Geochemical Processes Controlling the Formation of As-Rich Waters Within a Tailings Impoundment (Carnoulès, France)

The distribution of arsenic (As(III), As(V)) and iron (Fe(II), Fe(III)) species was monitored during 1 year in a borehole drilled in the Carnoulès tailings impoundment which contains As-rich pyrite. The concentrations of total As and Fe in subsurface waters exhibited strong variations over one year, which were controlled by dissolved oxygen concentrations. At high oxygen levels, extremely high As (up to 162 mM) and Fe (up to 364 mM) concentrations were reached in the borehole, with the oxidised species predominant. As and Fe concentrations decreased 10-fold under oxygen-deficient conditions, as a result of pH increase and subsequent precipitation of As(V) and Fe(III). From drill core sections, it appeared that at low dissolved oxygen levels, As(III) was primarily released into water by the oxidation of As-rich pyrite in the unsaturated zone. Subsequent As and Fe precipitation was promoted during transport to the saturated zone; this reaction resulted in As enrichments in the sediment below the water table compared to the original content in pyrite, together with the formation of As-rich (up to 35 wt% As) ferruginous material in the unsaturated zone. High amounts of As(V) were released from these secondary phases during leaching experiments with oxygenated acid sulfate-rich waters; this process is believed to contribute to As(V) enrichment in the subsurface waters of the Carnoulès tailings during periods of high dissolved oxygen level.     

Olivine xenocrysts in picritic magmas

Experimental partial melting of plagioclase lherzolite at 0.7 MPa confining pressure has produced euhedral olivine crystals by corrosion and overgrowth during cooling. The particular conditions of this experiment allow observation of both processes recorded in the crystal shape: corrosion boundaries are rounded, or straight when parallel to [001] intersection of {110} planes; (010) and {110} facets are developed by fast overgrowth during quenching. These observations support the contention that phenocrysts in basaltic or picritic magmas are, in part, xenocrysts. The possible mantle origin of olivine crystals in two natural occurrences of ultramafic magmas; the picritic pillow lavas of the Troodos, and a wehrlitic intrusion of the oman ophiolite, is investigated. In both cases discriminant characteristics are deduced from detailed microstructural study. The mantle origin of olivine megacrysts in the investigated picrites raises the question about the existence of picritic magmas in the mantle.     

Étude des spectres du signal sismique initial lors d'un tir nucléaire souterrain. Determination du coefficient d'atténuation dans le granite

Résumé A l'aide de formules empiriques, établies à partir des valeurs des amplitudes spectrales obtenues au sein d'un massif à différentes distances du point zéro et pour des tirs de puissances échelonnées, on calcule les spectres des signaux sur la surface de la sphère inélastique-élastique où l'on admet que débute le signal sismique proprement dit. Ces spectres sont d'autant plus plats que l'énergie du tir est faible. La comparaison des spectres obtenus à des distances variables permet de montrer que le coefficient d'atténuation exponentielle en fonction de la fréquence est proportionnel à celle-ci, ce qui confirme l'hypothèse de la constance du facteur de qualitéQ.Summary From the spectral amplitudes obtained at several distances from underground explosions for several values of the emitted energy, we calculate the same spectrum on the sphere where the seismic signal is supposed to begin. This spectrum becomes more flat if the energy becomes smaller. A comparison between the spectra which are obtained at several distances, shows that the exponential attenuation coefficient is proportional to the frequency. This confirms the hypothesis of a constance of the quality factorQ.     

