渤海蓬莱9-1中生代花岗岩体岩石地球化学特征及其区域构造意义

蓬莱9-1花岗岩体是渤海海域首次发现的中生代花岗岩,鉴于渤海海域在华北克拉通中的重要构造位置,该花岗岩的形成时代和成因机制的研究对区域构造研究具有重大意义。锆石LA-ICP-MS U-Pb定年结果表明该花岗岩体形成于中侏罗世160~165Ma。花岗岩属于高钾钙碱性系列,为准铝质-过铝质花岗岩;富Al_2O_3(14.84%~17.19%)和Sr(485×10~(-6)~909×10~(-6)),贫Y(0.66×10~(-6)~1.39×10~(-6))和Yb(小于2.0×10~(-6)),无铕的负异常,多数样品表现为铕的弱正异常,表现出C-型埃达克岩特征。表明渤海地区在160~165Ma期间处于挤压地壳增厚环境下,以地壳减薄为标志的克拉通破坏过程彼时尚未发生,其区域动力学环境可能仍处于华北板块-华南板块碰撞拼接的影响范围内。     

河元背地区绳索取心钻进泵压计算模型的建立与应用

泵压是反映金刚石绳索取心钻进时井内作业是否正常的重要参数。为了进一步研究泵压波动变化与实际钻进作业之间的关系,指导钻进工作的快速、安全开展,结合江西相山河元背地区CUSD2井实际泵压波动数据及相关钻进资料,建立了适用于本井的循环系统压力损失计算模型。对比分析模型计算的理论泵压与实际泵压的波动变化趋势,将模型应用于实际钻进,在此基础上预测后续地层的泵压波动区域范围,发现7 MPa的泵压安全值不再适用于后续地层钻进,调整设置泵压安全值为10 MPa,并利用邻井泵压波动数据进一步验证其可靠性。适当调整修正理论模型,使其可应用于河元背以及相山地区绳索取心钻进中,指导该地区钻探工作。     

CO2加富对塔玛亚历山大藻叶绿素荧光参数及产毒的影响

由大气中CO_2浓度升高引起的海洋酸化,是全球性的重大环境问题之一。本研究采用实验生态学的方法,以塔玛亚历山大藻(Alexandrium tamarense)为研究对象,分析其在CO_2加富条件下叶绿素荧光动力学参数及产毒特征的变化。调制叶绿素荧光结果显示,CO_2加富对塔玛亚历山大藻的PSⅡ最大光化学量子产量(Fv/Fm)、最大相对电子传递效率(r ETRmax)有显著影响(P0.05),且随着培养时间的增长Fv/Fm、r ETRmax均降低,对半饱和光强(Ik)、快速光曲线初始斜率(α)却无显著影响(P0.05)。结果说明CO_2加富能促进塔玛亚历山大藻的PSⅡ最大光化学量子产量,提高其最大光能转换效率和相对最大电子传递效率。高效液相色谱法分析结果显示,该株塔玛亚历山大藻主要产漆沟藻毒素1(GTX1)、漆沟藻毒素4(GTX4)、N-磺酰氨甲酰基毒素(C1)及N-磺酰氨甲酰基毒素(C2)四种PSTs毒素,CO_2加富不改变主要麻痹性贝毒(PSTs)的种类组成,但能显著提高氨基甲酸酯类毒素(GTX1、GTX4)产量(P0.05),而降低N-磺酰氨甲酰基类毒素(C1、C2)产量(P0.05),说明加富能使塔玛亚历山大藻所产毒素发生转化,进而影响藻细胞的整体毒性。     

