The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

Heavy metal pollution in sediments of a typical mariculture zone in South China

The heavy metal inventory and the ecological risk of the estuarine sediments in Hailing Bay, an important maricultural zone along the southern coast of China, were investigated. Results show that the surface sediments were mainly polluted by As (2.17-20.34 mg/kg), Ni (1.37-42.50mg/kg), Cu (1.21-58.84 mg/kg) and Zn (11.69-219.22 mg/kg). Furthermore, the aquafarming zone was significantly more polluted than the non-aquafarming zone, and cluster analysis suggested additional sources of heavy metal input in the aquafarming zone. As, Cr, Cu, Ni, Pb and Zn were mainly present in the non-bioavailable residual form in the surface sediments, whereas Cd was predominantly in the highly mobile acid soluble and reducible fractions. The ecological risk of the polluted sediments stemmed mainly from Cd, and from As, Cu and Pb to less degrees. The highest potential risks occurred near the aquaculture base, indicating the need to control heavy metal inputs from aquafarming activities.     

Isolation,purification and characterization of the hydrogen evolution promoting factor of hydrogenase ofSpirulina platensis

A component (s-factor) with obvious promoting effect on hydrogen evolution of hydrogenase has been isolated and extracted from a cell-free preparation ofSpirulina platensis. The effect of the s-factor in the reaction system is similar to that of Na₂S₂O₄, but is coupled with light. The s-factor has the maximum absorption peak at 620 nm in the oxidized state, at 590 nm in the reduced state. The partially purified s-factor showed two bands by SDS-PAGE and is distinctly different from phycocyanin, which has no change of oxidized state and reduced state absorption spectra, and also has no promoting effect on hydrogenase ofSpirulina platensis under the light. The research supported by the NSFC.     

多源数据融合的城市体检评估

融合遥感影像、社会开放大数据、统计资料等多源数据,以长沙市为例,围绕生态宜居、健康舒适、安全韧性、交通便捷、风貌特色、整洁有序、多元包容、创新活力等8个方面构建城市体检指标体系,运用归一法和层次分析法对城市自然本底和运行体征展开计算评估,结果发现：1）长沙市人居环境整体良好,城市生态宜居和整洁有序度较高,交通便捷和安全韧性建设亟需加强,风貌特色、健康舒适、创新活力、多元包容等仍有改善空间。2）各区县专题发展水平不均,在保留区域功能特色的基础上,应该着重解决发展的短板。3）城市中心城区人口密度、空气质量优良天数、万车死亡率等指标达到最高水平,但在便民服务设施完整覆盖度、住宅建筑更新和开发、群体包容等方面与城市发展需求还有一定差距。根据多源数据城市体检结果可知,长沙市未来需要以问题和需求为导向,精准治理“城市病”,努力提高城市居民生活满意度、幸福感和归属感。     

辽南早元古代花岗岩的变形温度及其构造意义

辽南早元古代辽河群中片麻状花岗岩的变形温度显示出645—690℃,550—610℃和485℃±三组温度值,表明花岗岩遭受了三幕构造变形。而区域构造解析亦表明辽河群在早元古时期经历了三幕构造变动。花岗岩的温度系列与区域变形序列具有一致性,排除了花岗岩晚期构造侵位的可能性。变形温度以550—610℃居多,意味着该幕构造形迹保存最好。第三幕变形变质作用相对较弱,仅局部出现485℃的温度值。     

关于海域面积精确计算的若干问题探讨

海域面积精确计算是实现海洋功能区划的基础和关键之一。本文通过对江苏省海洋功能区划工作中误差的分析 ,并针对其产生原因 ,在地图投影的选择和坐标的变换、扫描精度的控制、配准精度的控制、图象的数字化和图形编辑等方面 ,提出了相应的优化处理方法 ,提高了海域面积计算的精度 ,将其中误差控制在估计值范围内 ,从而在实际工作中有一定的应用价值。     

A linear tessellation model to identify spatial pattern in urban street networks

Street patterns reflect the distribution characteristics of a street network and affect the urban structure and human behavior. The recognition of street patterns has been a topic of interest for decades. In this study, a linear tessellation model is proposed to identify the spatial patterns in street networks. The street segments are broken into consecutive linear units with equal length. We define five focal operations using neighborhood analysis to extract the geometric and topological characteristics of each linear unit for the purpose of grid-pattern recognition. These are then classified by Support Vector Machine, and the result is optimized based on Gestalt principles. The experimental results demonstrate that our method is effective for mining grid patterns in a street network.     

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素

城市经济脆弱性作为当前脆弱性研究中的重要领域,为人-地系统耦合研究提供了新的视角,并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵,基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系,运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性,并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年,河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）;（2）河西走廊地区的城市经济脆弱性具有明显的空间特征,经历了东西高、中部低到整体较高的演变过程;（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子,提出针对性优化措施。     

重力异常垂向一阶导数的一种简便算法

利用拉格朗日插值导出了重力异常垂向一阶导数的计算公式，给出了地面以及地面之上不同高度的求导系数。该公式可以计算地面上的重力垂向一阶导数，还可以直接计算地面之上任意高度上的垂向一阶导数。鉴于该公式除系数不同外，与上延公式完全相同，因此，程序设计尤为简单。使用本公式对模型数据和实际资料进行了处理，证明了本算法的实用性。     

企业三维仿真Web GIS系统的设计

随着Internet的发展和人们对各类信息需求的增加及企业面向社会提高知名度的需要,使得企业三维仿真WebGIS系统有着较为广泛的应用前景。文章探讨了利用VisualBasic等开发企业三维仿真webGIS系统的过程和方法。