Carbon isotope fractionation between graphite and diamond during shock experiments

Abstract— Carbon isotopic compositions were measured for shock‐produced diamond and shocked graphite formed at peak pressures ranging from 37 to 52 GPa. The δ¹³C values of diamonds produced in a sealed container were generally lower than that of the initial graphite. The differences in the carbon isotopic composition between initial graphite and shocked graphite/diamond may reflect kinetic isotopic fractionation during the oxidation of the graphite/diamond and/or analytical artifacts possibly induced by impurities in the samples. The pressure effect on the isotopic fractionations between graphite and diamond can be estimated from the δ¹³C values of impurity‐free diamonds produced using a vented container from which gases, including oxygen, in pore spaces escaped during or after the diamond formation (e.g., 0.039 ± 0.085‰ at a peak pressure of 52 GPa). Any isotopic fractionation induced by shock conversion of graphite to diamond is too small to be detected in natural shock‐induced diamond‐graphite systems related to terrestrial impact cratering processes.     

丽江高美古台址和2m级望远镜项目(英文)

自 1992年起云南天文台开始了在云南省西北部的天文选址。丽江高美古最终被选择作为未来中国地基天文光学观测的新址点。并且 ,在国家科技部 ,云南省政府 ,以及中科院的支持下 ,2m级天文望远镜项目在 2 0 0 0年 12月获得立项。在文中 ,我们简要的介绍了高美古台址的情况 ,并给出了 2 .4m望远镜的详细情况 ,以及其他相关情况。     

山东省1∶20万水文地质数据库建设的主要内容及开发应用设想

山东省1∶20万空间数据库结合山东省区域水文地质特点,共建立了27个图层,完成12个图幅的建库工作。通过该项工作,为今后进行空间分析和应用研究打下了基础,并为数字水文地质图空间数据库的建设积累了丰富的经验。     

银河系运动学参数的确定

利用 2 0 2个太阳附近疏散星团的视向速度和自行观测资料 ,对太阳的运动和银河系的运动学参数进行了研究。其中 ,距离在 0 .5kpc到 2kpc之间的 12 8个疏散星团对平均太阳运动分量的解算结果是 (u0 ,v0 ,w0 ) =(- 13.8± 1.4 ,- 5 .0± 1.6 ,- 11.6± 2 .9)km/s ;Oort常数和银河系径向运动参数的解算结果分别为 (A ,B) =(16 .9± 1.1,- 11.6± 2 .6 )km·s- 1·kpc- 1及 (C ,D) =(2 .5± 1.1,- 2 .1± 0 .9)km·s- 1·kpc- 1。     

疏散星团NGC6530天区的恒星自行和成员概率

利用上海天文台的照相底片资料,确定了疏散星团NGC6530天区364颗恒星的自行和成员概率,并对有关自行测定的方法、结果和精度等问题作了较为详细的介绍和讨论。使用的底片历元差为87年,全部恒星自行中误差的均方根值为1．09mas/a。     

The equilibrium configuration of rapid rotating compact stars and some gravitational effects

In this paper, the equilibrium configurations of rapid rotating compact stars and some gravitational effects are studied within the general relativity by use of the Harrison-Wheeler equation of state and by the self-consistent field method. Numerical calculations show that the equilibrium configuration of a rotating star is a spheroid. For large spin velocities, say, ω > 3.0 × 10² sec⁻¹ the eccentricity and mass increase very rapidly as the angular velocity increases, for the critical angular velocity of the rotating star, the eccentricity is about 0.7, the increase in mass is about 10–35%. The difference of the gravitational redshifts at the surface of the star caused by rotation, and the difference of the light bending when the beam moves in the direction of rotation or in the opposite direction are obvious.     

