黔西地区构造变形特征及其煤层气地质意义

黔西地区处于特提斯与滨太平洋两个构造域的交接地带,多期性质不同的构造作用形成了现今错综复杂的构造变形特征。根据构造变形的差异,可划分为织金-纳雍NE向构造变形区、水城-紫云NW向构造变形区和黔西南复杂构造变形区。在野外地质的基础上,结合微观变形特征和矿物流体包裹体测试分析,认为黔西地区构造变形属于上地壳低温-中低温环境下的脆性-脆韧性变形;由于黔西地区基底构造相对稳定,成煤期后断块内部变形较弱,煤储层形成了一定程度的构造裂隙,有助于渗透率的提高,煤层气勘探开发前景良好。     

Experimental study of poromechanical behavior of saturated claystone under triaxial compression

This paper presents experimental results of drained and undrained triaxial compression tests of saturated Meuse–Haute/Marne claystone. The emphasis is to study the evolution of pore pressure with growth of microcracks and the effect of pore pressure on mechanical behavior. Basic mechanical responses are first investigated through drained triaxial compression tests, showing nonlinear stress strain relations, volumetric dilatancy and pressure sensitivity. In undrained triaxial compression tests, the pore pressure exhibits a transition from increase to decrease due to the transition from volumetric compressibility to dilatancy caused by the growth of microcracks. The failure surfaces, determined by total stress and Terzaghi’s effective stress under undrained condition, are compared with the one under drained condition.     

Spatial heterogeneity of cyanobacteria-inoculated sand dunes significantly influences artificial biological soil crusts in the Hopq Desert (China)

Artificial biological soil crusts (ABSCs), formed by inoculating Microcoleus vaginatus Gom. and Scytonema javanicum Born. et Flah. onto the topsoil of desert dunes, proved to be effective tools for the stabilization of moving dunes and promotion of soil fertility. As dominant driving forces in arid habitats, the abiotic environmental conditions of undulating dunes produce a gradient of abiotic stresses on cyanobacteria. Cyanobacteria are considered pioneering phototrophs in early soil crust communities in deserts. In this study, the development of ABSCs under various environmental site conditions was investigated using 16S rRNA-based polymerase chain reaction, denaturing gradient gel electrophoresis (DGGE), and soil property measurements. After inoculation in 2002 and long-term development, patchy moss crusts were observed on the dunes. All of the available sequenced bands in the DGGE gels belonged to Oscillatoriales and Nostocales. The dominant Nostocales genus in the ABSCs was still Scytonema; however, more Oscillatoriales genera were identified, which belonged to Microcoleus and Phormidium. The cyanobacterial compositions of different slope types were significantly distinct (p < 0.05), particularly those from windward slopes. The crusts of the top-dune slopes were more heterogeneous. In addition, the soil physicochemical properties and richness indices of the windward slopes were significantly lower than those of the leeward and interdune slopes (p < 0.05). Compared with uninoculated control dunes, all of the inoculated dunes had far higher biodiversities.     

Variation of albedo to soil moisture for sand dunes and biological soil crusts in arid desert ecosystems

Surface albedo plays a crucial role in the energy balance of soils. The surface albedo and surface soil moisture of bare sand and biological soil crusts (BSCs) were concurrently observed on field plots of shifting sand dune and in revegetated desert ecosystems at Shapotou, northwestern China, to study relationships between surface albedo, solar elevation angle, and surface soil moisture. Results indicated that rainfall exerted a remarkable lowering effect on the variation of surface albedo by increasing surface soil moisture. Surface albedo was an exponential function of solar elevation angle, and the normalized surface albedo (solar elevation angle effect was removed) decreased exponentially with the increase of surface soil moisture. Sand surface had a higher albedo (0.266) than BSCs (0.226) when the surfaces were very dry. However, sand surface albedo became increasingly lower than that of BSCs when the surfaces were in wet conditions and when the soil moisture exceeded a critical value. The changes in soil surface albedo from sand dune to BSCs after revegetation in shallow soil profiles associated with the variation of the surface soil moisture can be seen as an indicator of the degree of sand dune stabilization when compared with the original shifting sand dune soil.     

