Les rhyolites hyperalcalines (pantellérites) du lac Tchad. Composition et signification tectonomagmatiqueThe peralkaline rhyolites (pantellerites) of the Lake Chad. Composition and tectonomagmatic significance

Remnants of rhyolite lava-dome and of alkaline microgranite extrusions emerge, as inselbergs, in the alluvial plain, south of Lake Chad. The peralkaline, arfvedsonite- and acmite-bearing rhyolites are determined as pantellerites. They can be related to a tectonomagmatic stage, dated of the Late Cretaceous, of the western central Africa rift system. They may constitute the NNE extension of a N50° to 30° elongated succession of small alkaline complexes, from the Gulf of Guinea to the North-Cameroon, which initiated the magmatic activity of the Cameroon Line. To cite this article: J.-P. Vicat et al., C. R. Geoscience 334 (2002) 885–891.     

Investigation of the pyrolytic liberation of molecular nitrogen from Palaeozoic sedimentary rocks

Open-system non-isothermal pyrolysis up to 1,200°C in combination with elemental analysis was used to study the thermal liberation of molecular nitrogen (N₂) from sedimentary rocks and kerogen concentrates of Palaeozoic age from the Central European Basin system and an Eocene shale (Liaohe Basin, China) with a high content (36%) of ammonium feldspar (buddingtonite). The N/C_org (atomic) ratios of the kerogen concentrates ranged from 0.005 to 0.014, which represents the range commonly observed for coals. Bulk N/C_org ratios of the Palaeozoic shales extended from 0.035 to 0.108, indicating the presence of significant amounts of inorganic nitrogen. Namurian A and A-B (CnA; CnA-B) samples typically exhibited the earliest onset of N₂ generation with intense, characteristic peaks around 600°C. N₂ liberation from the buddingtonite-rich sample occurred at higher temperatures, with a broad peak around 700°C. Pyrograms of the kerogen concentrates showed no or strongly reduced N₂ generation in the 500–700°C range. On-line isotope-specific analysis of the pyrolytically liberated N₂ on one sample revealed a variability of ∼10‰ in the δ¹⁵N values and a steady increase in δ¹⁵N with temperature during the main phase of N₂ generation.     

Failles normales Paléocène à Lutétien en zone sud-pyrénéenne (Aragon,Espagne) et flexuration de la plaque ibérique

Close to the South Pyrenean thrust front, synsedimentary normal faults develop in the ‘Garumnian’ continental deposits (Maastrichtian to Palaeocene) and in the carbonate platform during the Lutetian. During the Lutetian, this deformation is accompanied by a change in the sedimentation characterized by the deposit of two series of laminated limestones associated to monogenetic breccias. These normal faults would have formed at the bending of the Iberian plate subducting under Europe. They may also be considered as the starting point for the megaturbidites that deposited further north in the Eocene turbiditic basin. To cite this article: Y. Hervouët et al., C. R. Geoscience 337 (2005).     

Shallow karst exploration using MT-VLF and DC resistivity methods1

A geophysical test was carried out over a well-located and fairly embedded karstic conduit. The MT-VLF method was selected because of its high resolution and its ability to provide a resistivity parameter sensitive to water and Clay. This method was used together with DC resistivity methods which allow vertical adjustment of the VLF data and show consistency between the investigation and target depths. After correcting the deformations due to the polarization of the primary field, the MT-VLF data show clearly, in the Central part of the site, that the conduit does not coincide with an anomaly axis but coincides with the boundary between a conductive area and a resistive area. 2D modelling confirms that direct detection of the conduit is not feasible and that the conduit is located close to a conductive zone corresponding to a completely Clay-filled fractured zone. This situation was observed on the whole site and the conduit seemed systematically to thread its way between the conductive zones to join the outlet. The distribution of the conductive fractured zones and the direction of the hydraulic gradient were two important elements in predicting the location of the conduits. A 3D approach would increase the probability of finding the conduits in such a case.     

