在某污染的工业废物填埋场环境水文 地质评价中的同位素水文学研究

本文论述了某污染的工业废物填埋场场址的地质、水文地质条件,应用水化学方法、环境同位素技术(地下水中氚及氢、氧稳定同位素)和同位素单孔示踪技术等同位素水文学领域中的新方法对区内地下水的活动条件以及填埋场场址区分布的第四系孔隙潜水和第三纪红层孔隙-裂隙水的成因进行了分析,测量并确定了填埋场下部地下水的流速及流向。研究结果表明场区地下水的运动与地表水无直接水力联系。污染的工业废物填埋后不会通过地下水的迁移造成对地表水的污染,进而证实填埋场的地质、水文地质条件对处置污染的工业废物是安全可靠的。     

关于间接测定碘的分析方法研究

用硝基苯萃取[Cd（Phen）3]^2＋I2^-离子对,再用盐酸反萃取,利用氢化物发生-原子荧光光谱法测定镉的含量,从而间接测定碘。实验在pH=5．2的NaAc-HAc缓冲体系下进行,优化了还原剂KBH;中邻菲罗啉的浓度,镉溶液用量,萃取剂硝基苯的用量,反萃取盐酸的酸度,并制备碘的标准曲线,其线性相关系数R2≥0．9942,线性范围0～10ng／mL,精密度为8．5％,检出限0．80ng／mL,利用标准曲线测出水样中碘的浓度为17．78ng／mL,结果令人满意。实验表明,开发原子荧光光谱间接分析方法,使其能够准确测量更多种类的元素,有着十分积极的意义,同时也能够促进该方法得到更广范的应用。     

Texture Segmentation Based on Image Model and Neural Network

INTRODUCTIoNImagetextureanalysisisanimportantpartofresearchin-tocomputervision.Forobjectidentificationandunderstand-ing,textureanalysisisthebasisoftheresearchwork.Ingeneral,texturecanberegardedasakindofstructurethatconsistsofmanytextureelementsorpatternswhicharemoreorlesssimilar,i.e.,primitivesthatformtexturesandspatialdependenceorinteractionbetweentheprimitives.Ex-tensiveresearchhasbeendoneintextureanalysis,andrefer-ence(Haralick,l979)hasmadeathoroughsurvey.Amongthesetextureanalysismetho…     

Adsorption of phenanthrene on Al (oxy)hydroxides formed under the influence of tannic acid

Although there has been substantial research done on adsorption of metals/metalloids by Al (oxy)hydroxides, little is known regarding the adsorption of polyaromatic hydrocarbons (PAHs) on Al (oxy)hydroxides, especially those formed in the presence of organic acid. This paper investigated the adsorption of phenanthrene on Al (oxy)hydroxides formed with initial tannate/Al molar ratios (MRs) 0, 0.001, 0.01, and 0.1 (referred to MR0, MR0.001, MR0.01, and MR0.1, respectively) through batch adsorption experiments and FTIR study. The results showed that Al (oxy)hydroxides were important sorbents for phenanthrene. The adsorption kinetic data were fitted well with the pseudo-second-order equation. According to a modified Freundlich model, the adsorption capacities of Al (oxy)hydroxides followed a descending order of MR0.1 > MR0 ≥ MR0.01 > MR0.001, which was inconsistent with the organic carbon content in the Al (oxy)hydroxides. Adsorption capacity correlated with the specific surface area, micropore area, and micropore diameter of Al (oxy)hydroxides, yet the relationships were not statistically significant (P > 0.05). FTIR results showed that physical interaction was essential in phenanthrene adsorption onto the Al (oxy)hydroxides, which could be explained by an entropy-driven process. Surface hydrophobicity of Al (oxy)hydroxides played a key role in phenanthrene adsorption. Additional π–π electron donor–acceptor interaction of phenanthrene (acting as electron donor) with aromatic ring of tannic acid (electron acceptor) could be also important in phenanthrene adsorption by high MR Al (oxy)hydroxides, yet it needs further study. The findings obtained in the present study are of fundamental significance in understanding the mechanism of immobilization of PAHs in low organic matter but oxide-rich soils.     

Red clay deposits on the Chinese Loess Plateau during 11.0–2.6?Ma and its implications for long-term evolution of East Asian monsoon

Loess and red clay on the Chinese Loess Plateau have produced a detailed history of the East Asia monsoon for the past eight million years. Recently, a well-conserved red clay sequence was discovered at Shilou on the eastern edge of Chinese Loess Plateau, extending the monsoon history back to approximately 11 Ma. By comparing lithologic features, particle size distribution, magnetic susceptibility and deposition rate of Shilou red clay sequence, the paleomonsoon evolution from 11 to 2.6 Ma can be divided into four stages: largely fluctuated stage (11.0–8.0 Ma), relatively strengthened period (8.0–6.5 Ma), extremely changed stage (6.5–4.9 Ma) and further intensified period (4.9–2.6 Ma). The new evidence indicates that variation of paleomonsoon has close relationship with uplifting of the Tibetan Plateau and ongoing global cooling and the consequent expansion of ice sheets during 11.0–2.6 Ma.     

