南海北部油气缓释环境沉积物脂类化合物组成特征

认识沉积环境有机碳留存状况是阐述油气形成过程中有机碳早期成岩的关键内容。以南海珠江口盆地及其邻近海域为背景,通过研究表层沉积物中脂类化合物的形态组成,认识脂类有机碳的来源和留存状态,阐述特征脂类分子的早期成岩特征。结果表明,研究区域表层沉积物有机碳含量为0.22%～0.66%,有机碳稳定同位素分布在-20.88‰～-22.93‰之间,表现为显著的海源特征。沉积物中共检测出21种脂肪酸、6种脂肪醇、8种甾醇和植醇;总脂肪酸、脂肪醇、甾醇和植醇含量分别为12.57～40.27μg/g、5.35～8.98μg/g、0.15～3.75μg/g和0.01～3.99μg/g干重,总体表现为靠近珠江口和台湾海峡略高。脂类化合物的存在形态以游离态(FR)和碱性水解态(BH)为主,酸性水解态(AH)贡献较低;其中植醇和甾醇呈现显著的BH优势,植醇中未检出AH组分的贡献。脂类化合物主要来自于海洋现场生产,海洋微藻和细菌的相对贡献率分别为21.18%～33.78%和11.02%～15.64%,陆源高等植物贡献低于5%。来源于硫酸盐还原菌的支链脂肪酸在靠近珠江口海域高达1.79～2.62μg/g,占总脂肪酸的5.14%～6.50%,并与硫酸盐还原过程相关的古菌分布相一致。     

应力路径和干湿状态对堆石料颗粒破碎的影响研究

堆石料颗粒破碎是引起高土石坝变形的重要因素。在大坝填筑、蓄水期,堆石料的应力路径和干湿状态均是变化的。通过大型三轴试验,系统地研究了应力路径和干湿状态对堆石料颗粒破碎规律的影响。试验结果表明：（1）相同初始条件下,按不同应力路径达到同一轴向应变停机时测定的颗粒破碎率是不同的,等围压?3试验产生的颗粒破碎最大,等平均主应力p试验的次之,等最大主应力?1试验的最小,但不同应力路径下的颗粒级配演化规律是一致的。（2）相同初始条件下,湿样的颗粒破碎率明显高于干样,且二者的差距随着围压的增大而增大,不同干湿条件下的颗粒级配演化规律同样是一致的。（3）建立的考虑母岩强度的颗粒破碎率与塑性功的关系可以较好地统一描述不同应力路径及干湿状态下的颗粒破碎。该研究成果可为建立复杂应力路径及干湿变化条件下考虑颗粒破碎的堆石料弹塑性本构模型提供依据。     

可液化场地碎石桩复合地基地震动力响应分析

采用砂土液化大变形弹塑性本构模型分析可液化砂土,采用模量随应力与应变变化的等效非线性模型增量形式分析碎石桩,应用FLAC3D有限差分软件对地震动力作用下可液化场地碎石桩复合地基进行三维动力响应分析。模拟分析了在地震作用下碎石桩刚度效应和排水效应对加固处理可液化场地的抗液化效果,从初始小变形到液化后大变形的变形发展,超静孔压累积与消散,及桩与土的变形与应力分配变化等。结果表明,所用模型与方法可合理描述可液化场地碎石桩复合地基在地震作用下场地的动力响应特性和抗液化效果;在地震作用下可液化场地中桩周土体与碎石桩体的竖向应力与水平向剪切应力向碎石桩体集中,竖向有效应力比可降至约1/6～1/3;桩周土体与桩体为非协调变形,剪应变比可达7～10;碎石桩抗液化影响范围约为2.5～3倍桩径,对超过3.5倍桩径范围影响较小;碎石桩与砂土渗透系数比大于100时对降低砂土中超静孔隙水压影响明显;碎石桩对场地的加密效应可显著降低超静孔隙水压力,而碎石桩刚度则对超静孔隙水压力变动影响较小,但有助于减低地面加速度响应峰值。     

Geochemistry,Paleoenvironment and Mechanism of Organic-Matter Enrichment in the Lower Silurian Longmaxi Formation Shale in the Sichuan Basin,China

