高原富营养化湖泊杞麓湖微囊藻毒素分布特征、相关因子及其健康风险分析

杞麓湖作为典型的富营养化高原湖泊,其藻华暴发引发的微囊藻毒素(microcystins, MCs)污染问题会危害水生态安全并造成人体健康风险。为了评估杞麓湖流域MCs的秋冬季节污染现状以及健康风险情况,对湖内和7条主要入湖河流入湖口的表层水进行采样检测,分析MCs主要异构体的时空分布特征,研究MCs与水质和浮游植物等环境因子的关系,并通过人体非致癌健康风险评价MCs的风险等级。结果发现,MCs浓度自秋季到冬季呈下降趋势,秋季湖内胞内MCs(IMCs)占比超过99%,冬季IMCs与胞外MCs(EMCs)浓度接近。MC-RR和MC-LR是主要的MCs异构体类型,其中MC-RR在秋季浓度占比高于MC-LR和MC-YR,而冬季MC-LR最高。MCs与微囊藻密度等生物因子呈极显著正相关关系,与TN、TP和NH₃-N营养盐呈显著负相关关系。杞麓湖EMCs污染的风险指数范围为0.004~0.110,处于极低或低风险,冬季风险略高于秋季,因南岸入湖EMCs污染以及湖内IMCs释放带来的风险需要进一步关注。     

Quantifying temporal changes in Tornionjoki river ice breakup dates and spring temperatures in Lapland since 1802

Cryophenological records （i.e. observational series of freeze and breakup dates of ice） are of great importance when assessing the environmental variations in cold regions. Here we employed the extraordinarily long observational records of river ice breakup dates and air temperatures in northern Fennoscandia to examine their interrelations since 1802. Historical observations, along with modern data, comprise the informational setting for this analysis carried out using t-test. Temperature history of April-May season was used as cli- matic counterpart for the breakup timings. Both records （temperature and breakup） showed seven sub-periods during which their local means were distinctly different relative to preced- ing and subsequent sub-periods. The starting and ending years of these sub-periods oc- curred in temporal agreement. The main findings of this study are summarized as follows： （1） the synchrony between the temperature and river ice breakup records ruled out the possibility that the changes would have occurred due to quality of the historical series （i.e. inhomoge- neity problems often linked to historical time-series）; （2） the studied records agreed to show lower spring temperatures and later river ice breakups during the 19th century, in comparison to the 20th century conditions, evidencing the prevalence of cooler spring temperatures in the study region, in agreement with the concept of the Little Ice Age （1570-1900） climate in North-West Europe; （3） the most recent sub-period demonstrate the highest spring tem- peratures with concomitantly earliest river ice breakups, showing the relative warmth of the current springtime climate in the study region in the context of the past two centuries; （4） the effects of anthropogenic changes in the river environment （e.g. construction and demolition of dams） during the 20th century should be considered for non-climatic variations in the breakup records; （5） this study emphasizes the importance of multi-centurial （i.e. historical） cryo- phenological information for highly interesting viewpoints of climate and environmental his- tory.     

