Leaching characteristics of ash from the May 18, 1980, eruption of Mount St. Helens volcano,Washington

Leaching of freshly erupted air-fall ash, unaffected by rain, from the May 18, 1980, eruption of Mount St. Helens volcano, Washington, shows that Ca²⁺, Na⁺, Mg²⁺, SO ₄ ^2? , and Cl^? are the predominant chemical species released on first exposure of the ash to water. Extremely high correlation of Ca with SO₄ and Na with Cl in water leachates suggests the presence of CaSO₄ and NaCl salts on the ash. The amount of water soluble material on ash increases with distance from source and with the weight fraction of small (less than 63 micrometers) ash particles of high-surface area. This suggests that surface reactions such as adsorption are responsible for concentrating the soluble material. CaSO₄, NaCl, and other salts are probably formed as microscopic crystals in the high-temperature core of the eruption column and are then adsorbed by silicate ash particles. The environmentally important elements Zn, Cu, Cd, F. Pb, and Ba are released by a water leach in concentrations which could pose short-term hazards to some forms of aquatic life. However, calculated concentrations are based on a water-to-ash ratio of 4:1 or less, which is probably an underestimation of the regionally operative ratio. A subsequent leach of ash by warm alkaline solution shows dramatic increases, in the amount of dissolved SiO₂, U, and V, which are probably caused by increased dissolution of the glassy component of ash. Glass dissolution by alkaline ground water is a mechanism for providing these three elements to sedimentary traps where they may coaccumulate as uraniferous silica or U-V minerals. Leaching characteristics of ash from Mount St. Helens are comparable to characteristics of ash of similar composition from volcanoes in Guatemala. Ashes from each locality show similar ions predominating for a given leachate and similar fractions of a particular element in the ash removed on contact with the leach solution.     

Use of 234U and 238U isotopes to evaluate contamination of near-surface groundwater with uranium-mill effluent: a case study in south-central Colorado, U.S.A.

The ²³⁴U/²³⁸U alpha activity ratio (AR) was determined in 47 samples of variably uraniferous groundwater from the vicinity of a uranium mill near Cañon City, Colorado. The results illustrate that uranium isotopes can be used to determine the distribution of uranium contamination in groundwater and to indicate processes such as mixing and chemical precipitation that affect uranium concentrations. Highly to moderately contaminated groundwater samples collected from the mill site and land immediately downgradient from the mill site contain more than 100?μg/l of dissolved uranium and typically have AR values in the narrow range of 1.0–1.06. Other samples from the shallow alluvial aquifer farther downgradient from the mill contain 10–100?μg/l uranium and plot along a broad trend of increasing AR (1.06–1.46) with decreasing uranium concentration. The results are consistent with mixing of liquid mill waste (AR≈1.0) with alluvial groundwater of small, but variable, uranium concentrations and AR of 1.3–1.5. In the alluvial aquifer, the spatial distribution of wells with AR values less than 1.3 is consistent with previous estimates of the probable distribution of contamination, based on water chemistry and hydrology. Wells more distant from the area of probable contamination have AR values that are consistently greater than 1.3 and are indicative of little or no contamination. The methodology of this study can be extended usefully to similar sites of uranium mining, milling, or processing provided that local geohydrologic settings promote uranium mobility and that introduced uranium contamination is isotopically distinct from that of local groundwater.     

Precise Multibeam Acoustic Bathymetry

The maximum error in ocean depth measurement as specified by the International Hydrographic Organization is 1% for depth greater than 30m. Current acoustic multibeam bathymetric systems used for depth measurement are subject to errors from various sources which may significantly exceed this limit. The lack of sound speed profiles may be one significant source of error. Because of the limited ability of sound speed profile measurement, depth values are usually estimated using an assumed profile. If actual sound speed profiles are known, depth estimate errors can be corrected using ray-tracing methods. For depth measurements, the calculation of the location at which a sound pulse impinges on the sea bottom varies with the variation of the sound speed profile. We demonstrate that this location is almost unchanged for a family of sound speed profiles with the same surface value and the same area under them. Based on this observation, we can construct a simple constant-gradient equivalent sound speed profile to correct errors. Compared with ray-tracing methods, the equivalent sound speed profile method is more efficient. If a vertical depth is known (or independently measured), then depth correction for a multibeam system can be accomplished without knowledge of the actual sound speed profile. This leads to a new type of precise acoustic multibeam bathymetric system.     

Variability of Sea-Ice Extent in Baffin Bay over the Last Millennium

Comparison of an ice core glaciochemical time-series developed from thePenny Ice Cap (PIC), Baffin Island and monthly sea-ice extent reveals astatisticallysignificant inverse relationship between changes in Baffin Bay spring sea-iceextent andPenny Ice Cap sea-salt concentrations for the period 1901–1990 AD.Empiricalorthogonal function analysis demonstrates the joint behavior between changesin PICsea-salt concentrations, sea-ice extent, and changes in North Atlanticatmosphericcirculation. Our results suggest that sea-salt concentrations in snowpreserved on thePIC reflect local to regional springtime sea-ice coverage. The PIC sea-saltrecord/sea-ice relationship is further supported by decadal and century scalecomparisonwith other paleoclimate records of eastern Arctic climate change over the last700 years. Our sea-salt record suggests that, while the turn of the century wascharacterized bygenerally milder sea-ice conditions in Baffin Bay, the last few decades ofsea-ice extentlie within Little Ice Age variability and correspond to instrumental recordsof lowertemperatures in the Eastern Canadian Arctic over the past three decades.     

