Garnet growth at high- and ultra-high pressure conditions and the effect of element fractionation on mineral modes and composition

In this paper we show that thermodynamic forward modelling, using Gibbs energy minimisation with consideration of element fractionation into refractory phases and/or liberated fluids, is able to extract information about the complex physical and chemical evolution of a deeply subducted rock volume. By comparing complex compositional growth zonations in garnets from high-and ultra-high pressure samples with those derived from thermodynamic forward modelling, we yield an insight into the effects of element fractionation on composition and modes of the co-genetic metamorphic phase assemblage. Our results demonstrate that fractionation effects cause discontinuous growth and re-crystallisation of metamorphic minerals in high pressure rocks. Reduced or hindered mineral growth at UHP conditions can control the inclusion and preservation of minerals indicative for UHP metamorphism, such as coesite, thus masking peak pressure conditions reached in subducted rocks.Further, our results demonstrate that fractional garnet crystallisation leads to strong compositional gradients and step-like zonation patterns in garnet, a feature often observed in high-and ultra-high pressure rocks. Thermodynamic forward modelling allows the interpretation of commonly observed garnet growth zonation patterns in terms of garnet forming reactions and the relative timing of garnet growth with respect to the rock's pressure–temperature path. Such a correlation is essential for the determination of tectonic and metamorphic rates in subduction zones as well as for the understanding of trace element signatures in subduction related rocks. It therefore should be commonplace in the investigation of metamorphic processes in subduction zones.     

Evaluation of Probe-Induced Flow Distortion of Campbell CSAT3 Sonic Anemometers by Numerical Simulation

The Campbell CSAT3 sonic anemometer is one of the most popular instruments for turbulence measurements in basic micrometeorological research and ecological applications. While measurement uncertainty has been characterized by field experiments and wind-tunnel studies in the past, there are conflicting estimates, which motivated us to conduct a numerical experiment using large-eddy simulation to evaluate the probe-induced flow distortion of the CSAT3 anemometer under controlled conditions, and with exact knowledge of the undisturbed flow. As opposed to wind-tunnel studies, we imposed oscillations in both the vertical and horizontal velocity components at the distinct frequencies and amplitudes found in typical turbulence spectra in the surface layer. The resulting flow-distortion errors for the standard deviations of the vertical velocity component range from 3 to 7%, and from 1 to 3% for the horizontal velocity component, depending on the azimuth angle. The magnitude of these errors is almost independent of the frequency of wind speed fluctuations, provided the amplitude is typical for surface-layer turbulence. A comparison of the corrections for transducer shadowing proposed by both Kaimal et al. (Proc Dyn Flow Conf, 551–565, 1978) and Horst et al. (Boundary-Layer Meteorol 155:371–395, 2015) show that both methods compensate for a larger part of the observed error, but do not sufficiently account for the azimuth dependency. Further numerical simulations could be conducted in the future to characterize the flow distortion induced by other existing types of sonic anemometers for the purposes of optimizing their geometry.     

The maximum Ice Age (LGM) glaciation of the Central- and South Karakorum: an investigation of the heights of its glacier levels and ice thicknesses as well as lowest prehistoric ice margin positions in the Hindukush, Himalaya and in East-Tibet on the Minya Konka-massif