The effect of desertification on carbon and nitrogen status in the northeastern margin of the Qinghai-Tibetan Plateau

Environmental degradation resulting from desertification often accelerates biodiversity loss and alters carbon (C) and nitrogen (N) stocks within grassland ecosystem. In order to evaluate the effect of desertification on plant diversity and carbon (C) and nitrogen (N) stocks, species compositions and C and N contents in plants and soil were investigated along five regions with different degrees of desertification in the northeastern margin of the Qinghai-Tibetan Plateau (control, light, moderate, severe and very severe stages). The study showed: (1) species composition and richness changed significantly with the development of grassland desertification; (2) the aboveground biomass C and N contents in the control were 101.60 and 4.03 g m^?2, respectively. Compared to the control, the aboveground tissue C and N contents significantly decreased from light, moderate, severe to very severe stages. (3) The root C and N contents in the control in 0–40 cm depth are 1,372.83 and 31.49 g m^?2, respectively, while the root C and N contents in 0–40 cm were also declining from the control, light, moderate, severe to very severe stages. (4) Compared to the plant, the soil made a greater contribution for C and N distribution, in which the soil organic C and total N contents in 0–40 cm depth in the control are 20,386.70 and 3,587.89 g m^?2, respectively. At the same time, soil organic C and N contents also decreased significantly from the control to very severe stages. These results suggest that grassland desertification not only alters species compositions and leads to the loss of plant diversity, but also results in greater loss of organic C and N in alpine meadow, in which there is a negative effect on reducing greenhouse gas emission.     

Field experiments and numerical simulations of whirlpool foundation pit dewatering

A whirlpool foundation pit is a small-diameter, deep circular pit. Because of its depth and small diameter, a large drawdown is required, and a limited number of wells can be installed inside the pit. During excavation, partially penetrating wells inside and outside the foundation pit have to be installed to lower the water level when the aquifer is too thick. However, partially penetrating wells near partially penetrating curtains cannot be treated by analytical methods. Therefore, it is necessary to use numerical methods to predict dewatering during excavation. Field experiments were performed on whirlpool foundation pit 1880 of Baosteel Group, Shanghai, China, to obtain pumping rates and drawdown, pumping with a single well and two wells in the confined aquifer. The results indicate that the drawdown inside the pit induced by pumping wells outside the foundation pit was small, whereas it was large for pumping wells inside the pit. The pumping wells inside and outside the pit had to be combined to lower the water level. A three-dimensional numerical model was developed to simulate the dewatering process. The hydraulic conductivities of the confined aquifers were inversed by using the pumping tests. Operation schedules were simulated with the corrected model for different combinations of wells inside and outside the pit. The results suggest that different schedules and operation conditions affect drawdown. The monitored results during dewatering indicate that the simulation and field measurements were in agreement. The results can be applied to similar situations.     

Accumulation and ecological effects of soil heavy metals in conventional and organic greenhouse vegetable production systems in Nanjing,China

The spatial variability of soil heavy metals in conventional and organic greenhouse vegetable production (CGVP and OGVP) systems can reveal the influence of different farming activities on their accumulation and plant uptake. This provides important basic data for soil utilization and pollution risk assessment. Based on horizontal and vertical spatial analysis, this paper presents the spatial variability and accumulation of soil heavy metals. The effects on plant uptake and factors influencing heavy metal accumulation are presented using the two typical greenhouse vegetable sites in Nanjing City, China as examples. Results showed that different greenhouse vegetable production systems had their own dominant heavy metal accumulation, specifically, Hg and Pb in CGVP system and Cd in OGVP system. The spatial analysis showed that horizontally, distribution of soil properties and heavy metal concentrations in the two sites showed decreases from specific regions to the periphery for organic matter (OM), Cd, Cu, Hg, Pb, and Zn in CGVP and OM, As, Cd, Cu, Hg, Pb, and Zn in OGVP. Vertically, soil properties and heavy metals mainly vary in the topsoil. The key factor for the accumulation was excess fertilizer input. Variation of soil properties and the accumulation of soil heavy metals significantly influenced heavy metal uptake by plants. However, accumulation risk varied according to different heavy metals and different plant species. Environmental management of these two kinds of production systems should pay more attention to fertilizer application, plant selection, and soil properties.     

