The algal community at an ecocline of a cold sulphidic spring (Sovra artesian borehole,Slovenia)

The physicochemical parameters of the sulphide spring water from a 500?m deep artesian borehole in Sovra Valley (Slovenia) are stable, with very little variation: temperature, 9.2 ± 0.0 °C; pH 7.70 ± 0.11; specific electrical conductivity, 777 ± 8 μS/cm; and dissolved oxygen, 0.19 ± 0.11 mg/l. The water from the borehole is hard, rich in sulphates, and has a notable concentration of sulphide, while it is low in chlorides. Communities of phototrophs were analysed at the oxygenic ecocline at the outflow from the borehole, and from further downstream. Caloneis tenuis, Frustulla vulgaris, Gomphonema sp., Navicula radiosa, Oscillatoria sp., and Tribonema vulgare successfully thrive exclusively at the outflow from the borehole under sub-optimum conditions for the majority of phototrophs. Downstream from the borehole, where the hydrogen sulphide degasses, autotrophic biofilms were dominated by different diatoms. The Bray–Curtis similarity index confirms the distinctive phototrophic communities along the oxygenic ecocline downstream from the sulphidic spring. The sulphidic ecocline downstream from the spring is indicative of the composition of phototrophic communities, as some species appear only downstream from the spring. An ecocline downstream from the borehole of the sulphidic spring was reflected also in the bacterial indicator groups. This study brings novel insights to the limited knowledge in the field of oxygenic phototrophy related to sulphidic springs.     

Magnetic,geochemical and mineralogical properties of sediments from karstic and flysch rivers of Croatia and Slovenia

The aim of the present work was to investigate links between the low-field magnetic susceptibility (MS) and chemical and mineral composition of sediments from several Croatian and Slovenian rivers, as well as to determine possible anthropogenic influence on these sediments. MS measurements are a fast and simple method, which serves as a proxy for the estimation of pollution in different environmental systems. The investigated rivers are predominantly unpolluted rivers from Croatian and Slovenian karstic and flysch areas, which belong to the Adriatic or the Black Sea watersheds: the Dragonja, the Mirna, the Ra?a, the Ri?ana, the Reka, the Rak, the Cerkni?nica, the Unec and the Ljubljanica rivers. It was assumed that, due to their mostly unpolluted status, they could serve as a database for natural MS background values for this region. For comparison, several rivers and a lake from the Celje old metallurgic industrial area (Slovenia) were also investigated: the Savinja, the Hudinja, the Voglajna rivers and Slivni?ko Lake. They form a sub-basin of the Sava River drainage basin. Sediments of the clean karstic and flysch rivers showed extremely low MS values, with mass susceptibility values ranging from 0.58 × 10^?7 to 5.11 × 10^?7 m³/kg, and isothermal remanent magnetism (IRM) values ranging from 0.71 to 7.88 A/m. In the Celje industrial area, river sediments showed much higher MS values, with mass susceptibility values ranging from 1.31 × 10^?7 to 38.3 × 10^?7 m³/kg, and IRM values ranging from 0.91 to 100.42 A/m. The highest MS value was found in the Voglajna River at Teharje-?tore, a point which showed a significant number of anomalies of toxic metals in earlier investigations. Semiquantitative determination of relations between grain size and concentration of magnetite was performed using the Thompson-Oldfield method. X-ray diffraction (XRD) mineralogical analysis showed that sediments of the Celje area have mostly quartz as major mineral, with relatively small amount of carbonate minerals, while in sediments of karstic rivers carbonate minerals prevail. Statistically significant correlations were obtained between MS and Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd and Ba in the Slovenian karstic region and between MS and Cr, Fe, Co, Ni and Zn in flysch drainage basins. On the contrary, no correlation of MS and Hg content was obtained.     