A continuing prehistoric ice stream network between the Karakorum main crest and the Nanga Parbat massive has been evidenced, which, flowing down from the current Baltoro- and Chogolungma glaciers and filling the Shigar valley as well as the Skardu Basin, has flowed together with the Gilgit valley glacier to a joint Indus parent glacier through the Indus gorge. The ice stream network received an influx by a plateau glacier covering the Deosai plateau, which was connected through outlet glaciers to the ice filling of the Skardu Basin and the Astor glacier at the Nanga Parbat, as well as to the lower Indus glacier. The field observations introduced here in part confirm the results as to the Ice Age glacier surface area of Lydekker, Oestreich and Dainelli, but go beyond it. In additon, a reconstruction of the surface level of this ice stream network and its glacier thicknesses up to the highest regions of the present-day Karakorum valley glaciers has been carried out for the first time. In the area under investigation the Karakorum ice stream network showed three ice cupolas, culminating at an altitude of 6200–6400 m. Between the mountain groups towering 1000–2000 m higher up, they communicated with each other over the transfluence passes in a continuous glacier surface without breaks in slope. In the Braldu- and Basna valley ice thicknesses of 2400–2900 m have been reached. In the Skardu Basin, where the glacier thickness had decreased to c. 1500–1000 m, the ELA at an ice level of 3500-3200 m asl had fallen short to the extent that from here on down the Indus glacier a surface moraine cover has to be suggested. However, 80% of the surface of the ice stream network was devoid of debris and had an albedo of 75-90%. The lowest joint glacier terminus of the ice stream network was situated - as has already been published in 1988 – in the lower Indus valley at 850–800 m asl. The reconstructed maximum extension of the ice stream network has been classified as belonging to the LGM in the wider sense (60–18 Ka BP). Four Late Glacial glacier positions (I–IV), with a decreasing ice filling of the valleys, have been differentiated, which can be locally recognized through polish lines and lateral moraine ledges. The valley (trough-) flanks with their ground moraine covers, oversteepened by glacier abrasion, have been gravitationally destroyed by crumblings, slides and rock avalanches since the deglaciation, so that an interglacial fluvial-, i.e. V-shaped valley relief has been developed from the in part preserved glacial relief. The contrast of the current morphodynamics with regard to the preserved forms is seen as an indication of the prehistorically completely different - namely glacigenic – valley development and the obvious rapidity of this reshaping at still clearly preserved glacial forms provides evidence of their LGM-age. In an additional chapter the lowest ice margin positions, so far unpublished, are introduced, which have been reconstructed for the Hindukush, Central Himalaya and on the eastern margin of Tibet.     

Modular development of an inline monitoring system for waterborne pathogens in raw and drinking water

The state-of-the-art monitoring of drinking water hygiene is based on the cultivation and enumeration of indicator bacteria. Despite its proven reliability, this approach has the disadvantages of being (a) relatively slow and (b) limited to a small number of indicator bacteria. Ideally, alternative methods would be less time-consuming while providing information about a larger set of hygienically relevant microorganisms including viruses. In this paper, we present insights into the design of a modular concentration and detection system for bacteria, bacteriophages and viruses. Following further validation, this or similar techniques have the potential to extend and speed up the monitoring of raw and drinking water hygiene in the future. The system consists of different modules for the concentration of microorganisms, an amplification and detection unit that includes a module for the differentiation between live and dead microorganisms, and an automated system for decision support and self-diagnosis. The ongoing testing under controlled laboratory conditions and real-life conditions in the water supply industry yields further system improvements. Moreover, the increased sensitivity and broader range of microbiological parameters emphasize the need for a reconsideration of the currently used criteria for the assessment of (drinking) water hygiene.     

A multi-parameter extension of temperature/salinity diagram techniques for the analysis of non-isopycnal mixing

The technique of water mass analysis based on temperature-salinity curves is extended to more than three water masses (or water masses defined by temperature-salinity curves rather than points) by including one or more additional parameters and solving the equations of linear mixing without additional assumptions. The oceanographical significance of the result is studied by means of examples. It is shown that the method is particularly useful for investigations of mesoscale mixing as observed in frontal zones where interleaving and intrusions are commonly observed, and that it can be used for obtaining bulk estimates of the impact of non-isopycnal, small-scale mixing events on the mesoscale fields. Possible parameters are discussed and sources of errors reviewed. Examples are used to show that major nutrients can be used as parameters to detect non-isopycnal mixing although limitations in the historical data and low data accuracy lead to considerable error bounds at present. It is argued that introduction of continuous flow analysis techniques and continuous vertical profiling in marine chemistry will greatly improve the potential of the method.     