Tectonic analysis of an oceanic transform fault zone based on fault-slip data and earthquake focal mechanisms: the Húsavík–Flatey Fault zone, Iceland

The Húsavík–Flatey Fault (HFF) is an oblique dextral transform fault, part of the Tjörnes Fracture Zone (TFZ), that connects the North Volcanic Zone of Iceland and the Kolbeinsey Ridge. We carry out stress inversion to reconstruct the paleostress fields and present-day stress fields along the Húsavík–Flatey Fault, analysing 2700 brittle tectonic data measured on the field and about 700 earthquake focal mechanisms calculated by the Icelandic Meteorological Office. This allows us to discuss the Latest Cenozoic finite deformations (from the tectonic data) as well as the present-day deformations (from the earthquake mechanisms). In both these cases, different tectonic groups are reconstructed and each of them includes several distinct stress states characterised by normal or strike-slip faulting. The stress states of a same tectonic group are related through stress permutations (σ₁−σ₂ and σ₂−σ₃ permutations as well as σ₁−σ₃ reversals). They do not reflect separate tectonic episodes. The tectonic groups derived from the geological data and the earthquake data have striking similarity and are considered to be related. The obliquity of the Húsavík–Flatey Fault implies geometric accommodation in the transform zone, resulting mainly from a dextral transtension along an ENE–WSW trend. This overall mechanism is subject to slip partitioning into two stress states: a Húsavík–Flatey Fault-perpendicular, NE–SW trending extension and a Húsavík–Flatey Fault-parallel, NW–SE trending extension. These three regimes occur in various local tectonic successions and not as a regional definite succession of tectonic events. The largest magnitude earthquakes reveal a regional stress field tightly related to the transform motion, whereas the lowest magnitude earthquakes depend on the local stress fields. The field data also reveal an early extension trending similar to the spreading vector. The focal mechanism data do not reflect this extension, which occurred earlier in the evolution of the HFF and is interpreted as a stage of structural development dominated by the rifting process.     

Cosmogenic Be dating of the Salpausselkä I Moraine in southwestern Finland

We determined in situ cosmogenic ¹⁰Be ages for nine boulders sampled on the Salpausselkä I (Ss I) Moraine. Previous dating of this moraine indicated that it formed during the Younger Dryas Stadial along the southern margin of the Scandinavian Ice Sheet in southern Finland. Our new exposure ages range from 10.9±1.0 to 13.5±1.2 ¹⁰Be ka, with an error-weighted mean age of 12.4±0.7 ¹⁰Be ka. Our results confirm four previous ¹⁰Be ages obtained 40 km northeast of our sample location. The combined data (n=13) indicate that retreat from the Ss I Moraine occurred at 12.5±0.7 ¹⁰Be ka, in excellent agreement with an age of 12.1 ka for retreat from the Ss I Moraine based on varve chronologies. These results identify the Ss I Moraine as among the best-dated margins associated with Late Quaternary ice sheets.     

Structures in the Canyon Mountain Ophiolite indicate an island-arc intrusion

Lithosphere created in an interarc basin is expected to be characterized by features distinguishing it from “normal” oceanic lithosphere. Apart from island-arc geochemical affinities and from the occurrence of hydrous high-T parageneses in the mantle and deep crustal sequences, it is expected that due to a low rate of spreading, vertical transport prevails over lateral drifting.

The Canyon Mountain complex located in an island-arc environment of Permo-Triassic age offers a remarkable illustration of these expected geological characteristics. In particular, mantle diapirism is deduced from the structural study. Smaller diapirs are formed in crustal formations. The intrusions took place at variable temperatures (1300°–800°C) and were accompanied by multistage melting in hydrous conditions.     

A conceptual hydrogeological model of ophiolite hard-rock aquifers in Oman based on a multiscale and a multidisciplinary approach

