Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

鄂尔多斯盆地南部的黄土塬区地震资料处理与解释,第一部分:地震资料处理

Branching river channels and the coexistence of valleys, ridges, hiils, and slopes＇as the result of long-term weathering and erosion form the unique loess topography. The Changqing Geophysical Company, working in these complex conditions, has established a suite of technologies for high-fidelity processing and fine interpretation of seismic data. This article introduces the processes involved in the data processing and interpretation and illustrates the results.     

Converted-wave seismology in anisotropic media revisited,Part I: Basic theory

We have developed new basic theories for calculating the conversion point and the travel time of the P-SV converted wave (C-wave) in anisotropic, inhomogeneous media. This enables the use of conventional procedures such as semblance analysis, Dix-type model building and Kirchhoff summation, to implement anisotropic processing, and makes anisotropic processing affordable. Here we present these new developments in two parts: basic theory and application to velocity analysis and parameter estimation. This part deals with the basic theory, including both conversion-point calculation and moveout analysis. Existing equations for calculating the PS-wave (C-wave) conversion point in layered media with vertical transverse isotropy (VTI) are strictly limited to offsets about half the reflector depth (an offset-depth ratio, xlz, of 0.5), and those for calculating the C-wave traveltimes are limited to offsets equal to the reflector depth (x/z=l.0). In contrast, the new equations for calculating the conversion-point extend into offsets about three-times the reflector depth (x/z=3.0), those for calculating the C-wave traveltimes extend into offsets twice the reflector depth (x/z=2.0). With the improved accuracy, the equations can help in C-wave data processing and parameter estimation in anisotropic, inhomogeneous media. This work is funded by the Edinburgh Anisotropy Project (EAP) of the British Geological Survey. First author: Xiangyang Li, Mr. Li is currently a professorial research seismologist (Grade 6) and technical director of the Edinburgh Anisotropy Project in the British Geological Survey. He also holds a honorary professorship in multicomponent seismology at the School of Geosciences, University of Edinburgh. He received his BSc(1982) in Geophysics from Changchun Geological Institute, China, an MSc (1984) in applied geophysics from East China Petroleum Institute (now known as the China University of Petroleum), and a PhD (1992) in seismology from the University of Edinburgh. During 1984–1987, he worked as a lecturer with the East China Petroleum Institute. Since 1991, he has been employed by the British Geological Survey. His research interests include seismic anisotropy and multicomponent seismology.     

Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.     

Observed Evolution of Linear and Nonlinear Effects at the Dahan Downhole Array,Taiwan: Analysis of the September 21, 1999 M 7.3 Chi-Chi Earthquake Sequence

— In this paper, the site characteristics of the Dahan downhole array are studied by analyzing the September 21, 1999 M 7.3 Chi-Chi earthquake sequence including the main shock and some aftershocks. The four-level array (0 m, 50 m, 100 m and 200 m) is located to the north of Hualien City in eastern Taiwan. Polarization analysis is used to check the orientation errors of the seismometers at different levels of depth. If the surface instrument is chosen as reference, the angle between the major polarization axes of the surface and any downhole records is the orientation error that must be corrected for the downhole accelerographs. The orientation errors at depths of 50 m, 100 m and 200 m are 32°, 120° and –84°. After the corrections, the coherency between the surface and downhole records is substantially improved. Spectral ratio analysis shows that the predominant frequency of the Chi-Chi main shock shifts to a lower frequency. We also simulate ground motions at different depths by using the Haskell method with a linear velocity structure model. The record at surface is chosen as the input motion. Compared with the observed data, ground acceleration can be well reproduced for the aftershocks (weak-motion events) of the September 21, 1999 M 7.3 Chi-Chi earthquake. However, for the Chi-Chi main shock, the synthetic waveform cannot match well with the observation neither in amplitude nor in phase. This indicates that large ground shaking probably induced the nonlinear site effect at that time, and the model used cannot support it.Acknowledgement. The authors would like to express their thanks to Dr. L.F. Bonilla and one anonymous reviewer for their valuable suggestions. This research was supported by the National Science Council under grant number NSC 89-2921-M-194-007. The Institute of Earth Sciences, Academia Sinica supplied the strong-motion data. The support of these organizations is gratefully acknowledged.     

东北地区矿业开发态势与矿山环境地质问题综合研究

在论述东北地区矿业开发态势的同时,阐述了区内能源矿产、金属矿产及非金属矿产开采引发的主要环境地质问题,针对区内复杂的矿山环境地质问题现状,提出了开展东北地区矿山环境地质综合研究问题的工作思路.     

石灰改良膨胀土力学性质的研究

膨胀(?)主要是由强亲水性粘土矿物蒙脱石和伊利石组成的,是具有膨胀性、多裂隙性和超固结性的高塑性粘性土。在铁路施工中,膨胀土不能直接作为路基填土,必需进行改良。通过室内试验的方法来讨论石灰改良膨胀土的力学性质在各种影响因素下的变化规律。     

The mechanisms of paragenesis and separation of silver, lead and zinc in hydrothermal solutions

On the basis of an experimental study and thermodynamic calculation, the mechanisms of paragenesis and separation of silver, lead and zinc in the hydrothermal system have been studied. At acidic to nearly neutral pH, their chloride complexes are stable, and among them the chloride complexes of zinc are most stable. And the sulfide complexes are the dominant species at nearly neutral to alkaline pH,while the sulfide complexes of silver are most stable. With decreasing temperature, [ Cl^-] ,fO2, and increasing pH, the solubilities of silver, lead and zinc will decrease, leading to their deposition and separation. For sulfide complexes, the concentrations of reduced sulfur and pH are two important factors affecting their stabilities. Complexes of different forms and stabilities respond to the variation of conditions to different extents, which gave rise to the paragenesis and separation of silver, lead and zinc in the whole ore-forming process of dissolution, transport and deposition.     

An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

The effects of land use on runoff and soil nutrient losses in a gully catchment of the hilly areas： implications for erosion control

1 Introduction Soiland waterlossisoneofthe worldwide environm entalissuesthreatening sustainable land use in semiarid areas.However,soiland water loss is highly variable in space and time,and its variability resultsfrom m any factorsoperating ata wide ran…