniferous in age and are included in the Göktepe Formation of earlier studies. However, some rudist species are described from thickly bedded gray marbles that have a concordant contact with the overlying schist sequence. Although the rudists have been metamorphosed, it is observed that some contain fossils are well enough preserved to determine the following rudist fauna: Hippurites lapeirousei (GOLDFUSS), Hippurites nabresinensis FUTTERER, Hippurites cf. colliciatus WOODWARD. This rudist fauna dates the schist sequence as Santonian–Campanian. The schist sequence is overlain by a thick tectonostratigraphic pile of orthogneiss which has been interpreted as the Pan-African metamorphic core of the Menderes Massif. A widespread cataclastic and mylonitic zone is present between the underlying rudist-bearing marbles and the structurally overlying orthogneiss sequence. The existing kinematic studies in the footwall and hangingwall of this tectonic contact reveal two different phases of deformations, a contractional phase followed by an extensional phase. During the contractional event, which occurred at 36 Ma, the orthogneiss sequence was thrust faulted northwards over the schist sequence. This thrust fault was later reactivated as a low-angle normal fault beneath a supradetachment sedimentary basin of Early-Middle Miocene age. The fossil discoveries of this study and the existing kinematic studies reveal that a new structural model for the central Menderes Massif in which the tectonometamorphic units form a major southward closing recumbent fold needs to be reviewed.     

A comparison of climatological observing windows and their impact on detecting daily temperature extrema

Climatological observing window (COW) is defined as a time frame over which continuous or extreme air temperature measurements are collected. A 24-h time interval, ending at 00UTC or shifted to end at 06UTC, has been associated with difficulties in characterizing daily temperature extrema. A fixed 24-h COW used to obtain the temperature minima leads to potential misidentification due to fragmentation of “nighttime” into two subsequent nighttime periods due to the time discretization interval. The correct identification of air temperature extrema is achievable using a COW that identifies daily minimum over a single nighttime period and maximum over a single daytime period, as determined by sunrise and sunset. Due to a common absence of hourly air temperature observations, the accuracy of the mean temperature estimation is dependent on the accuracy of determination of diurnal air temperature extrema. Qualitative and quantitative criteria were used to examine the impact of the COW on detecting daily air temperature extrema. The timing of the 24-h observing window occasionally affects the determination of daily extrema through a mischaracterization of the diurnal minima and by extension can lead to errors in determining daily mean temperature. Hourly air temperature data for the time period from year 1987 to 2014, obtained from Toronto Buttonville Municipal Airport weather station, were used in analysis of COW impacts on detection of daily temperature extrema and calculation of annual temperature averages based on such extrema.     

Precipitation projections under GCMs perspective and Turkish Water Foundation (TWF) statistical downscaling model procedures

Insect outbreaks are major disturbances that affect a land area similar to that of forest fires across North America. The recent mountain pine bark beetle (D endroctonus ponderosae) outbreak and its associated blue stain fungi (Grosmannia clavigera) are impacting water partitioning processes of forests in the Rocky Mountain region as the spatially heterogeneous disturbance spreads across the landscape. Water cycling may dramatically change due to increasing spatial heterogeneity from uneven mortality. Water and energy storage within trees and soils may also decrease, due to hydraulic failure and mortality caused by blue stain fungi followed by shifts in the water budget. This forest disturbance was unique in comparison to fire or timber harvesting because water fluxes were altered before significant structural change occurred to the canopy. We investigated the impacts of bark beetles on lodgepole pine (Pinus contorta) stand and ecosystem level hydrologic processes and the resulting vertical and horizontal spatial variability in energy storage. Bark beetle-impacted stands had on average 57 % higher soil moisture, 1.5 °C higher soil temperature, and 0.8 °C higher tree bole temperature over four growing seasons compared to unimpacted stands. Seasonal latent heat flux was highly correlated with soil moisture. Thus, high mortality levels led to an increase in ecosystem level Bowen ratio as sensible heat fluxes increased yearly and latent heat fluxes varied with soil moisture levels. Decline in canopy biomass (leaf, stem, and branch) was not seen, but ground-to-atmosphere longwave radiation flux increased, as the ground surface was a larger component of the longwave radiation. Variability in soil, latent, and sensible heat flux and radiation measurements increased during the disturbance. Accounting for stand level variability in water and energy fluxes will provide a method to quantify potential drivers of ecosystem processes and services as well as lead to greater confidence in measurements for all dynamic disturbances.