To investigate the mechanism of the organic-matter enrichment in the Lower Longmaxi Formation shale, the geochemistry and total organic carbon(TOC) of the Longmaxi Formation black shales in the Jiaoshiba, Zhaotong, and Weiyuan areas of the Sichuan Basin were analyzed. Paleoproductivity proxy parameters(Babio, Siex, and Ni/Al), clastic influx proxies(TiO_2 and Ti/Al), redox indices(V/Cr, Ni/Co, V/(V+Ni), and U/Th), and hydrothermal indicators(Fe, Mn,and Y concentrations; Fe/Ti ratio and a Ni-Zn-Co diagram) were employed to decipher the paleoenvironment of the Lower Longmaxi Formation shales. TiO_2 and Ti/Al indicated low terrigenous detrital influx in all three areas. However, Babio, Siex,and Ni/Al indicated high productivity in the Jiaoshiba area. V/Cr, Ni/Co, and U/Th indicated higher oxygen content with larger fluctuations in the Zhaotong and Weiyuan areas. Fe, Mn, and Y concentrations and the Fe/Ti ratio implied greater active hydrothermal activity in the Weiyuan area. These heterogeneities were considered to be closely related to the paleoenvironment and paleogeography, and the large basement faults that developed during the Chuanzhong paleo-uplift could have provided vents for deep-hydrothermal-fluid upwelling. The redox indices(V/Cr, Ni/Co, and U/Th) and a paleoproductivity proxy(Ni/Al) displayed a significant correlation with the TOC, suggesting that both excellent preservation conditions and high paleoproductivity were the controlling factors for the enrichment of organic matter in the Longmaxi Formation shale. There was no obvious correlation between the clastic influx proxy(Ti/Al) and the TOC due to the extremely low supply of terrigenous debris. The hydrothermal indicator(Fe/Ti) was negatively correlated with the TOC in the Weiyuan area, indicating that hydrothermal activity may have played a negative role in the accumulation of organic matter. This study suggests that the enrichment of organic matter in the Longmaxi Formation marine shale varied according to the paleogeography and sedimentary environment.     

典型铬渣污染场地铬污染特征研究

选取西南岩溶区某傍河铬渣堆场为研究对象,对场地不同位置与深度的土壤及地下水样品进行采集,通过数理统计对Cr在场地中的空间分布特征以及场地对地下水的影响进行了分析。结果表明:土壤中总Cr浓度的水平分布具有差异性,表层土壤Cr浓度由上游到下游呈明显降低趋势,变化率为3.59;深层饱水带土壤中总Cr浓度分布受到地下水流场的影响,场地下游土壤铬浓度明显高于上游;杂填土垂向剖面的铬浓度分布不同于坡残积红黏土,杂填土中铬浓度随着深度的增加而增加,浓度与土壤深度的关系可用y=63.88ln（x）-75.221来表示;而在红黏土中剖面中,铬大量聚集在土壤表层,后随着深度的增加铬浓度逐渐降低,接近基岩面有升高趋势;场地地下水中Cr（Ⅵ）的浓度受深层土壤中总Cr浓度的影响,两者呈正相关。      

不同超富集、富集植物-玉米间作模式对玉米中镉吸收、转运的影响研究

为了研究Cd污染条件下,玉米分别与苋菜、黑麦草、龙葵间作对重金属Cd吸收和转运的特点,从而选择适宜与玉米间作的富集植物,同时达到修复重金属Cd污染土壤的目的。该文以镉(Cd)污染的河南棕壤黏土为供试土壤,通过盆栽试验,基于玉米各器官中Cd含量、富集系数、转运系数、土壤有效态Cd含量的变化,研究了间作苋菜、黑麦草、龙葵对玉米各器官Cd的积累特性的影响及其迁移转运机制。结果表明：(1)龙葵、苋菜、黑麦草间作使得玉米地上部Cd含量显著性降低(P<0.05),其中以籽粒中Cd含量的下降最为显著。间作苋菜、黑麦草、龙葵,玉米籽粒中Cd含量分别下降了67.6%、75.7%和79.9%。(2)间作苋菜、黑麦草、龙葵使得玉米的富集系数较单作处理下玉米的富集系数分别下降了49.3%、39.7%和68.5%,且差异达到显著水平。(3)与苋菜、黑麦草间作相比,间作龙葵的玉米转运系数分别下降了27.5%、24.2%,且差异均达到显著水平。通过对人体每天摄入Cd量的安全值计算得出间作后土壤中Cd全量应低于2.26 mg·kg-1,土壤有效态Cd含量低于0.88 mg·kg-1。该污染农田在间作模式下,食用玉米Cd暴露对居民健康不存在风险。间作苋菜、黑麦草、龙葵能够抑制玉米对Cd的吸收,同时阻控玉米地上部Cd向地上部的转移,尤其是向籽粒转移。通过间作苋菜、黑麦草、龙葵,不仅降低了主栽作物玉米的Cd累积量,实现玉米安全、优质种植,同时也达到了修复污染土壤的目的。     

