High pressure equation of state for molten CaCO3 from first principles simulations

Carbonate melts are important active metasomatic agents and efficient transport agents; their thermodynamic properties at high temperatures and pressures are therefore of considerable interest for various geochemica applications. However, due to the extreme challenges in relevant experiments, current knowledge of even the density of carbonate melts is limited. In this study, we provide high quality volumetric data of Ca CO3-melt from firs principles at high temperatures and pressures(up to3,500 K and 60 GPa). The accuracy of these data is demonstrated through comprehensive comparison with available experimental data and a thorough discussion of the predictability of the re-scaling method proposed in this study. Based on the simulations, an equation of state has been established that is critical to relevant highly disputed questions such as the decomposition and solidification boundaries of Ca CO3 melts, the latter of which is briefly discussed in this study with a newly derived ab initio melting curve to high pressures.     

济阳坳陷东营凹陷古近系沙河街组深湖相油面岩的特征及成因

古近系沙河街组沙三段下部发育的深湖相油页岩是东营凹陷最重要的优质烃源岩.该油页岩呈深灰色或棕褐色,页理发育,主要由富含有机质纹层和浅灰色钙质纹层形成的毫米级沉积层偶组成.其中有机质纹层中的有机碳含量在5%以上,富含藻类化石及鱼化石等;钙质纹层主要由方解石组成,呈灰白色.沉积环境分析表明,该油页岩形成于湿润气候条件下的半咸水-微咸水的深湖缺氧环境中,沉积速率较慢,湖盆处于欠补偿状态,水体分层结构使沉积有机质得到有效保存.藻类等水生生物勃发吸收了更多的CO2,从而诱发大量内生成因的碳酸盐沉淀,形成碳酸盐纹层,而藻类的死亡则导致湖水有机质输送通量增多,使沉积物中有机质保存量增大,促使高有机质丰度烃源岩的形成.因此,分层的水体结构和藻类的勃发是油页岩形成的重要控制因素.     

莱州湾地区10万年以来沉积环境变化

本文用热释光测年和地球化学标志法研究了莱州湾地区沉积环境的变化。石英的375℃热释光峰作为测年基础。岩芯样品的测定结果、反映了自全新世(1.2万年)至晚更新世(11万年)地层的年代特点。实验中来用了Sr/Ba、Rb、Mn/Fe和CaO作为地球化学标志,所得数据经Sheppard方程和Fisher判别处理。在得到的沉积环境变化曲线和大洋δ~(18)O曲线对比中可以看出,本区在十万年以来出现过三次海陆相地层变化序列,其中在距今11—7万年和深度为43.5—60m处,在距今4.6—2.1万年和深度为23—35m处,以及在距今1.1—0.6万年和深度为8—11m处出现过三次海相地层,分别与沧州、献县和黄骅海侵事件相应,并同时受到全球气候变化的控制。     

Prevention of water and quicksand inrush during extracting contiguous coal seams under the lowermost aquifer in the unconsolidated Cenozoic alluvium—a case study

Extracting the contiguous coal seams under the lowermost aquifer in the unconsolidated Cenozoic alluvium is apt to water and quicksand inrush. By using a series of investigation methods including empirical formulas, numerical simulation, theoretical analysis, etc., the study focused on the fracture and the excess pore water pressure in the overlying strata in the process of extracting no. 8 coal seam firstly and no. 9 coal seam (under no. 8 coal seam) subsequently in no. 8102 working face of Luling coal mine in the north of Anhui Province of China. When no. 8 coal seam was extracted, the water-conducting fractured zone penetrated into the lowermost aquifer and rapid dissipation of excess pore water pressure above the gob occurred, accompanied by relatively high seepage hydraulic gradient over the headgate and the tailgate. When no. 9 coal seam was extracted, failure did not obviously extend upwards and the excess pore water pressure decreased slowly and a relatively high seepage hydraulic gradient transferred downwards from the headgate to the tailgate in the inclined profile. The safe water head (H _s) in the lowermost aquifer was confirmed to 15.6 m. Therefore, water and quicksand inrush was avoided effectively in the process of extracting the contiguous coal seams by dewatering, controlling mining height, and laying double resistance nets in the working face.     

