基于DGT和化学提取法研究浙西北地质高背景区土壤镉生物有效性

地质高背景区相较于人类活动引起的土壤镉污染影响范围更广,在区域尺度上对生态系统和人类健康构成危害。土壤镉生物有效性是决定其生物可利用性、生物毒性的关键因素,因此探寻可行的土壤镉生物有效性评价方法对污染农用地安全利用和风险管控具有重要的理论和实际意义。DGT技术、单一提取法、连续提取法和土壤溶液法常用于测定土壤有效镉,但已有研究成果主要基于同种土地利用类型土壤的室内盆栽实验,难以代表自然污染土壤中的复杂情况。为探明各土壤重金属有效态提取技术对地质高背景区不同土地利用类型土壤Cd生物有效性评估效果,本文以浙江西北部土壤Cd高地质背景区水田土壤-水稻籽实和旱地土壤-小白菜样品为研究对象,实验应用DGT技术、单一提取法（0.01mol/L氯化钙提取）、连续提取法（七步连续提取）和土壤溶液法评价土壤中镉生物有效性。结果显示：①研究区水田和旱地土壤Cd平均含量分别为1.07mg/kg和0.73mg/kg,显著高于浙江和全国土壤平均水平,Cd的异常富集主要与浙西北地区广泛分布的黑色岩系有关。②相较于碳酸盐岩区,黑色岩系区土壤中Cd的生物有效组分占比较高,水田和旱地土壤Cd的活动系数（MF）高达59.9%和51.8%,Cd易在土壤-作物系统中发生迁移富集;③植物体内镉含量Cd-P与不同方法测定的有效镉含量均呈显著正相关,但Cd-P与DGT技术测定的有效镉含量相关性优于其他三种方法,水田土壤测得的有效Cd与水稻籽实相关关系：$ {{C}}_{\text{soln}} $>CDGT>$ {{C}}_{{\text{CaCl}}_{\text{2}}} $>$ {{C}}_{{\text{F}}_{\text{1}}\text{+}{\text{F}}_{\text{2}}\text{+}{\text{F}}_{\text{3}}} $,旱地土壤测得的有效Cd与小白菜相关关系：CDGT >$ {{C}}_{{\text{CaCl}}_{\text{2}}} $>$ {{C}}_{{\text{F}}_{\text{1}}\text{+}{\text{F}}_{\text{2}}\text{+}{\text{F}}_{\text{3}}} $>$ {{C}}_{\text{soln}} $。综合比较不同土壤有效Cd测定方法的优缺点,DGT技术可以模拟植物体对Cd的动态吸收过程,更能准确地反映土壤Cd生物有效性,预测作物Cd含量水平,这与已有研究成果一致。此外,本文研究成果表明DGT技术评价土壤Cd生物有效性,不仅适用于人为污染区,也可应用于地质高背景区。     

Late Cretaceous-Cenozoic history of the Lake Baikal depression and formation of its unique biodiversity

Independent methods of geological and molecular-biological chronologies have made it possible to define generally corresponding stages in the geological and biological evolution of the environments and communities of Lake Baikal since the Late Cretaceous, i.e., during the last 70 myr. All the abiotic elements drastically changed during geological evolution, with destruction of existing and formation of new natural complexes. Nevertheless, some specific zones retained relicts of former settings. The resulting present-day natural complex includes elements of different ages and geneses. Similar to different natural zones of the present-day Earth, which are populated by different biocoenoses, stages in the development of abiotic elements are also characterized by different faunal and floral assemblages. Some taxa were replaced by others, and the resulting aqueous biota of Lake Baikal includes different-age and ecologically different elements. The oldest groups of Baikal organisms appeared approximately 70 Ma ago, although the largest proportion of the lake biota started forming 4–3 Ma ago in response to the most drastic changes in the abiotic elements of the environment. The youngest taxa appeared 1.8 to 0.15 Ma ago, i.e., during the period when superdeep lake environments and mountainous glaciations were developing. The chronological coincidence of main stages in development of abiotic and biotic elements of the nature indicates their relationships. Particular transformations of abiotic elements and the probable mechanism of their influence on the evolution of living communities are also considered.     