磺基水杨酸光度法连续测定岩石中的铁和钛

本文提出用磺基水杨酸(SSA)作显色剂,在不同pH值和同一波长下.于一分试液中连续测定铁和钛的分析方法。测定波长为420nm,测铁的pH值为8—11,Fe量在0—10μg/ml范围内服从比尔定律;测钛的pH值为2,TiO_2量在0—14μg/ml范围内服从比尔定律。     

Metallogeny of Shoshonite-Hosted Copper-Gold Deposits in Middle-South Parts of Tancheng-Lujiang Deep Fault Zone and Its Vicinity,Eastern China

ＩＮＴＲＯＤＵＣＴＩＯＮＳｈｏｓｈｏｎｉｔｅｓａｒｅｐｏｔａｓｓｉｃｉｇｎｅｏｕｓｒｏｃｋｓｗｈｉｃｈｏｃｃｕｒｍａｉｎ－ｌｙｉｎｓｕｂｄｕｃｔｉｏｎ－ｒｅｌａｔｅｄｔｅｃｔｏｎｉｃｓｅｔｔｉｎｇｓ（Ｍｏｒｒｉｓｏｎ,１９８０）．Ｔｈｅｙａｒｅｃｏｍ...     

广辟水源 高青县城区供水走出一片新天地

根据高青县城区的供水实际情况，分析开辟县城第三供水水源，实施水库连网的必要性。依据大芦湖水库的地理位置、水量及水质特点，把大芦湖水库作为高青县城理想的第三供水水源，技术可行，经济合理，从而解决城区供水矛盾。     

Deep root of a continent-continent collision belt: Evidence from the Chinese Continental Scientific Drilling (CCSD) deep borehole in the Sulu ultrahigh-pressure (HP-UHP) metamorphic terrane, China

The Chinese Continental Scientific Drilling (CCSD) deep borehole, which reached a depth of 5158 m in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, provides a new window into the deep root of a continent-continent collision belt, and the tectonic processes by which supracrustal material is recycled into the mantle by subduction and then uplifted to the surface. Major research themes of the CCSD project were to: (1) determine the three-dimensional composition, structure and geophysical character of the deep root of this orogenic belt; (2) investigate the nature and timing of the UHP metamorphism; (3) investigate the processes of crust-mantle interaction involved in the formation and exhumation of the UHP rocks; (4) study the process of fluid circulation and mineralization during subduction and exhumation; (5) study the rheological properties of the various rocks during subduction and exhumation; (6) develop and refine dynamic models for deep subduction and exhumation of crustal rocks, and (7) establish a long-term, natural laboratory for the study of present-day crustal dynamics (e.g., stress, strain, fluid activity). The CCSD has developed precise oriented profiles of the main borehole in terms of lithology, geochemistry, oxygen isotopes, zircon SHRIMP U-Pb ages, ⁴⁰Ar-³⁹Ar ages, deformation, rheology, mineralization, physical properties of the rocks, petrophysical logs, seismic reflections and underground fluids. The present paper summarizes the integrated research results of this project, especially the new findings concerning the deep root of a continent-continent collision.     

Zircon U–Pb ages and O–Nd isotopic composition of basement rocks in the North Qinling Terrain, central China: evidence for provenance and evolution

The Qinling Group was previously interpreted as the oldest Precambrian basement unit of the North Qinling Terrain, recording its formation and early crustal evolution. The Qinling Group consists predominantly of gneisses, amphibolites, and marbles, which underwent multi-phase deformation and metamorphism. In order to better constrain the provenance and tectonic setting of this group and the evolution of the North Qinling orogenic belt, in situ U–Pb dating and oxygen isotopic analysis of zircons in combination with whole-rock geochemistry and Sr–Nd isotope analysis was performed on the two dominant rock types, amphibolite and felsic gneiss. Felsic gneisses exhibit enrichment of LREEs and LILEs (Rb, Ba, Th, K, Pb), negative Eu anomalies and depletion of HFSEs (Nb, Ta, P, Ti). The rocks have slightly elevated δ¹⁸O values (6.5–9.3 ‰) and initial ε _Nd values of ?4.6 corresponding to two-stage Nd model age of 1.99 Ga. Amphibolites are also enriched in LILEs and LREEs and depleted in Nb and Ta and have homogeneous δ¹⁸O values (5.0–6.0 ‰), but higher initial ε _Nd values (2.8–3.3) and younger two-stage Nd model ages (1.29–1.24 Ga) compared to the gneisses. The zircon age record indicates that the gneisses and amphibolites were formed in a ~960 Ma volcanic arc environment rather than in a rift setting as previously suggested. A major metamorphic event took place during the Early Paleozoic. Based on the age spectrum of detrital zircons, the Qinling Group is interpreted as an autonomous geological unit, which was mainly derived mostly from 1,000 to 900 Ma old granitoid rocks. The North Qinling Terrain can be regarded as a remnant of the Grenville orogenic belt with an early Neoproterozoic evolution different from that of the North and South China blocks.