Low permeability Neogene lithofacies in Northern Croatia as potential unconventional hydrocarbon reservoirs

We present two examples of describing low permeability Neogene clastic lithofacies to outline unconventional hydrocarbon lithofacies. Both examples were selected from the Drava Depression, the largest macrostructure of the Pannonian Basin System located in Croatia. The first example is the Beni?anci Field, the largest Croatian hydrocarbon reservoir discovered in Badenian coarse-grained clastics that consists mostly of breccia. The definition of low permeability lithofacies is related to the margins of the existing reservoir, where the reservoir lithology changed into a transitional one, which is mainly depicted by the marlitic sandstones. However, calculation of the POS (probability of success of new hydrocarbons) shows critical geological categories where probabilities are lower than those in the viable reservoir with proven reserves. Potential new hydrocarbon volumes are located in the structural margins, along the oil-water contact, with a POS of 9.375%. These potential reserves in those areas can be classified as probable. A second example was the Cremu?ina Structure, where a hydrocarbon reservoir was not proven, but where the entire structure has been transferred onto regional migration pathways. The Lower Pontian lithology is described from well logs as fine-grained sandstones with large sections of silty or marly clastics. As a result, the average porosity is low for conventional reservoir classification (10.57%). However, it is still an interesting case for consideration as a potentially unconventional reservoir, such as the ”tight” sandstones.     

Cold and warm air temperature spells during the winter and summer seasons and their impact on energy consumption in urban areas

The main objective of this study is to determine and analyze cold and warm air temperature spells in the last 6 years (2007–2012) and reveal their impact on electrical energy consumption in a small-sized city such as Sombor (Serbia) with less than 50,000 inhabitants. Hourly air temperature values and electrical energy consumption data have been used as database for all methods. Warm and cold temperature spells (during heat and cold waves) have had the increasing tendencies in the last 6 years and they reflect on additional electrical energy consumption. Detailed analysis showed that higher energy demands occur during workdays and daytime period. Monitoring of the amount of consumed energy showed a clear relationship during the winter cold temperature spells, when electrical energy demand was higher than 0.3 MW. In summer period, the relationship was weaker and consumption was higher than 0.15 MW only when temperature exceeded 30 °C. A small number of air condition devices in houses and companies and mainly one-store buildings with thick walls, which make a good insulation from the outside air temperatures, are probably the main reasons for the above-mentioned results in summer. This paper introduces a new method to resolve the problem of short-term load forecasting, based on the support vector machines (SVM) technology and particle swarm optimization that has been used to optimize the SVM parameters. Similar-day-based forecast has shown that similar days for training should be filtered also using classifier of temperature period (cooling degree-days or heating degree-days in a row). Forecasting error is smaller compared to solutions where similar days are found only on season and temperature.     

Microcrystals of Th-rich monazite (La) with a negative Ce anomaly in metadiorite and their role for documenting Cretaceous metamorphism in the Slavonian Mountains (Croatia)

Microcrystals (1–15 μm) of unusual monazite (La) with 41–47 mol% cheralite [ThCa(PO₄)₂] component and a strong negative Ce anomaly are described from a metadiorite from the SW Slavonian Mountains, Psunj, Croatia. The dioritic host rock still shows a relictic igneous fabric on macroscopic scale. However, metamorphic reaction textures can be recognized in thin section. These include partial recrystallization of igneous plagioclase to albite coupled with the formation of epidote. Furthermore, partial replacement of igneous hornblende by a fine-grained orthoamphibole-chamosite-epidote paragenesis can be observed and replacement of ilmenite by titanite. The compositions of the metamorphic minerals indicate upper greenschist facies conditions (460–500 °C according to two-feldspar geothermometry) under a high oxygen fugacity. Microstructures show that the monazite crystals belong to the metamorphic paragenesis and formed at the expense of magmatic allanite. Their negative Ce anomalies reflect the oxidizing conditions of metamorphism. Application of the xenotime in monazite solvus geothermometer provides unrealistically high temperatures of ~500–660 °C which disagree with the greenschist facies metamorphic paragenesis. We interpret that the presence of cheralite has a profound effect on the nature of the monazite-xenotime solvus curve and hence the existing calibrations of this geothermometer may be generally unsuitable for cheralite-rich monazite. An important geological result is that the Th-U-total Pb ages of the monazite grains are uniformingly Upper Cretaceous. Our data thus suggest that the imprint of the Alpine orogeny on the Slavonian Mountains was stronger than presumed until now.     

A Review of Coastal Fog Microphysics During C-FOG

Boundary-Layer Meteorology - Our goal is to provide an overview of the microphysical measurements made during the C-FOG (Toward Improving Coastal Fog Prediction) field project. In addition, we...     