Effectiveness of fast electron retention in the magnetic cavern during disturbance of the magnetic field azimuthal symmetry

The loss rate of fast electrons (with an energy much higher than the energy of the plasma electron thermal motion), when they leave a magnetic cavern during a disturbance of the magnetic field azimuthal symmetry, is studied. The cases of point and volume sources of fast particles have been considered. The plasma density in the cavern is supposed to be low, so that collisions of fast electrons with plasma particles can be neglected. The effect of the electric field on particle motion is neglected because it is assumed that the electric charge particles outgoing from the cavern is compensated by the counter current of plasma conductivity electrons. The dependence of the loss value on the harmonic number and the amplitude of the cavern boundary radius disturbance has been obtained.     

Composition and Formation Conditions of Lower Eocene Shallow-Marine Carbonates in Southern Armenia

Lithology and Mineral Resources - Nummulite facies are known to be a good indicator of Eocene shallow-water paleoenvironments. Nummulitic limestones are widespread in the Lower Eocene of...     

利用奇异谱分析提高极移中长期预报精度

由于空间大地观测数据传输耗时及处理过程复杂, 导致极移测量值的获取存在时延, 无法满足对高精度的极移预报值有重大需求的应用领域. 针对极移复杂的时变特性, 提出一种基于奇异谱分析(singular spectrum analysis, SSA)的预报方法. 首先用SSA分离提取极移时序中的高频组分与低频组分; 其次建立最小二乘(least square, LS)外推与自回归(AutoreGressive, AR)模型对极移高频和低频组分进行组合预报. 结果表明, SSA方法能够准确地分离和提取极移低频和高频组分, 对低频和高频组分组合预报可以显著改善极移的中长期(30--365d)预报精度, 与国际地球自转和参考系服务局(International Earth Rotation and Reference Systems Service, IERS)提供的A公报中的极移预报值相比, SSA方法对极移PMX分量(本初子午线方向)和PMY分量(西90$^\circ$子午线方向)的中长期预报精度改进最高分别可达45.97%和62.44%. 研究结果验证了SSA方法对极移中长期预报改进的有效性.     

Surface and Fundamental Modes of Oscillations in Thin Coronal Loops

Astronomy Letters - The oscillations in thin magnetic flux tubes in the solar corona are considered. The surface and fundamental modes of oscillations are shown to be the main modes of fast and...     

基于GIS的寿宁县猕猴桃种植区提取

本文在对寿宁县当前经济发展和农业自然资源状况进行充分分析的基础上,根据猕猴桃的生长发育条件,确定相应的指标,应用GIS空间分析技术实现了寿宁县猕猴桃适宜种植区的自动提取.以此体现农业气候信息系统在种植区划上的可行性、优越性,并根据分析结果做出了相关的总结,以供有关部门参考.     

Evolution of the Fine Structure of the Matter Distribution of a Free-Falling Droplet in Mixing Liquids

Izvestiya, Atmospheric and Oceanic Physics - In this paper we study the evolution of the matter distribution pattern of ink droplets falling freely into calm water and forming a cumulative back jet...     

Subpollen Particles as Atmospheric Cloud Condensation Nuclei

Izvestiya, Atmospheric and Oceanic Physics - Bioparticles constitute a significant fraction of atmospheric aerosol. Their size range varies from nanometers (macromolecules) to hundreds of...     

中国旅游城市生态安全系统评估与类型划分研究 ——基于节点权重约束网络DEA模型

采用 DPSIR概念模型作为旅游生态安全系统的基本形态,引入网络 DEA模型测度系统运行效率,从“投入-产出”的研究视角探究旅游生态安全系统内部作用机理。采用结构方程模型对网络 DEA模型的结构及权重加以限制,构建具有节点权重约束的网络 DEA评价模型,对主要旅游城市生态安全系统实例进行实证研究。研究结果认为：将生态安全系统分为自然运行阶段、管理反馈阶段2阶段进行效率评价,加权综合得出各旅游城市生态安全系统的综合评价值,以此为依据将样本城市划分为按系统效率的评价结果将其分划为绿色发展型、稳步发展型、高效发展型、双向提升型和管理能力缺失型,针对各类型旅游城生态安全系统特点提出改善其生态安全系统状况的建议。