初论雪峰山地区基性-超基性岩镍钴铜金矿找矿方向

近年来,雪峰山地区的基性-超基性岩矿床找矿工作取得了一定的进展。为了及时总结成矿规律,指导进一步的找矿工作,本文在大量野外调研的基础上,系统总结了该地区基性-超基性岩岩体的地质特征、已有找矿进展的长界镍矿和字溪金矿地质特征及已发现的镍钴铜金等矿化特征,并与国内外同类型矿床的成矿特征进行了比较,最后提出了如下认识:雪峰山地区具备找寻基性-超基性岩矿床潜力,目标矿种主要为镍、钴、铜及金矿,主要矿床类型为岩浆硫化物型镍钴铜矿及蚀变热液型金矿。前者目标地质体以通道-洪江-中方-古丈一带新元古代基性-超基性岩群/带最为有利,后者则以隘口岩群及艾头坪-大洪山岩群的大洪山段最为有利。     

Evolution trend of the water quality in Dongping Lake after South-North Water Transfer Project in China

To investigate the evolution trend of water quality in Dongping Lake after South-North Water Transfer Project operation as well as to ensure the safe usage of the water receiving areas, water samples were collected and determined before and after water delivery in different hydrological seasons. Then, comprehensive pollution index method, comprehensive nutrition state index method and health risk assessment model were utilized to evaluate the quality, nutrition, and health risk of Dongping Lake water. Results showed that the quality of Dongping Lake water still met level Ⅲ (light pollution) no matter before or after water delivery. The nutrition state was improved from light eutropher before water delivery to mesotropher after water delivery. The health risk level was reduced from high-medium before water delivery to medium level after water delivery. In summary, the operation of the eastern route of South-North Water Transfer Project is beneficial for water environment improvement of Dongping Lake.     

对PCM编码式GPS站点布设模式的评价和改进

本文主要对PCM编码式的布设模式进行分析和改进,介绍PCM编码式和闭锁深度倍数式2种站点布设模式,然后在最小有效距离（MED）为6.31倍断层闭锁深度的情况下,通过精度评价方法对比2种布设模式的结果,发现二者相差不大。进一步研究MED的合理选择,结果表明,MED取20倍的闭锁深度比6.31倍的闭锁深度更为合理。在MED为20倍的情况下对比研究PCM编码式和常规闭锁深度倍数式布设模式的优劣,结果表明,PCM编码式的布设模式优于常规模式。将PCM编码式的布设模式应用于川滇地区的巧家-东川剖面进行检验,发现PCM编码式的结果优于目前站点分布得到的结果,说明合理的站点布设可得到精度更优的结果。本文研究对于断层形变监测中精确获取形变参数具有重要意义。     

Research Progress of Seafloor Pockmarks in Spatio-Temporal Distribution and Classification

Seafloor pockmarks are important indicators of submarine methane seepages and slope instabilities.In order to promote the understanding of submarine pockmarks and their relationship with sediment instabilities and climate changes,here we summarize the research results of pockmarks in the spatio-temporal distributions and shaping factors.Most of pockmarks occur along active or passive continental margins during the last 25 kyr B.P..Circular and ellipse are the most common forms of pockmarks,whereas pockmarks in a special crescent or elongated shape are indicators of slope instabilities,and ring-shape pockmarks are endemic to the gas hydrate zones.Further researches should be focused on the trigger mechanism of climate changes based on the pockmarks in the high latitudes formed during the deglaciation periods,and the role of gas hydrates in the seafloor evolution should be elucidated.In addition,the feature of pockmarks at their early stage(e.g.,developing gas chimneys and gas driving sedimentary doming)and the relations between pockmarks and mass movements,mud diapirs could be further studied to clarify the influences of rapid methane release from submarine sediments on the atmospheric carbon contents.