Experimental research on expansion characteristics of Mengzi expansive soil with water,salt and acid immersion

Swelling tests of Mengzi remolded expansive soil inundated with different types of wetting fluids (distilled water, saline water and acidic water) were carried out using advanced consolidometer. Swelling characteristics of expansive soil under different initial conditions were studied. The dose–response model was used to fit the rules of swelling time interval for expansive soil with water immersion. The quantitative relationships between the swelling deformation and initial conditions (initial water content, initial dry density and overburden pressure) were attained using 3D regression analyses. The differences in deformation rules of expansive soil with water immersion in each region are bigger for the differences of genetic types, mineral compositions, chemical characteristics of soils and sample preparation techniques and instrument error. The expansion deformation rules of soil immersed in salt and acid solution are the same as the rules of soaked soil. The important indices obtained can be provided to the engineering design, construction and stability evaluation of expansive soil slopes.     

Fluoride and arsenic hydrogeochemistry of groundwater at Yuncheng basin,Northern China

High fluoride and arsenic concentrations in groundwater have led to serious health problems to local inhabitants at Yuncheng basin, Northern China. In this study, groundwater with high fluoride and arsenic concentration at Yuncheng basin was investigated. A majority of the samples (over 60%) belong to HCO₃ type water. The predominant water type for the shallow groundwater collected from southern and eastern mountain areas was Ca/Mg-Ca-HCO₃ types. For the shallow groundwater from flow through and discharge area it is Na-HCO₃/SO₄-Cl/SO₄/Cl type. The predominant water type for the intermediate and deep groundwater is of Na/Ca/Mg-Ca-HCO₃ type. According to our field investigation, fluoride concentration in groundwater ranges between 0.31 and 14.2 mg/L, and arsenic concentration ranges between 0.243 and 153.7 μg/L. Out of seventy collected groundwater samples, there are 31 samples that exceed the World Health Organization (WHO) standard of 1.5 mg/L for fluoride, and 15 samples exceeds the WHO standard of 10 μg/L for arsenic. Over 40% of high fluoride and arsenic groundwater are related to the Na-HCO₃ type water, and the other fifty percent associated with Na-SO₄-Cl/HCO₃-SO₄-Cl type water; little relation was found in calcium bicarbonate type water. A moderate positive correlation between fluoride and arsenic with pH were found in this study. It is due to the pH-dependent adsorption characteristics of F and As onto the oxide surfaces in the sediments. The observed negative correlation between fluoride and calcium could stem from the dissolution equilibrium of fluorite. The high concentration of bicarbonate in groundwater can serve as a powerful competitor and lead to the enrichment of fluoride and arsenic in groundwater. Most of the groundwater with high fluoride or arsenic content has nitrate content about or over 10 mg/L which, together with the observed positive correlations between nitrate and fluoride/arsenic, are indicative of common source of manmade pollution and of prevailing condition of leaching in the study area.     

Kiel Ⅳ-IRMS双路在线分析微量碳酸盐的碳氧同位素

石笋能重建百年、十年的气候事件,为达到空间高分辨率,对微量碳酸盐的检测提出了更高要求,传统磷酸酸解法的样品用量大(约10 mg)已经无法满足微量样品的分析,而激光探针质谱分析方法需对检测结果进行校正。本文采用KielⅣ-IRMS双路在线分析技术对微量碳酸盐样品的碳、氧同位素进行检测研究其可行性,并以GBW 04405和NBS 19为例研究了不同样品量的碳酸盐标准样品在不同反应时间对同位素分馏的影响。结果表明,由于标准样品所需的反应时间不同,从而导致同位素分馏值的差异。对样品量为4~85μg的标准样品GBW 04405进行检测,δ13C、δ18O测量值分别为0.574‰±0.027‰、-8.519‰±0.065‰,与推荐值0.57‰±0.03‰、-8.49‰±0.14‰基本一致,表明该方法能够满足微量碳酸盐测试的要求。将KielⅣ-IRMS双路在线分析技术与GasbenchⅡ-IRMS检测方法进行对比,对于标准样品GBW 04405,KielⅣ-IRMS所用样品量约为50μg,δ13C、δ18O测量值分别为0.576‰±0.012‰、-8.501‰±0.050‰,GasbenchⅡ-IRMS所用样品量约为140μg,δ13C、δ18O测量值分别为0.569‰±0.034‰、-8.590‰±0.099‰。表明KielⅣ-IRMS方法相比于GasbenchⅡ-IRMS方法所需样品量少,精度高,结果重现性好,该方法在碳酸盐样品的应用上能达到空间高分辨率。