Speciation of boron with Cu2+, Zn2+, Cd2+ and Pb2+ in 0.7 M KNO3 and in sea-water

The stability constants, $\text{K}{}^1{}_{\mathrm{MB}}$, for borate complexes with the ions of Cu, Pb, Cd and Zn are determined in this work by DPASV in 0.7 M KNO₃ at metal concentrations of 10^?7 M. The acidity constants of the Cu²⁺ ion are determined by DPASV in the same conditions. The following values for log $\text{K}{}^1{}_{\mathrm{MB}}$ () have been obtained: CuB: 3.48, CuB₂: 6.13, PbB: 2.20, PbB₂: 4.41, ZnB: 0.9, ZnB₂: 3.32, CdB: 1.42, and CdB₂: 2.7, while the values for the acidity constants of Cu are $\text{pK}{}^1{}_{\mathrm{CuOH}}\text{= 7.66}$ and . At the low concentration of boron in 35%. S sea-water complexes with borate represent only about 0.2% Cu, 0.03% Pb, 0.02% Zn and 0.003% Cd.     

High-resolution seismic reflection profiles for the reconstruction of postglacial transgressive shorelines: An example from Greece

In 1982 we carried out a shallow-penetration, high-resolution seismic profiling study on the shelf of the southern Argolid, Peloponnesos, Greece, to identify and map the shores of the late Pleistocene and Holocene, and to establish their coastal environments. Portable equipment and a local boat were used. The lowest glacial shore occurs at ?115 to ?118 m, within the range of global values. The subsequent rise across the distinct old land surface left behind many shore features (scaps, beaches and beach ridges, channels and lagoons) now buried under a few meters of post-transgressive deposits. These features cluster at a small number of depths below present sea level, suggesting that the rise of the sea, usually too fast to leave an imprint, was episodically interrupted by brief stillstands or even temporary reversals of climatic or tectonic origin. The clusters can be roughly dated with reference to a global sea-level-rise curve; after 6000 yr B.P. sparse archaeological data establish a local curve. The seismic profiling technique, convenient and not costly, holds promise for the identification of postglacial shores elsewhere prior to sampling for dating. It has wide application for environmental reconstructions of vanished coastal zones as a basis for prehistoric resource assessments. These applications are illustrated with examples from this study.     

Synsedimentäre Gleitschollen großen Ausmaßes im terrestrischen Jungtertiär der Karawanken

Zusammenfassung Während der Sedimentation der Rosenbacher Kohleschichten (W.Klaus 1956, Untersarmat) spielten die Karawanken als Liefergebiet der Sedimente kaum eine Rolle. Wie aus der Verbreitung dieser Sedimente im Bereich des Karawankenkörpers zu erkennen ist, wurden zumindest seine nördlichen Teile damit bedeckt. Im Hangenden dieser, aus gut gerollten, tonig sandigen Kiesen (mit hohem Quarzanteil) gebildeten Rosenbacher Kohleschichten treten dann die ersten deutlichen Einschüttungen aus den Karawanken auf. Diese deuten auf eine beginnende Heraushebung hin. Ihre Geröllzusammensetzung zeigt an, daß am Beginn dieser Entwicklung noch ein deutlicher Gerölltransport aus dem Bereich der Periadriatischen Naht über den Nordstamm der Karawanken stattfand.Die fortschreitende Heraushebung unterbrach diese Transportwege und führte zum Lösen großer Schollen von Wettersteinkalk, die nach Norden abglitten. Begünstigt wurde dieser Vorgang durch die Unterlagerung des Wettersteinkalkes durch mächtige Raibler Schiefer, die als Gleitmittel dienten.Die abgeglittenen Schollen (Tafeln bis zu 100–150 m Mächtigkeit und Längserstreckungen bis 2000 m) wurden dann in die grobklastischen Sedimente des Vorlandes konkordant eingelagert. Beide Vorgänge, Lösen und Abgleiten ins Vorland dieser Tafeln deuten auf eine rasche Hebung des Karawankenkörpers hin.Die weitere Hebung brachte dann nur noch sehr grobe Karbonatkiese, die die hangenden Anteile des grobklastischen Jungtertiärs (Bärental Konglomerat) bilden.In der weiteren Folge wurden diese Sedimente noch vom Karawankenkörper über eine kurze Strecke überschoben und auch in die fortschreitende Hebung (Ostteile) miteinbezogen.

