Synthesis and characterisation of a multifunctional oil-based drilling fluid additive

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.     

A GIS-based method of risk assessment on no. 11 coal-floor water inrush from Ordovician limestone in Hancheng mining area,China

The no. 11 coal seam in the deep area of Hancheng mining area is mining in recent years, which is threatened by the water inrush from the Ordovician limestone aquifer. Coal-floor water inrush is governed by the water abundance of coal-floor aquifer, the water-resisting performance of coal-floor aquitard, and the pathway connecting the water source and the working face. To make an accuracy risk assessment of water inrush from the no. 11 coal seam floor, a GIS-based vulnerability index method (VIM) is adopted for its superior comprehensive consideration of more controlling factors, powerful spatial analysis, and intuitively display functions. This study firstly established an index system including the water pressure of the coal-floor aquifer, the unit water inflow, the thickness, the core recovery percentage, the thickness ratio of brittle rocks to ductile rocks, the thickness of effective aquitard, and the accumulated length of faults and folds, of which the former six indexes governed the water abundance of the coal-floor aquifer which was combined with the last two factors to determine the risk of coal-floor water inrush. Secondly, the thematic map of each controlling factor is established by GIS using the geological prospecting data, and the weight of each factor is determined by the analytic hierarchy process (AHP) after consulting the expert review panel. At last, a vulnerability index is obtained and used to assess the risk of coal-floor water inrush of the no. 11 coal seam. The risk of water inrush of the no. 11 coal seam of the study area was ranked to three zones: the southeastern shallow area in red color is the dangerous zone, the wide northwestern area in green color is the safe zone, and the transition area in yellow color is the moderate-risk zone. Compared with the actual water-inrush incidents, the risk assessment result was verified to achieve an accuracy of 82.35%, which is proved to be a dependable reference for the prevention and controlling of coal-floor water inrush of the no. 11 coal seam in Hancheng mining area.     

渝东北城口地区Y1井页岩有机地球化学特征及勘探前景

基于钻井资料,以总有机碳(TOC)、干酪根显微组分、等效镜质体反射率(Ro)及碳同位素等测试数据系统分析了渝东北城口地区Y1井五峰组—龙马溪组页岩的有机地球化学特征,利用页岩流体包裹体的显微特征、均一温度及激光拉曼数据深入分析了Y1井页岩气成藏特征。结果表明:Y1井上奥陶统五峰组—下志留统龙马溪组炭质页岩发育,TOC含量2%的富含有机质页岩厚度达83 m,干酪根类型以Ⅰ型干酪根为主,处于湿气生烃阶段。页岩裂缝脉体中大量烃包裹体和富含甲烷气体的含烃盐水包裹体证实城口地区五峰组—龙马溪组页岩发生了充足页岩气供给,具有高均一温度、高盐度的伴生盐水包裹体表明城口地区页岩气成藏时期的保存条件良好。这些Y1井页岩有机地球化学特征研究成果揭示了城口地区下古生界具备良好的页岩气勘探前景。     

中国阿尔泰契巴罗依北奥陶纪基性岩锆石U-Pb年龄、成因及其地质意义

中国阿尔泰山位于西伯利亚板块南缘,其内发育较为频繁的古生代侵入岩浆活动,为研究中亚造山带地壳增生的理想窗口。本文通过对北阿尔泰地区西段契巴罗依北基性岩体的岩相学、锆石LA-ICP-MS U-Pb测年及岩石地球化学数据进行研究,探讨该岩体就位的大地构造背景和成因机制,为研究区域构造演化提供了新资料。契巴罗依北基性岩体包括细粒辉长岩、角闪辉长岩、角闪苏长岩、细粒苏长岩等不同岩相,本次获得角闪辉长岩锆石U-Pb年龄为470.6±4.3Ma,首次确认在北阿尔泰造山带发育中奥陶世基性侵入岩。根据区域岩浆岩年代学及地质特征,结合契巴罗依北基性岩体岩石地球化学数据分析,认为该期基性岩浆可能形成于大陆板块边缘的弧后伸展环境,源于早古生代古亚洲洋向北俯冲,深部地幔发生板片断离导致软流圈地幔与上覆交代地幔相互作用后沿弧后伸展环境下的薄弱地带上侵就位     

Interpersonal communication sources and natural hazard risk perception: a case study of a rural Chinese village

This exploratory study contributes to our knowledge about the relationships between interpersonal communication sources and risk perception regarding natural hazards. Survey data (N?=?186) from a small village in northwest China was used, and the correlations between eight types of interpersonal communication sources related to disaster risk reduction and the perceived severity and perceived likelihood of occurrence of eight types of natural hazards were explored. Past studies have suggested that interpersonal communication sources are more likely to influence individuals in their perceived severity of natural hazards than in their perceived likelihood of occurrence. The results of this study moderately corroborate this finding. The results indicated that different sources have different relationships to risk perception, as positive correlations were found between obtaining information via certain trained science professionals (science teachers, emergency responders, scientific experts) and certain natural hazard risk perceptions, while negative relationships were found between obtaining information via certain personal contacts (other villagers and relatives and friends) and certain natural hazard risk perceptions. However, the strength of these relationships was weak (??0.197?≥?r?≤? 0.245). Age showed statically significant correlations with the perceived severity of most of the natural hazards. Studies with more representative samples and controls for theoretical factors are needed to better understand how interpersonal communication sources affect individuals' natural hazard risk perceptions.     

地理国情普查成果在土地资源监测中的应用初探

以江西省某县地理国情普查数据为基础,研究其与土地变更调查数据的相似性与差异性,结合土地资源监测的热点,初步探究地理国情普查成果在土地资源监测中应用,为地理国情普查成果应用提供思路与方向。     

城市轨道交通勘测大数据的集成与应用

正近年来,三维可视化技术日趋发展成熟,倾斜摄影技术、三维激光扫描技术等测绘新技术以及国内BIM技术的全面推广使用,使得建筑行业正在由二维设计建造向三维设计建造转变。由于城市轨道交通多建造在城市地下空间,与地上建筑相比,其在设计建造过程中面临着地下周边环境不可直观展示的困境,其更加迫切需要三维可视化技术来辅助地铁规划设计与建造施工。地质信息复杂多变,     

基于优化经验模态分解和聚类分析的滑坡位移智能预测研究

针对三峡库区"阶跃式"滑坡的变形特征,提出了一种新的滑坡位移预测方法。以白水河滑坡ZG118和XD-01监测点位移数据为例,采用基于软筛分停止准则的经验模态分解(SSSC-EMD)将累计位移-时间曲线和影响因子时间序列自适应地分解为多个固有模态函数(IMF),并采用K均值(K-Means)聚类法对其进行聚类累加,得到有物理含义的位移分量(趋势性位移、周期性位移以及随机性位移)和影响因子分量(高频影响因子和低频影响因子)。使用最小二乘法对趋势性位移进行拟合预测;采用果蝇优化-最小二乘支持向量机(FOA-LSSVM)模型对周期性位移和随机性位移进行预测。将各位移分量预测值进行叠加处理,实现滑坡累计位移的预测。研究结果表明,所提出的(SSSC-EMD)-K-Means-(FOA-LSSVM)模型能够预测"阶跃式"滑坡的位移变化规律,且预测精度高于传统的支持向量机回归(SVR)、最小二乘支持向量机(LSSVM)模型;并通过改变训练集长度,进行单因素分析,发现其与预测精度之间呈正相关关系。     

U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.