Geological, mineralogical and geochemical characteristics of the Radzimowice Au–As–Cu deposit from the Kaczawa Mountains (Western Sudetes, Poland): an example of the transition of porphyry and epithermal style

The sheeted quartz–sulfide veins of the Radzimowice Au–As–Cu deposit in the Kaczawa Mountains are related to Upper Carboniferous post-collisional potassic magmatism of the composite Zelezniak porphyry intrusion. Multiple intrusive activity ranges from early calc-alkaline to sub-alkaline and alkaline rocks and is followed by multiple hydrothermal events. Early crustally derived dacitic magma has low mg# (<63) and very low concentrations of mantle-compatible trace elements, high large-ion lithophile elements (LILE), moderate light rare-earth elements (LREE), and low high-field-strength elements (HFSE). Later phases of more alkaline rocks have higher mg# (60–70), and LILE, LREE, and HFSE characteristics that indicate mafic magma contributions in a felsic magma chamber. The last episode of the magmatic evolution is represented by lamprophyre dikes which pre-date ore mineralization and are spatially related to quartz–sulfide–carbonate veins. The dikes consist of kersantite and spessartite of calc-alkaline affinity with K₂O/Na₂O ratios of 1.1–1.9, mg# of 77–79, and high abundances of mantle-compatible trace elements such as Cr, Ni, and V. They have high LILE, low LREE, and low HFSE contents suggesting a subduction-related post-collisional arc-setting. The mineralization started with arsenopyrite that was strongly brecciated and overprinted by multiple quartz–carbonate phases associated with base-metal sulfides and Au–Ag–Bi–Te–Pb±S minerals. The sulfur isotope composition of sulfides ranges from –1.1 to 2.8 ³⁴S and suggests a magmatic source. At least two generations of gold deposition are recognized: (1) early refractory, and (2) subsequent non-refractory gold mineralization of epithermal style. Co-rich arsenopyrite with refractory gold and pyrite are the most abundant minerals of the early stage of sulfide precipitation. Early arsenopyrite formed at 535–345°C along the arsenopyrite–pyrrhotite–loellingite buffer and late arsenopyrite crystallized below 370°C along the arsenopyrite–pyrite buffer. Non-refractory gold associated with base-metal sulfides and with Bi–Te–Ag–Pb–S mineral assemblages has an average fineness of about 685, and is represented by electrum of two generations, and minor maldonite (Au₂Bi). Fluid inclusions from various quartz generations co-genetic with base-metal sulfides and associated with carbonates, tellurides and non-refractory gold indicate fluids with moderate salinity (9–15 wt% NaCl equiv.) and a temperature and pressure drop from 350 to 190°C and 1.2 to 0.8 kbar, respectively. According to the result of the sulfur isotope fractionation geothermometer the temperature of base-metal crystallization was in the range from 322 to 289°C. Preliminary results of oxygen isotope studies of quartz from veins indicate a gradual increase in the proportion of meteoric water in the epithermal stage. The gold to silver ratio in ore samples with >3 ppm Au is about 1:5 (geometric mean). Hydrothermal alteration started with sericitization, pyritization, and kaolinitization in vein selvages followed by alkaline hydrothermal alteration of propylitic character (illitization and chloritization), albitization and carbonatization. The mineralization of the Radzimowice deposit is considered as related to alkaline magmatism and is characterized by the superposition of low-sulfidation epithermal mineralization on higher-temperature and deeper-seated mesothermal/porphyry style.Editorial handling: B. Lehmann     

To what extent can atmospheric deposition influence the natural background of metals in ground waters? A case study in the Czech Republic

In harmony with requirements of Water Framework Directive the natural backgrounds of selected metals were established on the territory of Czech Republic. This paper is intended to provide characteristics and results of testing methods focused on quantification of the impacts of anthropogenic activities based on data of regional monitoring and their separation from acid atmospheric deposition including an appropriate discussion regarding the natural backgrounds of relevant metals. The results indicate that even in regions extremely affected by acid atmospheric deposition as is the territory of the Czech Republic this acid deposition will not have direct impact on the quality of ground waters on a regional scale. Consequently, the proved changes in quality of ground waters seem to have been caused by secondary processes, specifically by mobilization of metals in a rock environment due to increased acidity.     

OSL and ESR studies of Aeolian quartz from the Upper Pleistocene loess sequence of Nussloch (Germany)

As part of a chronological study of the famous Upper Pleistocene Nussloch (Germany) loess sequence, three samples were collected to check the applicability of palaeodosimetric dating methods (OSL and ESR) to quartz grains. The ESR-multicentre method showed a partial bleaching of the ESR centers in aeolian sands. This partial bleaching was also observed by OSL. Laminated loess seemed to be sufficiently bleached but showed a large scatter of the doses, which we ascribed to heterogeneous responses of the luminescent grains to the SAR protocol. Ages could nevertheless be calculated for the three samples and were found to be somewhat older than the IRSL and ¹⁴C ages obtained for the same layers of the laminated loess.     

The Solar Flare of November 4, 2001, and Its Manifestations in Energetic Particles from Coronas-F Data

Based on X-ray, gamma-ray, and charged-particle measurements with several instruments onboard the Coronas-F satellite and on ACE and GOES experimental data presented on the Internet, we investigate the parameters of the solar flare of November 4, 2001, and the energetic-particle fluxes produced by it in circumterrestrial space. The increase in relativistic-electron fluxes for about 1.5 days points to a moving source (shock front). The structure of the energetic-particles fluxes in the second half of November 5, 2001, can be explained by the passage of the coronal mass ejection that was ejected on November 1, 2001, and that interacted with the shock wave from the flare of November 4, 2001.     

Eagle Nebula Pillars: From Models to Observations

Over the past few years, our group has been developing hydrodynamic models to simulate formation of the Eagle Nebula pillars. The true test of any model is, of course, how well it can reproduce the observations. Here, we discuss how we go about testing our models against observations. We describe the process by which we “observe” the model data to create synthetic maps. We show an example of this technique using one of our model runs and compare the resultant synthetic map to the real one.     

Inferring the emission regions for different kinds of gamma‐ray bursts

Using a theoretical model describing pulse shapes, we have clarified the relations between the observed pulses and their corresponding timescales, such as the angular spreading time, the dynamic time as well as the cooling time. We find that the angular spreading timescale caused by curvature effect of fireball surface only contributes to the falling part of the observed pulses, while the dynamic one in the co‐moving frame of the shell merely contributes to the rising portion of pulses provided the radiative time is negligible. In addition, the pulses resulted from the pure radiative cooling time of relativistic electrons exhibit properties of fast rise and slow decay (a quasi‐FRED) profile together with smooth peaks. Besides, we interpret the phenomena of wider pulses tending to be more asymmetric to be a consequence of the difference in emission regions. Meanwhile, we find the intrinsic emission time is decided by the ratios of lorentz factors and radii of the shells between short and long bursts. Based on the analysis of asymmetry, our results suggest that the long GRB pulses may occur in the regions with larger radius, while the short bursts could locate at the smaller distance from central engine. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Evaluation of Interactions Between Oilfield Chemicals and Reservoir Rocks

Natural Resources Research - Sand failure and production occurs when the formation stress exceeds the strength of the formation, which is derived majorly from the natural material that cements the...