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During the sedimentation of the Rosenbacher Kohleschichten (W.Klaus 1956, Untersarmat) the Karawanken were not so important for yielding sediments. As to be seen by the distribution of these sediments in the Karawanken area, at least its northern parts were covered by them. The top layers of the Rosenbacher Kohleschichten, consisting of clayey, sandy, well shaped gravels (with a high percentage of quartz) show first strong embankments from the Karawanken indicating a beginning uplift. Their gravel composition assigns that at the beginning of this development there was yet a transport northward from the area of the Periadriatische Naht through the Nordstamm of the Karawanken on many places.The proceeding uplift interrupted some of these spillways and lead to a discharge of large plates of Wettersteinkalk which glided northward. This procedure was favored by the thick Raibler Schiefer underlying the Wettersteinkalk and working as a lubricant.The down-glided plates (to 100–200 m thickness and a width up to 2000 m) were then embedded concordantly in the coarse clastic sediments of the forelands. Both, discharge and gliding of the plates point to a quick uplift of the Karawanken during Obersarmat.The further uplift yielded only very coarse carbonate gravels forming the top layers of the coarse clastic Young Tertiary (Bärental Konglomerat).Henceforth these sediments were overthrust by the Karawankenbody over a short distance and included in the advancing uplift (Eastern parts).

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Résumé Pendant la sédimentation des Rosenbacher Kohleschichten (W. Klaus 1956, Sarmatien inférieur) les Karawanken ne jouaient pas un grand rôle dans l'apport de sédiments. Tout au moins les sédiments couvraient-ils les pentes nord des Karawanken. Le toit des Rosenbacher Kohleschichten (formées par les graviers sableux et argileux, bien roulés, avec quartz abondant) montrent les premiers remblaiements provenant des Karawanken. Ceuxci indiquent le commencement du soulèvement des Karawanken. La composition des galets indiquent que, au commencement de ce développement, il y avait encore un transport bien marqué de galets depuis la suture périadriatique par dessus le rameau septentrional des Karawanken. Le soulèvement progressif interrompit cette voie de transport et conduisit à la séparation des grands blocaux du Wettersteinkalk, qui glissèrent vers le Nord. Ce processus était favorisé par la présence d'une puissante couche de Schistes de Raibler en-dessous du Wettersteinkalk, agissant comme lubrifiant.Puis les blocaux entraînés (des plaques de 100 à 200 m. d'épaisseur, jusqu'à 2000 m. de long), venaient s'intercaler en concordance dans les sédiments clastiques grossiers de l'avant-pays. Les deux phénomènes, séparation et glissement de ces plaques dans l'avantpays, indiquent un soulèvement rapide des Karawanken. Le soulèvement ultérieur ne délivra que de gros cailloux carbonatiques qui forment la partie supérieure du Miocène clastique (Bärentalkonglomerat).Dans la suite, ces sédiments furent chevauchés sur une courte distance par les Karawanken et impliqués aussi dans le soulèvement encore en cours (partie orientale).

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Relationship between electric currents,photospheric motions,chromospheric activity,and magnetic field topology

Through coordinated observations made during the Max'91 campaign in June 1989 in Potsdam (magnetograms), Debrecen (white light and H), and Meudon (MSDP), we follow the evolution of the sunspot group in active region NOAA 5555 for 6 days. The topology of the coronal magnetic field is investigated by using a method based on the concept of separatrices - applied previously (Mandriniet al., 1991) to a magnetic region slightly distorted by field-aligned currents. The present active region differs by having significant magnetic shear. We find that the H flare kernels and the main photospheric electric current cells are located close to the intersection of the separatrices with the chromosphere, in a linear force-free field configuration adapted to the observed shear. Sunspot motions, strong currents, isolated polarities, or intersecting separatrices are not in themselves sufficient to produce a flare. A combination of them all is required. This supports the idea that flares are due to magnetic reconnection, when flux tubes with field-aligned currents move towards the separatrix locations.     