Ophiolites are found all over the world: from the Alps to the Himalayas, in Cuba, Papua-New Guinea, New Caledonia, Newfoundland, etc. They are composed of hard rocks—basalt, dolerite, gabbro and peridotite, which are formed at the mid-oceanic ridges, with specific ridge-related tectonic fracturing and intense hydrothermal alteration. Their geological and thus their hydrogeological properties differ from those of both granite or classical gabbro and classical basaltic lava. A conceptual hydrogeological model of these hard-rock aquifers was developed based on the convergent results of a multidisciplinary approach at several spatial scales, from rock-sample (centimetre) to catchment (kilometre), on well-preserved ophiolite rocks in Oman. In ophiolite rocks, groundwater circulation takes place mostly in the fissured near-surface horizon (50 m thick), and, to a lesser degree, in the tectonic fractures. Hydrograph analysis (Water Resour Res 34:233–240, 1977), interpretation of numerous pumping tests using both classical Theis and dual porosity models [Water Resour Res 32:2733–2745, 1996; Comput Geosci J (in press)], and mercury porosity and hydraulic conductivity lab-measurements support the aquifer parameter estimates. The hydraulic conductivity K of the fissured horizon is estimated at 10^–5 to 10^–6 m/s for gabbro and dolerite, and 10^–7 m/s for peridotite. The storage coefficient S of the peridotite aquifer is estimated at 10^–3 and appears to be controlled mainly by microcracks (20 to 100 m wide). Tectonic fractures in the ophiolite have similar hydrodynamic properties regardless of lithology (10^–1<T<10^–4 m²/s and 10^–1<S<10^–3) though the probability of obtaining productive wells is two to three times greater in gabbro and dolerite than in peridotite. Some of the tectonic fractures produce small hydrothermal, hyperalkaline springs in the peridotite. The water budget and hydrochemistry of the Oman ophiolite are characterized and support the conceptual hydrogeological model. Despite low annual rainfall, a relatively low hydraulic conductivity and a significant storage coefficient explain why most of the streams in peridotite are perennial.

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Résumé Les ophiolites se trouvent partout dans le monde : des Alpes à lHymalaya, à Cuba, Papouasie Nouvelle-Guinée, Nouvelle Calédonie, etc. Les ophiolites sont composées de roches dures basaltiques, de dolérites, gabbros et péridotites, qui sont formées aux rides mi-océaniques, avec, en relation avec les rides, une fracturation tectonique et une altération hydrothermale intense. Leurs propriétés géologiques et hydrogéologiques diffèrent de celles des granites ou des gabbros classiques ou des laves basaltiques classiques. Un modèle hydrogéologique conceptuel des aquifères de hard-rock a été développé sur les résultats convergents dune approche multidisciplinaire à différentes échelles spatiales, de léchantillon de roche de quelques centimètres à la taille du bassin versant en kilomètres, des ophiolites bien conservées dOman. Dans les roches ophiolitiques, la circulation des eaux souterraines est surtout localisée dans les fissures dun horizon de surface de plus dune cinquantaine de mètres et à un degré moindre dans les fractures tectoniques. Lanalyse des hydrographes (Water Resour Res 34:233–240, 1977), linterprétation des nombreux essais de pompage utilisant des modèles classiques de Theis et des modèles à double porosité (Water Resour Res 32:2733–2745, 1996; Comput Geosci J (Soumis), la porosité au mercure et la conductivité hydraulique calculée en laboratoire supportent lestimation des paramètres de laquifère. La conductivité hydraulique K de lhorizon fissuré est estimée entre 10^–5 et 10^–6 m/s pour les gabbros et les dolérites, et 10^–7 m/s pour les péridotites. Le coefficient demmagasinement S de laquifère de péridotite est estimé à 10^–3 et semble être contrôlé par les micro-fractures (20 à 100 m de largeur). Les fractures tectoniques dans les ophiolites possèdent des propriétés hydrodynamiques en regard de la lithologie (10-1<T<10-4 m²/s et 10-1/S/10-3) bien que la probabilité dobtenir des puits productifs est trois plus grand dans le grabbro et la dolérite que la péridétite. Quelques unes des fractures tectoniques produisent de petites sources hydrothermales hyperalcalines dans la péridotite. Le bilan hydrologique et hydrochimique de lophiolite dOman caractérise le modèle hydrogéologique conceptuel. Malgré des faibles précipitations annuelles, une relativement basse conductivité hydraulique et un coefficient demmagasinement significatif expliquent pourquoi la plus part des cours deau sur les péridotites ne sont jamais taris.

