Mantle Degassing and Diamond Genesis：A Carbon Isotope Perspective

The effect of Co2 and CH4 degassing from the mantle on the carbon isotopic composition of diamond has been quantitatively modeled in terms of the principles of Rayleigh distillation.Assuming the δ^13 C value of -5‰ for the mantle,the outgassing of CO2 can result in the large negative δ^13 C values of diamond,whereas the outgassing of CH4 can drive the δ^13C values of diamond in the positive direction.The theoretical expectations can be used to explain the full range of δ^13 C values from-34.4‰5 to 5‰ observed for natural diamonds.It is possible that diamond formation was triggered by the degassing of Co2 and/or CH4 from the mantle and the associated fractional crystallization of carbonate-bearing melt.     

High Pressure-Differential Thermal Analysis and Ultrasonic Wave Amplitude Analysis of Ice-Water Equilibrium at 1.5-5.0GPa

Water is the most active component in all geological systems.It has an important effect on the physical properties of minerals and melts.It also plays a key role in the evolution of the Earth.Accurate thermodynamics data on water are currently confined to pressures below 1.0GPa and temperatures below 900℃.Presented in this paper are new data available on the P-T properties of water at pressures up to 5.0GPa,develoged from differential thermal analysis and ultrasonic wave amplitude analysis.It has been found that there may exist another ternary point at 3.0GPa and that ultrasonic wave amplitude change of ice-water transition shows two inflection points above 2.0GPa, consistent with the two peaks of differential thermal curves above 2.0GPa .It may be a new phenomenon which needs further study.     

用水氡最大变化率法对强震时间作中短期预报

介绍了水氡变化率的物理含义以及变化率动态图象的生成方法,强震前在动态图象上存在着变化率≥０．０６高值异常区,异常区中心的最大变化率随时间有规律地演化,且与发震时间有着良好的统计关系。据此提出４个时间预测指标。检验性预测结果表明,预测的发震时间段长短大多数为２至６个月,可满足强震的中短期预报尺度的需要。     

华北联网数据采集与处理系统的建设

为实现遥测台网模拟系统向数字化系统的平稳过渡 ,提高速报速度 ,华北联网使数据采集与处理系统 (DAPS)纳入了同一技术系统轨道。在系统建设、运行与维护上 ,以及数据产出、数据服务等方面已初具规模 ,并在华北联网各台网发挥作用。     

长乐-南澳构造带白垩纪“片麻状”浆混杂岩的成岩机制研究——以泉州肖厝岩体为例

闽东南长乐南澳构造带沿线出露大面积白垩纪花岗岩岩基,普遍存在岩浆混合现象,肖厝侵入岩是其中的代表性岩体.野外观察和化学分析表明,肖厝侵入岩由二长花岗岩和辉长闪长岩、以及该两种混合端员岩浆混合形成的闪长质-花岗闪长质-花岗质过渡岩类组成;岩石总体富碱、富LREE和LILE、贫HFSE; A/CNK=0.82～1.05,属准铝质微过铝质钙碱性系列,部分受流体交代的岩石A/CNK值可升高至1.69;岩浆混合过程中发生了元素的选择性富集/亏损和同位素组成的均一化,（87Sr/86Sr）为0.7055～0.7061,εNd（t）为-1.9～-3.0.锆石年代学研究表明,肖厝侵入岩的岩浆混合开始于约136Ma,于121Ma时初始侵位于下地壳.结合区域地质特征,分析了肖厝侵入岩的成岩机制,提出岩体侵位早于长乐-南澳构造带的变质变形作用,两者不存在成因上的联系;118～～100Ma时该构造带曾发生过深层次地壳逆冲推覆,使形成于中—下地壳的韧性剪切带和肖厝侵入岩共同快速上升至地表.     

Investigation of Small‐Scale Preferential Flow with a Forced‐Gradient Tracer Test