Tidal flow asymmetry in the diurnal regime: bed-load transport and morphologic changes around the Red River Delta

The relation between tidal flow asymmetry and net transport of sediment in the semidiurnal regime has been extensively described. This study reveals that in the diurnal regime, the direction of long-term net bed-load transport and resulting morphologic changes is partly determined by the phase-angle relationship of O₁, K₁, and M₂. Simple analytical formulations of time-averaged bed-load transport were derived which separate the relative contributions of tidal asymmetry from that of residual flow with tidal stirring. In this particular case, the Red River Delta in Vietnam, transports related to tidal asymmetry are larger than those induced by the monsoon currents, and are an order of magnitude larger than those associated with topographic residual flow around the delta. Tide-induced morphologic changes dominate at water depths between 10 and 25 m, of which the patterns of erosion and deposition overlap with observed bathymetric changes. Additional observed changes that occur in more shallow water cannot be explained by tidal asymmetry and are probably related to wave action and to deposition from the buoyant river plume.Responsible Editor: Jens Kappenberg     

Forestry Projects under the Clean Development Mechanism?

Afforestation is considered an important option for mitigation of greenhousegas emissions. Recently, plantation projects have been suggested for inclusionunder the Clean Development Mechanism. While considered a cheap option,significant uncertainties make it difficult to determine the (net) carbonbenefits and profitability of forestry projects. The current uncertaintiesabout the regulatory framework of the CDM and the environmental and economicperformance of plantation forestry could create uncertainties with respect tothe additionality of such projects and thus their acceptance under themechanism.Six plantation forestry projects that were proposed in Brazil have been usedas cases to study sources of uncertainty for carbon benefits and economics forsuch projects. These cases vary widely in terms of productivity and productsdelivered. A quantitative model for calculating greenhouse gas balances andfinancial benefits and costs, taking a broad range of variables into account,was developed. Data from the developers of the proposed projects was used asmain source material. Subsequently, scenario's were evaluated, containingdifferent and realistic options for baseline vegetation, carbon creditingsystems and CDM modalities, fluctuations in product prices, discount rates andcarbon prices.The real cost of combined carbon sequestration and substitution for the caseprojects was below $3 per ton of carbon avoided, when based exclusivelyon data supplied by project developers. However, potential variations incarbon impact and costs based on scenario options were very large. Differentbaseline vegetation or adopting a different discount rate cause carbon creditsto vary by as much as an order of magnitude. Different carbon crediting systemsor fluctuations in (commodity) product prices cause variations up to200% in carbon credits and NPV. This makes the additionality of suchprojects difficult to determine. Five of the six case projects seem uneligiblefor development under the CDM. A critical attitude towards the use ofplantation projects under the CDM seems justified.     

Digital photogrammetry as a tool in analogue modelling: applications to volcano instability

Three techniques of digital photogrammetry have been applied successfully to laboratory analogue models to study surface displacements caused by various volcano deformation types. Firstly, side-perspective videos are used to differentiate profile displacements between cryptodome intrusion models and models deforming by ductile inner-core viscous flow. Both models show similar morphologic features including a bulged flank and an asymmetric upper graben. However, differences in displacement trajectories of the bulge crest reflect upward intrusion push contrasting with essentially downward displacement vectors of weak core models. The other two techniques use vertical views correlated automatically either as time-sequence monoscopic views or as coeval stereoscopic pairs. This exploits to a maximum the method’s potential by imaging surface displacements over the whole model. Successive monoscopic photograms, because they suffer only moderate numerical processing for topographic effect removal, can detect very small displacements occurring early in deformation processes. As illustrated by analysis of intrusion models, the monoscopic method allows prediction of fault locations and main displacement locations. It can also anticipate the principal strain directions, and separate different deformation stages. On the other hand, the stereo-photogrammetry technique, although more complicated, provides topography and volume changes, as well as pictures of surface displacements in three dimensions. Results are presented for the spreading of volcano models on a ductile substratum and viscous cored cones. We have found digital photogrammetry to be a useful tool for analogue modelling, because it provides quantitative data on surface displacements, including movement invisible to the eye, as well as topographic changes. It is a good method for investigating and comparing different deformation mechanisms. It is especially useful for interpretation of displacement patterns obtained from monitoring of natural active volcanoes. In fact, results of the methods used in the laboratory can be directly compared with field data from geodetic or photogrammetric surveys, as at Mount St. Helens in 1980.