鄱阳湖湿地溶解性有机质的光化学属性对水体光活性中间体(PPRIs)季节性变化的影响

湿地的水文和水化学在时空尺度上会呈现显著差异,进而会引发光化学反应的变化,光活性中间体(PPRIs)是水体间接光反应的产物,具有极强的氧化性,对水环境中有机物和污染物的归驱具有重要的影响,因此迫切需要探究湿地中PPRIs的产生过程。本研究通过捕获剂法监测了鄱阳湖湿地4个季节水体中3种PPRIs(¹O₂、·OH及³CDOM^*)的产生速率和稳态浓度的变化,并通过紫外吸收光谱、三维荧光光谱、以及傅立叶变换离子回旋共振质谱等技术对水体中可溶性有机质(DOM)组分的化学特征进行分析,揭示了鄱阳湖湿地不同季节水体中的DOM的光化学反应特性及与PPRIs产生的相关性。结果发现:鄱阳湖夏季和秋季水体的pH值、溶解有机碳(DOC)浓度较高,相反,硝酸盐、亚硝酸盐浓度在夏季和秋季较低。夏季和秋季的DOM中芳香族化合物丰度较高,并且木质素丰度明显高于冬季和春季。不同季节鄱阳湖水体有色可溶性有机物产生能力依次为秋季>夏季>冬季>春季。夏季和秋季水体中¹O₂和·OH产生速率和稳态浓度显著高于春季和冬季水体。pH、DOC、E2/E3、脂类、蛋白类及木质素类与PPRIs产生速率展现出了良好的正相关关系,尤其是其中的DOC与木质素类组分;另外在三维荧光指标结果中,荧光指数(FI)和新鲜度指数(β/α)与PPRIs呈现负相关关系,证明FI值越低即DOM陆源性越高、非新生DOM比例越高,则PPRIs产生速率越高。综上,PPRIs的光化学产生与植物源DOM密切相关。与春季和冬季相比,夏季和秋季鄱阳湖水体的有机质高,而其中DOM组分中芳香族化合物丰度较高,主要来自陆生植物和土壤有机质,其有机质的腐殖化水平较高,而在春季和冬季水体有机质主要来自湖泊本身和微生物产生的有机质,属于内源。淹水植物残体降解过程释放的有机组分,对夏、秋季DOM的来源和组成有着极易被忽视的影响和作用,而其中光化学活性较强的有机组分如木质素是造成其PPRIs产率更高的主要原因。     

金沙江观音岩水库消落带绝对优势植物的表型可塑性与适应策略

金沙江是长江上游梯级大库富集之地,在金沙江地区选择典型水库开展植物表型可塑性和适应策略研究对该区一众水库生态治理具有重要的参考价值。本文以金沙江观音岩水库消落带为研究区,定量比较了经多年周期性水淹干扰后,绝对优势植物根茎叶性状的表型可塑性,分析了绝对优势植物应对主导因子的关键性状及其协同响应特征和权衡策略。结果表明:1)调查共记录了植物种类11科21属21种,优势度大于0.1的仅有狗牙根和苍耳,为绝对优势种。2)淹水对狗牙根和苍耳功能性状具有极显著影响,是二者功能性状变异的主导因子。3)狗牙根的株高、主茎长、分茎数量、主茎宽、叶片数量和叶面积,以及苍耳的分茎数量、叶片数量、根冠比和比叶面积的表型可塑性指数均超过0.6,是应对淹水的敏感性状。但是,狗牙根的叶片数量、叶面积以及苍耳的比叶面积对淹水的可塑性响应表现出短期时效性,为非适应性可塑性。4)淹水深度调控狗牙根在“逃避”策略和“静默”策略之间的权衡选择,并通过不同的性状组合以及地上和地下部分资源分配以协同响应。5)淹水导致狗牙根和苍耳的生态对策趋同,均采取S/SR策略。此外,相比于狗牙根为水库消落带的普遍推荐种,苍耳因其存在水质污染风险而褒贬不一,但苍耳具有重要的药用价值,能否在每次淹水来临前进行刈割值得进一步探讨。     

地基GPS遥感大气水汽含量及在气象上的应用

简单介绍了地基GPS遥感大气水汽含量的原理以及GPS反演水汽信息的种类,比较了两种GPS数据解算水汽策略,分析了在解算过程中影响GPS水汽精度的因子。最后简述了GPS水汽在气象上应用的进展,并提出了以后需努力的方向。     

连云港海区养殖优质条斑紫菜原因研究

根据条斑紫菜的生物学特性及不同生育期的生长、发育要求,通过对我国沿海主要海区11～4月的海温、雾、风向、降水量及雨日和海区底质状况分析,得出连云港海区养殖条斑紫菜的客观条件比其他海区优越,所养殖的条斑紫菜品质好的结论。     