Distinct climate change synchronous with Heinrich event one, recorded by stable oxygen and carbon isotopic compositions in stalagmites from China

Uranium-series dating of oxygen and carbon isotope records for stalagmite SJ3 collected in Songjia Cave, central China, shows significant variation in past climate and environment during the period 20-10 ka. Stalagmite SJ3 is located more than 1000 km inland of the coastal Hulu Cave in East China and more than 700 km north of the Dongge Cave in Southwest China and, despite minor differences, displays a clear first-order similarity with the Hulu and Dongge records. The coldest climatic phase since the Last Glacial Maximum, which is associated with the Heinrich Event 1 in the North Atlantic region, was clearly recorded in SJ3 between 17.6 and 14.5 ka, in good agreement in timing, duration and extent with the records from Hulu and Dongge caves and the Greenland ice core. The results indicate that there have been synchronous and significant climatic changes across monsoonal China and strong teleconnections between the North Atlantic and East Asia regions during the period 20-10 ka. This is much different from the Holocene Optimum which shows a time shift of more than several thousands years from southeast coastal to inland China. It is likely that temperature change at northern high latitudes during glacial periods exerts stronger influence on the Asian summer monsoon relative to insolation and appears to be capable of perturbing large-scale atmospheric/oceanic circulation patterns in the Northern Hemisphere and thus monsoonal rainfall and paleovegetation in East Asia. Climatic signals in the North Atlantic region propagate rapidly to East Asia during glacial periods by influencing the winter land-sea temperature contrast in the East Asian monsoon region.     

微型氢化物发生装置在冷原子吸收分光光度法测汞中的应用

采用微型氢化物发生装置-冷原子吸收分光光度法测定了焊锡料及纽扣电池中的汞。在酸性介质中,用硼氢化钾将汞离子还原为汞原子,用载气将汞蒸气导入石英管,原子吸收分光光度计在波长253.7 nm处进行测定。选择了实验条件,对共存离子的干扰等进行了考察。方法的检出限为0.34 ng/mL,11次测定的相对标准偏差(RSD)小于6%,加标回收率为94.4%~104.7%。     

数字矿床模型研究与系统实现

数字矿床模型(DDM)是传统矿床模型的数字化.本文论述了数字矿床模型的概念,提出了其主要组成结构和建模关键技术.在吸收国内外地质领域专家系统建立的经验基础上,将人工智能技术与地理信息技术(WebGIS)相结合,通过构建矿床模型知识库,建立数字矿床模型推理网络结构,并以斑岩型铜矿为例论述了建立数字矿床模型的系统过程.本文是"十一五"期间国家高技术研究发展(863)计划的阶段成果.     

东秦岭二郎坪群中火山成因块状硫化物矿床地质地球化学特征及其成因讨论

二郎坪群是东秦岭造山带重要的组成部分,其火山建造中广泛发育有火山成因块状硫化物(VMS)矿床.文章总结并分析了南阳盆地东、西两侧二郎坪群中3个典型矿床(刘山岩、水洞岭和上庄坪)的研究资料,把二郎坪群VMS矿床分为3类:Zn-Cu型矿床(刘山岩矿床);Zn-Cu型与Zn-Pb-Cu型矿床(水洞岭矿床);Zn-Pb-Cu型矿床(上庄坪矿床).从刘山岩矿床到水洞岭矿床,再到上庄坪矿床,铜的含量减少,铅的含量增多.二郎坪群VMS矿床矿石富集LREE、Ce负异常及Eu正异常,说明矿床为热液成因.石英和重晶石中流体包裹体的氢氧同位素特征表明,成矿流体主要来自建造水,南阳盆地以西,矿床成矿流体中伴有较多古大气降水.矿石的硫同位素特征说明,二郎坪群VMS矿床中的硫可能为地幔岩浆硫和海水硫的混合硫.围岩与矿石的铅同位素组成基本一致,说明矿石和围岩可能来源于相似的物源区,成矿元素主要来源于地幔或下地壳深源物质,而水洞岭矿床明显有上地壳浅源物质的混染.研究表明,南阳盆地以西的水洞岭和上庄坪矿床可能形成于大陆边缘海环境,盆地规模较小,受陆源物质影响较大;而南阳盆地以东的刘山岩矿床可能形成于远洋盆地,盆地到达成熟阶段.用地震泵模式可解释二郎坪群VMS矿床的成因机制.