Organic carbon content in surface sediments—defining regional provinces

Approaches to quantify the organic carbon accumulation on a global scale generally do not consider the small-scale variability of sedimentary and oceanographic boundary conditions along continental margins. In this study, we present a new approach to regionalize the total organic carbon (TOC) content in surface sediments (<5 cm sediment depth). It is based on a compilation of more than 5500 single measurements from various sources. Global TOC distribution was determined by the application of a combined qualitative and quantitative-geostatistical method. Overall, 33 benthic TOC-based provinces were defined and used to process the global distribution pattern of the TOC content in surface sediments in a 1°×1° grid resolution. Regional dependencies of data points within each single province are expressed by modeled semi-variograms. Measured and estimated TOC values show good correlation, emphasizing the reasonable applicability of the method. The accumulation of organic carbon in marine surface sediments is a key parameter in the control of mineralization processes and the material exchange between the sediment and the ocean water. Our approach will help to improve global budgets of nutrient and carbon cycles.     

HESS observations of extragalactic objects

The HESS experiment (High Energy Stereoscopic System), consisting of four imaging atmospheric Cherenkov telescopes (IACTs) in Namibia, has observed many extragalactic objects in the search for very high energy (VHE) γ-ray emission. These objects include active galactic nuclei (AGN), notably Blazars, Seyferts, radio galaxies, starburst galaxies and others. Beyond the established sources, γ-ray emission has been detected for the first time from several of these objects by HESS, and their energy spectra and variability characteristics have been measured. Multi-wavelength campaigns, including X-ray satellites, radio telescopes, and optical observations, have been carried out for AGNs, in particular for PKS 2155-304, H 2356-309 and 1ES 1101-232, for which the implications concerning emission models are presented. Also results from the investigations of VHE flux variability from the giant radio galaxy M 87 are shown. For the HESS Collaboration.     

Investigating young water fractions in a small Mediterranean mountain catchment: Both precipitation forcing and sampling frequency matter

The proportion of water younger than 2–3 months (young water fraction, F_yw) has become increasingly investigated in catchment hydrology. F_yw is typically estimated by comparing seasonal tracer cycles in precipitation and streamflow, through water sampling. However, some open research questions remain, such as: (i) whether part of the summer precipitation should be discarded because the high evapotranspiration demand, (ii) how well F_yw serves as a metric to compare catchments, and (iii) how sampling frequency affects F_yw estimates. To address these questions, we investigated F_yw in soil-, ground- and stream waters for the small Mediterranean Can Vila catchment. Rainfall was sampled at 5-mm intervals. Mobile soil water and groundwater were sampled fortnightly. Stream water was sampled depending on flow at variable time intervals (30 min to 1 week). Over 58 months, this sampling provided 1,529 δ¹⁸O determinations. Isotopic analyses results led us to include summer precipitation in the input signal. We found the highest F_yw in mobile soil waters (34%), while this was almost zero for groundwater except during wet periods. For stream waters, F_yw depended on the discharge variations, so that the flow-weighted young water fraction () was 22.6%, whereas the time-weighted F_yw was just 6.2%. Both and its discharge sensitivity (S_d) varied when different 12-month sampling periods were investigated. The young water fraction that would be obtained from a virtual thorough sampling () was estimated from the S_d and the observed stream flow. This showed an underestimation of by 25% for the frequent dynamic sampling and 66% for weekly sampling, due to missing high flows. Our results confirm that F_yw and its discharge sensitivity are metrics very sensitive to meteorological forcing during the analysed period. Thus, comparisons between catchments need long-term mean annual values and their variability. Our findings also support the dependence of F_yw estimates on the sampling rate and show the advantages of flow-weighted analysis. Finally, catchment water turnover investigations should be accompanied by the analysis of flow duration curves.