A new tracer experiment (referred to as MADE‐5) was conducted at the well‐known Macrodispersion Experiment (MADE) site to investigate the influence of small‐scale mass‐transfer and dispersion processes on well‐to‐well transport. The test was performed under dipole forced‐gradient flow conditions and concentrations were monitored in an extraction well and in two multilevel sampler (MLS) wells located at 6, 1.5, and 3.75 m from the source, respectively. The shape of the breakthrough curve (BTC) measured at the extraction well is strongly asymmetric showing a rapidly arriving peak and an extensive late‐time tail. The BTCs measured at seven different depths in the two MLSs are radically different from one another in terms of shape, arrival times, and magnitude of the concentration peaks. All of these characteristics indicate the presence of a complex network of preferential flow pathways controlling solute transport at the test site. Field‐experimental data were also used to evaluate two transport models: a stochastic advection‐dispersion model (ADM) based on conditional multivariate Gaussian realizations of the hydraulic conductivity field and a dual‐domain single‐rate (DDSR) mass‐transfer model based on a deterministic reconstruction of the aquifer heterogeneity. Unlike the stochastic ADM realizations, the DDSR accurately predicted the magnitude of the concentration peak and its arrival time (within a 1.5% error). For the multilevel BTCs between the injection and extraction wells, neither model reproduced the observed values, indicating that a high‐resolution characterization of the aquifer heterogeneity at the subdecimeter scale would be needed to fully capture 3D transport details.     

李口集区块煤储层地质条件及煤层气采收率

基于煤田勘探资料和矿井实际观测结果,结合测试分析和数值计算,对平顶山矿区李口集区块煤储层地质条件进行了研究。结果表明：区块内主煤层的煤体结构破坏严重,小型裂隙发育但连通性较差,含气量中等且属于低压煤储层,煤层气采收率偏低,地面原位开采的难度较大。为此,建议该区块的煤层气开发以矿井抽采为主,并在煤矿采动带和采空区辅以合理的地面抽采工程。     

二维视电阻率断面的快速最小二乘反演

快速最小二乘反演是以平滑限定的最小二乘方法为基础,是对二维视电阻率断面进行反演的一种方法。反演过程不需要提供初始模型,在首次迭代时使用一均匀介质地下模型作为初始模型,该模型的视电阻率偏导数值可以用解析法得到。在后面的迭代中,使用了拟牛顿法去修改每一次迭代的偏导数矩阵,避免了偏导数矩阵的直接计算,从而减少了计算时间和存储空间。同时运用牛顿矩阵校正技术解最小二乘方程组也减少了大量的计算时间。总之,该方     

地球化学反应模型的发展及其应用

根据近年来地球化学反应模型的发展及其应用现状，对新发展的建模方法手段、模型计划方法以及模型计算软件作了简要的归纳和评述，最后以地球化学反应模型用于成矿动力学研究的应用为例，说明地球化学反应模型在地球化学研究中，对了解反应体系中物质的形态，分布、迁移和转化，起着重要的作用。     

Zircon U–Pb ages, Hf and O isotopes constrain the crustal architecture of the ultrahigh-pressure Dabie orogen in China

The crustal structure of the Dabie orogen was reconstructed by a combined study of U–Pb ages, Hf and O isotope compositions of zircons from granitic gneiss from North Dabie, the largest lithotectonic unit in the orogen. The results were deciphered from metamorphic history to protolith origin with respect to continental subduction and exhumation. Zircon U–Pb dating provides consistent ages of 751 ± 7 Ma for protolith crystallization, and two group ages of 213 ± 4 to 245 ± 17 Ma and 126 ± 4 to 131 ± 36 Ma for regional metamorphism. Majority of zircon Hf isotope analyses displays negative ε_Hf(t) values of − 5.1 to − 2.9 with crust Hf model ages of 1.84 to 1.99 Ga, indicating protolith origin from reworking of middle Paleoproterozoic crust. The remaining analyses exhibit positive ε_Hf(t) values of 5.3 to 14.5 with mantle Hf model ages of 0.74 to 1.11 Ga, suggesting prompt reworking of Late Mesoproterozoic to Early Neoproterozoic juvenile crust. Zircon O isotope analyses yield δ¹⁸O values of − 3.26 to 2.79‰, indicating differential involvement of meteoric water in protolith magma by remelting of hydrothermally altered low δ¹⁸O rocks. North Dabie shares the same age of Neoproterozoic low δ¹⁸O protolith with Central Dabie experiencing the Triassic UHP metamorphism, but it was significantly reworked at Early Cretaceous in association with contemporaneous magma emplacement. The Rodinia breakup at about 750 Ma would lead to not only the reworking of juvenile crust in an active rift zone for bimodal protolith of Central Dabie, but also reworking of ancient crust in an arc-continent collision zone for the North Dabie protolith. The spatial difference in the metamorphic age (Triassic vs. Cretaceous) between the northern and southern parts of North Dabie suggests intra-crustal detachment during the continental subduction. Furthermore, the Dabie orogen would have a three-layer structure prior to the Early Cretaceous magmatism: Central Dabie in the upper, North Dabie in the middle, and the source region of Cretaceous magmas in the lower.