Rationale for measurement of midocean tsunami signature

Abstract

Arguments are presented to justify midocean tsunami measurements and related investigations aimed toward improvement of tsunami prediction and warning. It is postulated that midocean tsunami signatures be measured simultaneously at several locations and correlated with high‐accuracy onshore measurements.     

Precise Multibeam Acoustic Bathymetry

The maximum error in ocean depth measurement as specified by the International Hydrographic Organization is 1% for depth greater than 30m. Current acoustic multibeam bathymetric systems used for depth measurement are subject to errors from various sources which may significantly exceed this limit. The lack of sound speed profiles may be one significant source of error. Because of the limited ability of sound speed profile measurement, depth values are usually estimated using an assumed profile. If actual sound speed profiles are known, depth estimate errors can be corrected using ray-tracing methods. For depth measurements, the calculation of the location at which a sound pulse impinges on the sea bottom varies with the variation of the sound speed profile. We demonstrate that this location is almost unchanged for a family of sound speed profiles with the same surface value and the same area under them. Based on this observation, we can construct a simple constant-gradient equivalent sound speed profile to correct errors. Compared with ray-tracing methods, the equivalent sound speed profile method is more efficient. If a vertical depth is known (or independently measured), then depth correction for a multibeam system can be accomplished without knowledge of the actual sound speed profile. This leads to a new type of precise acoustic multibeam bathymetric system.     

Geologic controls on movement of produced-water releases at US geological survey research Site A,Skiatook lake,Osage county,Oklahoma

Highly saline produced water was released from multiple sources during oil field operations from 1913 to 1973 at the USGS research Site A on Skiatook Lake in northeastern Oklahoma. Two pits, designed to hold produced water and oil, were major sources for release of these fluids at the site. Produced water spills from these and other features moved downslope following topography and downdip by percolating through permeable eolian sand and colluvium, underlying permeable sandstone, and, to a lesser extent, through shales and mudstones. Saline water penetrated progressively deeper units as it moved through the gently dipping bedrock to the north and NW. A large eroded salt scar north of the pits coincides with underlying fine-grained rocks that have retained substantial concentrations of salt, causing slow revegetation. Where not eroded, thick eolian sand or permeable sandstone bedrock is near the surface, and vegetation has been little affected or has reestablished itself after the introduced salt was flushed by precipitation. The extent of salt-contaminated bedrock extends well beyond existing surface salt scars. These results indicate that one of the legacies of surface salt spills can be a volume of subsurface salinization larger than the visible surface disturbance.     

Lossless compression of hydroacoustic image data

Despite rapid progress in improving mass-storage density and digital communication system performance, compression of hydroacoustic image data is still significant in many engineering and research areas since it can overcome data storage and transmission bandwidth limitations. In this paper, we present a novel and effective approach for lossless compression of hydroacoustic image data which consists of two stages. The first stage reduces the information redundancy. We propose several new techniques to remove redundancy between data samples, data blocks, and data frames. The second stage uses a newly developed cascade coding scheme. This simple scheme can achieve an efficiency of 97%. A decomposition algorithm is presented for finding the optimal cascade coding parameters. The algorithm decomposes a multivariable optimization problem into a series of one-variable optimizations. Our two-stage algorithm offers a compression ratio of 2-3 and provides an exact recovery of the original data. Because of its simplicity, the algorithm can be incorporated into a variety of echo sounder systems. The compression algorithms can also be implemented using low-level assembly language to meet the requirements of real-time applications     

A novel array of elliptic ring radiators

An array of elliptic ring radiators is proposed which generates a fan-type beam with controllable sidelobe levels. Such an array has applications in specialized acoustic systems such as sidescan sonars, sonars for fish finding and stock assessment, obstacle avoidance systems, and others. Two possible approaches to the design are presented. One approach utilizes a mapping which transforms a radiation pattern generated by a circular ring array to that of an elliptic ring array. This approach takes advantage of methodologies developed for the design of circular ring arrays. The other approach uses the concept of an equivalent linear array. This approach benefits from existing design techniques developed for linear arrays. It requires only simple matrix operations and does not involve any optimization. The design examples presented demonstrate that a fan-type beam with sidelobes suppressed to more than 40 dB in all possible directions is achievable     

Tsunami detectability using open-ocean bottom pressure fluctuations

Rationale for the measurement of open-ocean tsunami signatures are presented, and available pertinent data are reviewed. Models for tsunami signature and background noise are proposed in order to synthesize an optimum tsunami receiver. Using these models, the minimum tsunami amplitude (in cm) to yield the probability of correct tsunami detectionP_{D} = 0.999and probability of false alarmP_{F} = 10^{-3}is found to be0.718/sqrt{f_{0}}, wheref_{0}is the tsunami dominant frequency (in cycles/h). A realizable receiver is proposed and its performance is evaluated using actual tsunami signatures. It is demonstrated that the detection of a tsunami with an average amplitude as small as 0.7 cm is possible for theP_{D}andP_{F}as above. Simulation results using synthesized background noise are shown. Tidal effects on the receiver performance also are considered and are found negligible for a certain range of the receiver parameters, resulting in a considerable reduction of the signal processing required.