虚拟合作实验室-利用Internet开展大气科学国际合作研究的可行之路

试图提出一个由中美双方大气科学家参与的虚拟合作实验室的解决方案,实验室包括虚拟资料／信息系统、虚拟模拟系统、虚拟应用分析系统、虚拟培训学校、虚拟图书馆、虚拟可视化实验室和虚拟出版系统等。     

冬小麦农田裸温与气温差异分析及其应用

以矮秆代表作物冬小麦为研究对象,利用郑州农业气象试验站2010年10月15日—2011年6月2日农田小气候观测的各层裸温、气温、总辐射和覆盖度资料,采用对比差值、温度垂直梯度等方法统计分析,并对温度对比差值和总辐射曝辐量相关关系和温度的垂直梯度分布特征进行了研究,结果表明:25cm、150cm和300cm高度的日平均裸温和气温变化趋势基本一致,其对比差值呈由小变大趋势;各层裸温和气温的日分布符合温度日变化分布的一般规律,垂直梯度变化比较明显;各层对比差值呈单峰分布,峰值出现在正午12时左右;裸温和气温的对比差值与总辐射曝辐量呈线性相关。裸温与气温的垂直梯度变化有很好的一致性,可利用裸温不同层次间垂直梯度变化特征确定气温传感器合理的安装高度;根据麦田裸温垂直梯度变化特征,考虑到温度防辐射罩高度限制,矮秆作物田间小气候气温应在距离地表面25cm、50cm和150cm高度附近分别设置观测层次。     

A statistical analysis of the power law and the logarithmic law using wind data from a 164 m tower

The wind speed distribution with height is analysed by using hourly data for a full year recorded at 6 levels of a 164 m tower at Nanjing. A statistical error analysis shows that power law and logarithmic law are best applicable when the wind is strong. For the height range from 16 to 164 m, the power law represents the actual speed distribution better than does the logarithmic law.     

相对局部区域震源参数随机不确定性经验关系研究

在进行未来破坏性地震的强地面运动数值模拟时,震源参数选取的准确性对地震动预测的结果影响很大。震源参数的确定存在很多不确定性因素,既包含随机的不确定性因素,又包含认知的不确定性因素。本文在大量地震事件及文献调研的基础上,运用统计学方法对具备随机不确定性特征的震源参数进行统计研究,以震源参数经验公式的形态建立解释其随机性和不确定性的数学模型。为了研究局部地区震源参数的定标关系特征,获得更加适用于局部地震密集区域,尤其是包含中国大陆地区在内的局部区域的震源参数的经验关系,本文从GCMT地震目录中选取了1 700多个M_W≥5.5的地震事件,运用统计学方法研究地震密集地区的震源参数经验关系,包括震级、地震矩、破裂面积等,增加了相对较大的局部范围内凹凸体的地震样本数量,从统计学角度计算更加适合局部区域的震源参数的经验关系。统计结果表明:局部区域震例获得的震源参数的经验关系与不限区域震例获得的经验关系存在差异,尤其是涉及到断层破裂面积、凹凸体相关参数时差异较大,局部区域内震例获得的震源参数的经验关系将更具有代表性。应用本文获得的相对局部区域的经验公式计算未来破坏性地震的强地面运动所需的震源参数时,获得的地震动预测结果将更能体现目标区域真实的地震动特征,进而提高地震动预测结果的可靠性。      

灰色～周期外延组合模型在吉兰太盐湖卤水动态预测中的应用

本文利用灰色预测和周期外延预测模型的优点,提出了灰色预测与周期外延预测相结合的灰色～周期外延组合模型,对吉兰太盐湖卤水的动态变化进行了模拟,结果可靠,该模型可广泛应用地下水动态预测和其它序列预测。     

层状侵入体韵律层理形成过程的定量模拟——以四川攀枝花层状岩体为例

层状侵入体的韵律层理是一种特殊的岩石构造,长期以来其成因倍受关注,成因假说很多。本文在综合这些观点关于岩浆物理,化学性质的研究,尤其是在岩浆房地对流特征研究成果的基础上,提出了新的成因解释,认为固化带前锋处矿物的结晶,熔浆组分的扩散及固化带前锋本身的推进等３个因素的相互耦合是形成韵律层理的主要机制,这个过程是发生在一定过冷却条件下的,在这种定性认识基础上,笔者提出了旨在对韵律层理形成过程进行模拟计