A field comparison of two methods for the determination of copper complexation: Bacterial bioassay and fixed-potential amperometry

Complexation of copper added to seawater was determined by bacterial bioassay and fixedpotential amperometry. Consistent results were obtained by these two fundamentally different methods. The results of this study support the validity of both techniques and the field applicability of fixed-potential amperometry.The intercomparison studies were performed on samples collected at the N.Y.C. sewage sludge dumpsite and in relatively unpolluted coastal waters. In this limited study, the calculated free cupric ion concentrations at ambient total copper concentrations were similar at both sites.     

Benthic nutrient fluxes along the Laurentian Channel: Impacts on the N budget of the St. Lawrence marine system

Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L⁻¹), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L⁻¹, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m⁻² d⁻¹ in the hypoxic western LSLE to 100 μmol m⁻² d⁻¹ in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m⁻² d⁻¹, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 10⁶ t N, yielding an almost balanced N budget for the SL marine system.     

Selection of sand models and identification of parameters using an enhanced genetic algorithm

Numerous constitutive models of granular soils have been developed during the last few decades. As a consequence, how to select an appropriate model with the necessary features based on conventional tests and with an easy way of identifying parameters for geotechnical applications has become a major issue. This paper aims to discuss the selection of sand models and parameters identification by using genetic algorithm. A real‐coded genetic algorithm is enhanced for the optimization with high efficiency. Models with gradually varying features (elastic‐perfectly plastic modelling, nonlinear stress–strain hardening, critical state concept and two‐surface concept) are selected from numerous sand models as examples for optimization. Conventional triaxial tests on Hostun sand are selected as the objectives in the optimization. Four key points are then discussed in turn: (i) which features are necessary to be accounted for in constitutive modelling of sand; (ii) which type of tests (drained and/or undrained) should be selected for an optimal identification of parameters; (iii) what is the minimum number of tests that should be selected for parameter identification; and (iv) what is the suitable and least strain level of objective tests to obtain reliable and reasonable parameters. Finally, a useful guide, based on all comparisons, is provided at the end of the discussion. Copyright © 2015 John Wiley & Sons, Ltd.     

The position of the lowest levels in the boundary layer of atmospheric circulation models

Abstract

The error associated with the position of the lowest wind level in atmospheric boundary‐layer modelling is studied in connection with vertical resolutions typical of parametrization schemes for atmospheric circulation models. The test case is the neutrally stratified steady‐state boundary layer. Finite‐difference and finite‐element schemes of two types are used: in one case the lowest wind level is centred with respect to the surface and the lowest internal level where the shear stress is calculated, in the other case the lowest wind level is set very close to the surface (5 m). It is found that schemes of the latter type underestimate the friction force at the lowest level and consequently overestimate the wind and the surface stress. This error is largest at low resolution since it is due to the uncentring of the lowest wind level with respect to the stress levels. The error in schemes of the former type is different, and is associated with the determination of the surface stress from a wind at a height that may exceed the extent of the surface layer. For all neutral cases, this error can be made small by adding a corrective term to the traditional logarithmic formulation. This paper shows that considerably more error is generated by uncentred differencing than by deepening the surface layer.     

Internal erosion of chemically reinforced granular materials: a mathematical modeling approach

Internal erosion (IE) affects the stability of natural and reinforced materials by causing instability within their granular structure. The dislodgement and transport of eroded particles affect both the particulate concentration of eroding fluid and the pore network of eroded material. In this study, we examined these modifications using a transport model with a finite element code. First, IE tests on chemically reinforced sand columns were performed to obtain information about eroded material loss of mass, particulate concentration of effluent, porosity and permeability modifications, and existing IE stages. Second, based on experimental results, a mathematical one‐dimensional model has been formulated to monitor the evolution and spatial distribution of erodible solids, fluidized particles, porosity, permeability, and seepage stresses. The model consists of a set of coupled nonlinear differential equations solved in sequence. It provides valuable information about the extent and the dynamics of structural changes, which can be used to estimate an IE time for the hydraulic work to reach failure. Copyright © 2011 John Wiley & Sons, Ltd.     

Distribution and abundance of ichthyoplankton in the Manicouagan River estuary,a tributary of the lower St. Lawrence estuary

The species composition and relative abundance of ichthyoplankton were investigated during summer 1986 at four stations along the salinity gradient in the Manicouagan River estuary, a tributary of the lower St. Lawrence estuary. Physical characteristics of water masses indicated the presence of a strong saline front (>10‰ per km) delineating the freshwater and marine section of the Manicouagan estuary. The estuary supports a depauperate ichthyoplankton community, including four species of pelagic fish eggs and eight species of fish larvae. Species richness increased with salinity. The ichthyoplankton fauna can be divided into two distinct groups: freshwater and marine. These two groups result initially from spawning preferences exhibited by the different species abundance of freshwater larvae was maximal at the head of the estuary and marine larvae were most abundant at the most saline station. The length frequency distribution suggests that marine larvae are not effectively retained within the estuary. The Manicouagan estuary cannot be considered as a major spawning site nor an important nursery zone for any fish found in this area.     

