Mo isotope composition in Mo-rich high- and low-T hydrothermal systems from the Swiss Alps

We analyzed the molybdenum (Mo) isotope compositions (IC) of 59 samples from two molybdenite mineralizations (Alpjahorn and Grimsel) and from a Mo-rich hydrothermal breccia (Grimsel) from the Aar Massif, Switzerland. The formation temperature of the Late Paleozoic Mo mineralizations (300-600 °C) is much higher than that of the Pliocene breccia (100-160 °C). The Mo IC of the molybdenites varies over 1.35‰. Even in a single hand specimen it spans 0.45‰, indicating that fractionation processes during molybdenite precipitation can vary on a cm scale. The Mo IC of most molybdenites analyzed here are significantly heavier than that of the host rock (δ^98/95Mo = (0.05 ± 0.1)‰) and show a bimodal distribution centered around δ^98/95Mo ≈ 1.1‰ and 0.2‰. This result rules out single stage Rayleigh fractionation as the relevant formation mechanism and instead, redox variations are suggested to be a main factor controlling the Mo IC of the studied high-temperature Mo deposits. The range of the Mo IC in one single deposit, the Alpjahorn, overlaps with the variation range of almost all other published values for Mo IC in Mo deposits. Compared to the molybdenites, the breccia shows an even wider variation of 3.0‰ (δ^98/95Mo between −1.6‰ and +1.4‰). In contrast to the high-T molybdenite deposits, here the Mo was transported via oxidized surface waters into the breccia system, where it was reduced and precipitated. This indicates that oxidation and reduction of Mo complexes may lead to highly variable Mo IC in hydrothermal systems.     

Modeling meso- and sub-mesoscale circulation along the eastern Crimean coast using numerical calculations

A numerical experiment has been carried out using a hydrodynamical model with nonlinear equations of motion and heat and salt advection to reconstruct the fields of hydrophysical parameters taking into account the real atmospheric forcing for the autumn season along the southern coast of the Crimean Peninsula. The studied part of the coast is situated at 44.25°N 33.95°E/44.72°N 34.55°E. High spatial resolution is used for modeling: 350 m in the horizontal plane with 38 layers in the vertical; the bottom topography is described in detail with ~500 m resolution. Detected and studied meso- and sub-mesoscale structures in the current field agree well with the observational data, which is impossible or hard to identify in numerical experiments with coarser resolution. Their kinematic characteristics and the lifetime are defined and some mechanisms of their origin are suggested.     

Comparison of single-domain and dual-domain subsurface transport models

Subgrid modeling of some type is typically used to account for heterogeneity at scales below the grid scale. The single-domain model (SDM), employing field-scale dispersion, and the dual-domain model (DDM), employing local hydrodynamic dispersion and exchange between domains having large hydraulic conductivity contrasts, are well-known examples. In this paper, the two modeling approaches are applied to tritium migration from the H-area seepage basins to a nearby stream--Fourmile Branch--at the Savannah River Site. This location has been monitored since 1955, so an extensive dataset exists for formulating realistic simulations and comparing the results to data. It is concluded that the main parameters of both models are scale-dependent, and methods are discussed for making initial estimates of the DDM parameters, which include mobile/immobile porosities and the mass exchange coefficient. Both models were calibrated to produce the best fit to recorded tritium data. When various attributes of the dataset were considered, including cumulative tritium activity discharged to Fourmile Branch, plume arrival time, and plume attenuation due to closure of the seepage basins in 1988, the DDM produced results superior to the SDM, while causing no unrealistic upgradient dispersion. A sensitivity analysis showed that only the DDM was able to accurately produce both the instantaneous activity discharge and cumulative activity with a single parameter set. This is thought to be due to the advection-dominated nature of transport in natural porous media and the more realistic treatment of this type of transport in the DDM relative to the SDM.     

Fluid evolution during burial and Variscan deformation in the Lower Devonian rocks of the High-Ardenne slate belt (Belgium): sources and causes of high-salinity and C–O–H–N fluids