中国沿海多鳞四指马鲅(Eleutheronema rhadinum)与四指马鲅(E. tridactylum)形态与遗传位点差异分析

多鳞四指马鲅(Eleutheronema rhadinum)与四指马鲅(Eleutheronema tridactylum)是四指马鲅属(Eleutheronema)中的名贵经济鱼类,具有良好的养殖开发前景。本文对中国沿海多鳞四指马鲅与四指马鲅群体的26个形态特征值进行了多变量比较分析,提取了7个主成分,累计贡献率达到91.112%,前三个主成分贡献率分别为28.759%、21.467%、15.469%。多鳞四指马鲅与四指马鲅形态差异主要体现在头背部、尾柄部、背腹轴及头尾轴的特征。利用4个形态学参数建立了2群体判别公式,综合判别准确率高达100%,可作为多鳞四指马鲅与四指马鲅物种资源的初步判定方法。另外,利用简化基因组测序开发出多鳞四指马鲅与四指马鲅SNP标记69207个、In Del标记12884个,丰富了四指马鲅属鱼类遗传结构研究数据。本研究为进一步开展四指马鲅数属物种资源评估与保护、选育、功能基因研究提供基础资料。     

渤海湾曹妃甸深槽海区地形地貌特征及控制因素

通过研究浅层地震剖面、侧扫声纳和水深地形等数据资料,得出,曹妃甸沙岛的岬角地貌引起深槽海域局部潮流流速增大,甸头前沿深槽区以冲刷为主,最大水深达42 m,刷新了渤海湾最大水深记录,深槽部位的侵蚀量最大,深槽南坡冲刷幅度大于北坡,工程建设后期深槽区侵蚀冲刷程度有变小变缓趋势。早期深槽的形成是由于浅部断层受深部构造影响发生阶梯状错断沉陷,海底地层形成古凹槽,但深槽海底地层沉陷速率略大于沉积速率,使得深槽海域长期保持了渤海湾最大的水深环境。初步得出在历史时期曹妃甸深槽经过2万a以上长期存在,深槽的走向经历了南北向-北东向-北西向的转化过程。认为地质构造、古滦河三角洲演变、海洋水动力作用和人类活动等内外营力作用共同控制了曹妃甸海区地貌体系的发育与演化。达到了研究渤海湾曹妃甸深槽海区地形地貌控制因素和深槽的地质演化的目的,为曹妃甸港的规划、运营期维护和未来发展提供科学依据具有重要意义。     

A multiobjective steepest descent method with applications to optimal well control

Multiobjective optimization deals with mathematical optimization problems where two or more objective functions (cost functions) are to be optimized (maximized or minimized) simultaneously. In most cases of interest, the objective functions are in conflict, i.e., there does not exist a decision (design) vector (vector of optimization variables) at which every objective function takes on its optimal value. The solution of a multiobjective problem is commonly defined as a Pareto front, and any decision vector which maps to a point on the Pareto front is said to be Pareto optimal. We present an original derivation of an analytical expression for the steepest descent direction for multiobjective optimization for the case of two objectives. This leads to an algorithm which can be applied to obtain Pareto optimal points or, equivalently, points on the Pareto front when the problem is the minimization of two conflicting objectives. The method is in effect a generalization of the steepest descent algorithm for minimizing a single objective function. The steepest-descent multiobjective optimization algorithm is applied to obtain optimal well controls for two example problems where the two conflicting objectives are the maximization of the life-cycle (long-term) net-present-value (NPV) and the maximization of the short-term NPV. The results strongly suggest the multiobjective steepest-descent (MOSD) algorithm is more efficient than competing multiobjective optimization algorithms.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

Open image in new window

Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

经略21世纪海上丝路:重要航线、节点及港口特征

为了更好地认识21世纪海上丝绸之路(简称"海上丝路"),文章对"海上丝路"涉及的重要航线、节点及港口的地理位置、气候状况、水文特征、商业价值、人文背景等进行梳理。重要航线、节点及港口的使用与管理作为"海上丝路"建设的基础要素,是与造船能力并列的核心资源,三者之间环环相扣,构成"海上丝路"健康运营的完整体系。与沿"海上丝路"国家稳步推进航线、节点及港口的管理、开发与维护,打造坚实的战略支撑点、现代之"海上驿站",是成功实现我国资源多样化、产业走出去、贸易全球化的最佳路径之一,以此为契机,融入现有国际海洋法公约并在践行过程中制定利我的海上政策体制,助力"海之梦"、"中国梦"。