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Resumen Las rocas ofiolitas se encuentran en muchas partes del mundo desde los Alpes a los Himilaya, Newfoundland, Nueva Caledonia etc. Son rocas duras compuestas de basalto, dolerita, gabro y peridotita que son formadas por los cordones medio-oceánicos y por fracturación relacionada con los cordones tectónicos específicos y alteración hidrotermal intensa. La geología y los propiedades hidrogeológicas varian entre las de granito y gabro clásico y lava de basalto clásico. Se desarrolló un modelo conceptual de los acuíferos de las rocas duras Basado en los resultados convergentes de un enfoce multidisciplinario a varias escalas a partir de muestras de roca (centímetro) a cuenca kilómetro) enfocado en las rocas ofilíticas bien preservados en Oman. En las rocas ofiolíticas la circulación de agua ocurre principalmente en el horizonte de fisuras cercanas a la superficie (>50 m de espesor) y en un grado menos importante en fracturas tectónicas. Los estimados de los parámetros de estos acuíferos se basan en análisis de hidrógrafos (Water Resour Res 34:233–240, 1977), en la interpretación de pruebas de bombeo usando los modelos clásicos de Theis y de porosidad doble (Hamm y Bidaux 1996; Lods y Gouze, [en prensa]), y porosidad de mecurio y conductividad hidraúlica medida en el laboratorio. La conductividad hidraúlica K del horizonte fisurado se estima en 10E-5 a 10E-6 m-s para gabro y dolerita y 10E-7 para peridotita. El coeficiente de abastecimiento S del acuífero peridotita se estima en 10–3 y parece ser controlado principalmente por microfracturas (20 to 100 m de ancho). Las fracturas tectónicas en la ofiolita tienen propiedades hidrodinámicas similares independientes de la litología (10–1<T<10–4 m²/s and 10–1<S<10–3) pero la probabilidad de obtener pozos productivos es dos o tres veces mayor en gabro que en dolerita o peridotita. Algunas de las fracturas tectónicas producen pequeñas descargas de agua hidrotermal hiperalcalina en la peridotita. El presupuesto e hidroquímica de las ofilitas de Omán se caracteriza y apoya en el modelo conceptual hidrogeológico. La baja lluvia anual, una conductividad hidraúlica relativamente baja y un coeficiente de abastecimiento importante explican porqué la mejoría de los drenajes en peridotita es peremne.

     

Biological evidence of sea-level rise during the last 4500 years on the rocky coasts of continental southwestern France and Corsica

On the rocky coasts of the northwestern Mediterranean basin, biogenic littoral rims built by the coralline rhodophyte Lithophyllum lichenoides develop, whose remains may be preserved for millennia when submerged in a rising sea environment. These remains can be used as biological indicators of recent sea-level variations. Our survey of the continental coasts of Var and Bouches du Rhône, west of Marseilles (southern France) and of northern Corsica shows that relative sea level rose about 1.6 m in the study area during the last 4500 years without exceeding the present datum. The rate of sea-level rise was 0.4 mm per year between 4500 and 1500 yr B.P. and slowed down to 0.2 mm per year from 1500 yr B.P. to present time. There are also morphological indications of an acceleration of the rate of sea-level rise during the last century, supporting the evidence of tide gauges. Regions at the periphery of the above zone (Alpes Maritimes, Italian border zone, and the French and Spanish Catalonia regions) were also surveyed, but a weaker development of Lithophyllum rims and bad preservation of algal remains led to unconvincing dates which could also be linked to regional tectonic trends.     

The recreational use of beaches and consequences for the development of new trends in management: the case of the beaches of the Metropolitan Region of Barcelona (Catalonia, Spain)

This article offers some reflections on beach management, on the basis of the results of a survey on the recreational use of beaches and beach users' perception, which was carried out in the Metropolitan Region of Barcelona in 1992. The first part outlines the situation of the beaches, recent metropolitan beach policy and the organization of administrative bodies responsible for beach management. Survey objectives and methods are also explained briefly. In the second part, the principal results of the survey are presented and different beaches are compared in an attempt to analyse the types of users, the uses they make and the perception they have of the beaches. The conclusions identify new emerging social needs which demonstrate that new trends in beach management are also needed. Practical recommendations, related to this emerging perception of beaches as natural systems, are suggested.