Fluid inclusions in quartz veins of the High-Ardenne slate belt have preserved remnants of prograde and retrograde metamorphic fluids. These fluids were examined by petrography, microthermometry and Raman analysis to define the chemical and spatial evolution of the fluids that circulated through the metamorphic area of the High-Ardenne slate belt. The earliest fluid type was a mixed aqueous/gaseous fluid (H₂O–NaCl–CO₂–(CH₄–N₂)) occurring in growth zones and as isolated fluid inclusions in both the epizonal and anchizonal part of the metamorphic area. In the central part of the metamorphic area (epizone), in addition to this mixed aqueous/gaseous fluid, primary and isolated fluid inclusions are also filled with a purely gaseous fluid (CO₂–N₂–CH₄). During the Variscan orogeny, the chemical composition of gaseous fluids circulating through the Lower Devonian rocks in the epizonal part of the slate belt, evolved from an earlier CO₂–CH₄–N₂ composition to a later composition enriched in N₂. Finally, a late, Variscan aqueous fluid system with a H₂O–NaCl composition migrated through the Lower Devonian rocks. This latest type of fluid can be observed in and outside the epizonal metamorphic part of the High-Ardenne slate belt. The chemical composition of the fluids throughout the metamorphic area, shows a direct correlation with the metamorphic grade of the host rock. In general, the proportion of non-polar species (i.e. CO₂, CH₄, N₂) with respect to water and the proportion of non-polar species other than CO₂ increase with increasing metamorphic grade within the slate belt. In addition to this spatial evolution of the fluids, the temporal evolution of the gaseous fluids is indicative for a gradual maturation due to metamorphism in the central part of the basin. In addition to the maturity of the metamorphic fluids, the salinity of the aqueous fluids also shows a link with the metamorphic grade of the host-rock. For the earliest and latest fluid inclusions in the anchizonal part of the High-Ardenne slate belt the salinity varies respectively between 0 and 3.5 eq.wt% NaCl and between 0 and 2.7 eq.wt% NaCl, while in the epizonal part the salinity varies between 0.6 and 17 eq.wt% NaCl and between 3 and 10.6 eq.wt% for the earliest and latest aqueous fluid inclusions, respectively. Although high salinity fluids are often attributed to the original sedimentary setting, the increasing salinity of the fluids that circulated through the Lower Devonian rocks in the High-Ardenne slate belt can be directly attributed to regional metamorphism. More specifically the salinity of the primary fluid inclusions is related to hydrolysis reactions of Cl-bearing minerals during prograde metamorphism, while the salinity of the secondary fluid inclusions is rather related to hydration reactions during retrograde metamorphism. The temporal and spatial distribution of the fluids in the High-Ardenne slate belt are indicative for a closed fluid flow system present in the Lower Devonian rocks during burial and Variscan deformation, where fluids were in thermal and chemical equilibrium with the host rock. Such a closed fluid flow system is confirmed by stable isotope study of the veins and their adjacent host rock for which uniform δ¹⁸0 values of both the veins and their host rock demonstrate a rock-buffered fluid flow system.     

The origin of the Basse Normandie duplex,Boulonnais, France

Two Hercynian duplexes are developed in Viséan limestones in the Basse Normandie quarry. The lower duplex is completely exposed in a subvertical quarry wall; the partially exposed upper duplex lies immediately above the lower duplex. The duplexes are both located in the footwall of the Hydrequent thrust which emplaced Devonian clastic sediments above the Viséan limestones. The lower duplex exposes all the internal thrusts, a reference bed of chalky limestone, the roof and floor thrusts, and the duplex tip. The duplex has been graphically restored to its pre-deformation geometry by line-length and area balancing and its resultant geometry is close to the model of Boyer & Elliott. The lower duplex shortened by two different mechanisms, an initial phase of layer-parallel shortening which produced no cleavage, followed by thrust imbrication. The average contraction of the front portion of the duplex was ?49% (natural strain) of which ?27% is layer-parallel shortening and ?22% is thrust imbrication. However, locally the bulk shortening increases from zero at the duplex tip to over ?120% in a down-dip direction. The area balancing provides the most accurate estimates of bulk shortening; line-length balance calculations give minimum estimates only. An area balance on the whole of the lower duplex gives a bulk shortening of ?84%. An area balance of the upper duplex yields an average contraction of ?75% and the total contraction produced by both duplexes is ?92%.     

A soil geochemistry orientation survey for uranium at Koongarra, Northern Territory

A soil geochemistry orientation survey for U at Koongarra was designed to determine optimum conditions for future U exploration in the area. Soil samples were collected at various depths from auger holes drilled along two traverses over the Koongarra No. 1 orebody, along a single traverse over suspected mineralization at nearby Anomaly A, and at three background localities. Rock samples collected from surface outcrop, costeans, and drill core were used to investigate any elemental associations with the ore or primary dispersion which could then be traced in the overlying soils.The results showed that Cu and Pb are potentially suitable pathfinder elements, where U data are not definitive, while Co, Ni and Be also provide significant information. The optimum sample depth was 1.2 m. For a Koongarra-sized target the maximum sample spacing should be 30 m on lines 200 m apart, provided every anomalous sample is followed up with closer spaced sampling around it. Anomalies detected in alluvial soil deeper than 1.2 m were due to hydromorphic dispersion. Some of the general distribution patterns for individual elements may be related to soil-type variations.