Detection of turbulent coherent motions in a forest canopy part I: Wavelet analysis

Turbulence measurements performed at high frequencies yield data revealing intermittent and multi-scale processes. Analysing time series of turbulent variables thus requires extensive numerical treatment capable, for instance, of performing pattern recognition. This is particularly important in the case of the atmospheric surface layer and specifically in the vicinity of plant canopies, where largescale coherent motions play a major role in the dynamics of turbulent transport processes. In this paper, we examine the ability of the recently developedwavelet transform to extract information on turbulence structure from time series of wind velocities and scalars. It is introduced as a local transform performing a time-frequency representation of a given signal by a specific wavelet function; unlike the Fourier transform, it is well adapted to studying non-stationary signals. After the principles and the most relevant mathematical properties of wavelet functions and transform are given, we present various applications of relevance for our purpose: determination of time-scales, data reconstruction and filtering, and jump detection. Several wavelet functions are inter-compared, using simple artificially generated data presenting large-scale features similar to those observed over plant canopies. Their respective behaviour in the time-frequency domain leads us to assign a specific range of applications for each.     

Evidence of an early alteration process driven by magmatic fluid in Mururoa volcano

Evidence for a deuteric alteration process induced by a magmatic fluid has been found in the feeder zone of the Mururoa volcano (French Polynesia). Within the dikes, where basaltic glass does not show any evidence of pervasive alteration, vesicles are filled with dioctahedral smectites and calcite, while olivine phenocrysts are replaced by dioctahedral smectites, ankerite and calcite.The ¹³C signature of carbonates, the carbon and H₂O content of the whole rocks and their impoverishment in deuterium are compatible with the presence of magmatic CO₂ during the crystallization of intruding lavas and exclude contamination by seawater. Mass balance calculations on selected thin sections photographs of partly filled up vesicles and replaced olivine crystals, constrain, assuming a closed system interaction, the chemical composition of the initial fluid and the respective amounts of the initial solid phases involved in the alteration process. Thermodynamic modelings using the EQ3/6 software package correctly predict the mineralogic, chemical and isotopic exchanges accompanying alteration, thus validating the closed system assumption. The model which allows prediction of the influence of CO₂ on the alteration products, shows that, above a 0.25 CO₂ mole fraction in the initial fluid, the alteration is entirely controlled by the chemical composition of the initial solid phases. The presence of CO₂ implies the precipitation of dioctahedral smectites and carbonates instead of the magnesian smectites commonly observed in CO₂-free systems.The Mururoa feeder zone shows alteration features typical of a closed system interaction between the basaltic rock and a magmatic fluid in which seawater did not take part.     

Middle-Late Pleistocene polycyclic evolution of a stable coastal area (southern Apulia, Italy)

The Otranto–Leuca coastal tract is marked by the presence of numerous sea caves placed close to present sea level. They are located generally at the back of a shore platform covered by a sequence of breccia deposits, marine sediments and speleothems. At Grotta di Masseria dell'Orte, marine cemented sands rest on a narrow shore platform at about 6.2 m above mean sea level and are covered by speleothems older than 185 ka. At Grotta del Diavolo, which is mostly filled by breccia deposits, three beach levels have been detected at about 3.0, 3.5 and 5.9 m above msl. They are either covered by or overlie speleothems that yield an U/Th age of 340, 78 ka and between 170.3 and 146.5, respectively. Geomorphological evidence and radiometric ages indicate that the area after a period of uplift has been tectonically stable since the last part of the Middle Pleistocene so that marine landforms close to the present shoreline underwent a polycyclic evolution. The sedimentary fills of sea caves formed during Middle-Late Pleistocene glacial stages, when arid or semiarid conditions promoted the removal of regolith and the development of thick breccia deposits. During Marine Isotope Stages (MIS) 9.3, 5.5 and 5.1, cave sediments were partially eroded whereas beach layers and related speleothems developed. These are, in fact, the only marine isotope stages marked by a sea level position which in this Mediterranean region was either close to, or slightly higher than, the present one.     

A structural model for the seismicity of the Arudy (1980) epicentral area (Western Pyrenees, France)

The Western Pyrenees presents a diffuse and moderate ( M ≤ 5.7) instrumental seismicity. It nevertheless historically suffered from strong earthquakes (I = IX MSK). The seismic sources of these events are not yet clearly identified. We focus on the Arudy (1980) epicentral area ( M = 5.1) and propose here the reactivation of early Cretaceous normal faults of the Iberian margin as a potential source. The late Cretaceous inversion of this basin, first in a left-lateral strike-slip mode and then in a more frontal convergence, resulted in a pop-up geometry. This flower structure attests of the presence of a deep crustal discontinuity.
The present-day geodynamic arrangement suggests that this accident is reactivated in a right lateral mode. This reactivation leads to a strain partitioning between the deep discontinuity that accommodates the lateral component of the motion and shallow thrusts, rooted on this discontinuity. These thrusts accommodate the shortening component of the strain. The distribution of the instrumental seismicity fits well the structural model of the Arudy basin. Whatever the compressive regional context, the structural behaviour of the system explains too the extensive stress tensor determined for the Arudy crisis if we interpret it in terms of strain ellipsoid. Indeed numerical modelling has shown that this concomitant activity of strike-slip and thrust faulting results in an extensive component that can rise 50 per cent of the finite strain.
We identify too a 25–30 km long potential seismic source for the Arudy area. The size of the structure and its potential reactivation in a strike-slip mode suggest that a maximum earthquake magnitude of ∼6.5 could be expected. The extrapolation of this model at the scale of the Western Pyrenees allows to propose other potential sources for major regional historical earthquakes.