基于多光谱综合的MODIS数据云检测研究

云检测是卫星遥感数据处理中不可缺少的工作。通过分析云在不同波段中的大气辐射特点，结合MODIS数据的光谱特性，提出 一种多光谱综合的云检测方法。该算法从可见光反射率、红外波段亮温值以及亮温差等方面综合考虑，逐步建立一个云检测掩模。通 过对不同时期不同背景的MODIS数据进行验证和对比分析，结果表明，该模型的云检测效果理想，尤其对可见光波段难以识别的薄卷 云也有很好效果，为有效利用MODIS数据以及进行更加精确的反演提供可靠依据。     

A double-differenced cycle slip detection and repair method for GNSS CORS network

The difficulty to detect and repair cycle slip of carrier phase measurements is a key limit for continuously high accuracy of GNSS positioning and navigation services. We propose an automated cycle slip detection and repair method for data preprocessing of a CORS network. The method jointly uses double-differenced (DD) geometry-free (GF) combination and ionospheric-free observation corrected for the computed geometrical distance (IF-OMC) to estimate the cycle slips in dual-frequency observations. The DD GF combination, which is only affected by the ionospheric residual, can be used to detect cycle slips with high reliability except for special pairs such as (77, 60) on GPS L1/L2 frequencies. The detection principle of the IF-OMC observable is such that there is a large discontinuity related to the previous epoch when cycle slips occur at the present epoch. The disadvantages of these two combinations can be overcome employing the proposed detection method. The cycle slip pair (77, 60) has no effect on the GF combination, while a change of 14.65 m is derived from GPS L1/L2 observations using the IF-OMC algorithm. Using pre-determined station coordinates as precise values, we found that the accuracy of the DD IF-OMC combination was 18 mm for a 200-km CORS baseline. Therefore, cycle slips in dual-frequency observations can be correctly and uniquely determined using DD GF and IF-OMC equations. The proposed method was verified by adding simulated cycle slips in observations collected from the CORS network under a quiet ionosphere and shown to be effective. Moreover, the method was assessed with observations made during intense ionospheric activity, which generated extensive cycle slips. The results show that the algorithm can detect and repair all cycle slips apart from two exceptions relating to long data gaps.     

Geochemistry and tectonic environment of amphiholites of the Zanhuang metamorphic complex北大核心

Amphibolites, one of the kinds of Precambrian basement rocks, are exposed in the south-middle Zanhuang Metamorphic Complex, central-south segment of the Trans-North China Orogen. These metamorphic rocks were carefully studied through field investigations and petrographical and geochemical analyses. It was found that protoliths of the Zanhuang amphibolites are calc-alkaline and tholeiitic rocks with a large range of ΣREE (41.38 × 10-6 -232.55 × 10-5 ) and weak LREE enrichment. The multi-element variation results showed that K, Rb and Ba were relatively concentrated, Nb and Ta were of evident depletion while Ti was of weak depletion. Geochemical characteristics and various relevant geochemical discrimination diagrams showed that the Zanhuang amphibolites were formed in volcanic arcs of continental margin similar to the current continental margin, which was resulted from the subduction between the Western Block and the Eastern Block.     

不同堆载形式对群桩负摩阻力的影响

在既有桥墩桩基础周围土体堆载时,会引起土体的沉降和侧向变形,进而在桩身产生负摩阻力,对桩基变形及承载性能有很大影响。为研究围载和单侧边载作用下群桩中不同位置桩基的受力差异,以3×3群桩基础为研究对象,进行围载和单侧边载作用下的模型试验,分析了不同位置桩基轴力、侧摩阻力、中性点位置和基桩承载力安全系数等的变化规律及差异。研究结果表明：围载工况下,角桩的轴力、侧摩阻力最大,边桩次之,中心桩最小;中性点位置角桩最深,边桩略高,中心桩距桩顶最近。边载工况下,靠近边载侧和中间一排桩基轴力、侧摩阻力与围载时的变化规律类似,远离边载侧的一排桩基受边载影响较小,无负摩阻力;各桩基中性点位置变化规律类似于围载工况。与围载工况相比,边载时同一位置桩身轴力、负摩阻力均较小,中性点位置较高。与单侧边载工况相比,围载时各基桩承载力安全系数FS均较小且随荷载的增大衰减梯度较大。该研究成果为不同堆载形式下群桩基础的设计提供参考。