Toxicity of the organophosphate pesticide diazinon to crayfish of differing age

Diazinon is a widely applied agricultural pesticide whose effect importantly on the environment and the possible contamination of surface waters has led to increased interest in toxicological studies. Crayfish, as an ecologically important benthic macroinvertebrate, seems to be an appropriate model organism for such assessments. Acute toxicity tests were carried out on three crayfish age groups: young-of-the-year (total length = 25.0 ± 4.9 mm), juvenile (total length = 56.5 ± 3.8 mm) and adult (total length = 83.5 ± 5.7 mm). Young-of-the-year crayfish were found to be the most sensitive to diazinon (96 h LC50 = 0.15 mg L^?1), followed by juvenile crayfish (96 h LC50 = 0.27 mg L^?1), and adults (96 h LC50 = 0.51 mg L^?1). Crayfish were highly sensitive to diazinon. A delayed effect of Diazinon 60EC on adults was detected (144 h LC50 = 0.44 mg L^?1) suggests functional damage from the use of sublethal concentrations.     

Initiation of Coronal Mass Ejections by Sunspot Rotation

We study a filament eruption, two-ribbon flare, and coronal mass ejection (CME) that occurred in NOAA Active Region 10898 on 6 July 2006. The filament was located South of a strong sunspot that dominated the region. In the evolution leading up to the eruption, and for some time after it, a counter-clockwise rotation of the sunspot of about 30 degrees was observed. We suggest that the rotation triggered the eruption by progressively expanding the magnetic field above the filament. To test this scenario, we study the effect of twisting the initially potential field overlying a pre-existing flux-rope, using three-dimensional zero-β MHD simulations. We first consider a relatively simple and symmetric system, and then study a more complex and asymmetric magnetic configuration, whose photospheric-flux distribution and coronal structure are guided by the observations and a potential field extrapolation. In both cases, we find that the twisting leads to the expansion of the overlying field. As a consequence of the progressively reduced magnetic tension, the flux-rope quasi-statically adapts to the changed environmental field, rising slowly. Once the tension is sufficiently reduced, a distinct second phase of evolution occurs where the flux-rope enters an unstable regime characterised by a strong acceleration. Our simulations thus suggest a new mechanism for the triggering of eruptions in the vicinity of rotating sunspots.     

A Small Pore Observed with a 1.6 m Telescope

A small pore was observed with the New Solar Telescope of 1.6 m aperture at Big Bear Solar Observatory. At a wavelength of 705.68 nm, a diffraction limit of 0.09″ was reached and approximately 700 small structures were analyzed. The achieved high resolution has revealed details about the dynamics of small structures in and around the pore. The small structures either reside in the pore, enter the pore from the vicinity, or dip in and out of the pore. Their sizes are similar, ≈?0.2″, but their observed oscillations do not show power peaks at the same periods. Horizontal plasma flows were suppressed in the pore by 38 % for average velocities, and 65 % for maximum velocities, compared to the quiet Sun.     

Period studies of classical Algol-type binaries II: UX Leo,RW Mon,EQ Ori,XZ UMa and AX Vul

This study presents an investigation of the orbital period variations of five Algol type binaries, UX Leo, RW Mon, EQ Ori, XZ UMa and AX Vul based on all available minima times. The O–C diagrams of all systems exhibit a periodic variation superimposed on a downward parabolic segment. The mass loss due to magnetic braking effect in the cooler components is assumed to account for the parabolic variation with a downward shape, while it is suggested that the light-time effect (LITE) due to an unseen component around the eclipsing binaries explains the tilted sinusoidal changes in their O–C diagrams. The orbital period decrease rates for the systems are estimated as approximately between about 0.7 and 2.5 s per century. It is clearly seen that mass loss effect is more dominant than the expected mass transfer for classical Algols in this study. The minimum mass of the probable third bodies around the eclipsing pairs was calculated to be ?0.5 M_⊙ except for UX Leo, in which it was estimated to be approximately 0.9 M_⊙. In order to search for third lights in the light curves of five systems, the V-light curves of the systems were analyzed and their physical and photometric parameters were determined. For UX Leo, a significant third light contribution was determined. We found a very small third light that can be tested using multi-color light curves, for RW Mon, EQ Ori and XZ UMa, while a third light for AX Vul could not be exposed.