Solid-state C NMR analysis of size and density fractions of marine sediments: Insight into organic carbon sources and preservation mechanisms

Burial of organic carbon (OC) in ocean sediments acts as the ultimate long-term sink for both terrestrial and marine carbon, however, the mechanisms controlling the preservation of this carbon are poorly understood. To better understand these mechanisms, we applied solid-state ¹³C nuclear magnetic resonance (NMR) spectroscopy, along with elemental, stable carbon isotopic (δ¹³C) and lignin phenol analyses, to size and density fractions of sediments influenced by either mixed terrestrial and marine OC inputs (Washington Coast slope) or dominantly marine inputs (Mexican Margin). Elemental, isotopic and lignin analyses all reveal that within the Washington Coast sediment, the OC mixes linearly between nitrogen-poor and ¹³C-depleted, lignin-rich OC in the large and light fractions and nitrogen-rich and ¹³C-enriched, lignin-poor OC in the small and dense fractions, suggesting that this sediment contains a two-component mixture of terrestrial vascular plant- and marine-derived OC. The integral areas of each of seven NMR spectral regions in the different samples trend linearly when plotted versus δ¹³C signature, with most R² values of 0.78 or greater, demonstrating that the NMR spectra of the two sources of carbon also mix linearly between the two endmembers. The terrestrial endmember in this sediment appears to be dominated by lignin and black carbon whereas the source of the marine endmember is less clear from the NMR spectra. In contrast, all of the analyses indicate that OC in the Mexican Margin sediment fractions is homogenous and derives almost exclusively from marine sources. It appears that selective preservation of (bio)chemically recalcitrant lignin and black carbon is the primary mechanism of preservation of terrestrial OC, whereas mineral-protection is the dominant mechanism preserving marine OC in the Washington coast sediment. There is little evidence showing that either preservation mechanism functions in the Mexican Margin sediments.     

Spatial and temporal relationships between compression, strike-slip and extension in the Central Venezuelan Andes: Clues for Plio-Quaternary tectonic escape

The geometry of tectonic structures, attributed to the Neogene–Quaternary time interval, is described in the active setting of the Venezuelan Andes. Our methodology is based on the analysis of radar satellite and Digital Elevation Model imagery, complemented by structural fieldwork and the compilation of seismotectonic data to make a structural analysis on a regional scale. Radar images provide first class data for morphostructural analysis in areas of dense vegetation and frequent cloud covering, like the Venezuelan Andes. We focused our analysis in the Burbusay–Río Momboy and Boconó faults corner located in the central part of the belt.We have described three stages of deformation during the Neogene–Quaternary. The first one, Mio-Pliocene in age, is a NW–SE compression responsible for the uplift of the Venezuelan Andes. The second tectonic stage corresponds to a strike-slip regime of deformation marked by shearing along the Boconó, Burbusay and Valera faults, which separates two triangular wedges in the larger Trujillo block. This strike-slip faulting-dominated compressional-extensional tectonic regime allowed the Trujillo crustal block to move towards the NE. Wrenching has therefore started at some point between the Pliocene and the Quaternary. These two tectonic events are consistent with ongoing strain partitioning in the Venezuelan Andes. The third stage corresponds to extensional deformation limited to the Trujillo block and is still active today. Extension is associated with the motion of crustal blocks moving relative to each other, probably above the upper-lower crust boundary. Such extensional deformation can be understood considering that the crust extends and stretches at the same time as it moves towards the NE. The combination of both horizontal lateral motion and extension is characteristic of a tectonic escape process. The northeastward escape of the Trujillo block, which belongs to the larger North Andes block, occurs as a result of the combination of the NW–SE intracontinental convergence between the South-American plate and the Maracaibo block, and the presence to the north of the Caribbean oceanic plate considered as a free boundary. We have showed that the kinematics of the Caribbean plate offers not only a favorable environment, but may also be considered as the driving force of the tectonic escape of the North Andes block.     

Quantum-mechanical calculation of the vibrational spectrum of beryl (Al4Be6Si12O36) at the Γ point

A quantum-mechanical calculation of the zone-centre phonon spectrum of beryl has been performed, by using an hybrid HF/DFT Hamiltonian (B3LYP). An excellent agreement with the experiment has been obtained, being the difference between the calculated and the experimental vibrational frequencies (Raman, IR-TO and IR-LO) less than 5 cm^?1 on average. In the few cases where a relatively large disagreement between calculated and experimental data is observed, an explanation can be found which attributes the reason of the discrepancies to the experimental data rather than to the calculated ones. The calculation (i) allows the identification, in the experimental spectra, of the peaks corresponding to fundamental modes, overtones, combination bands and leakage; (ii) solves problems of band assignements due to the presence of LO–TO splitting in the IR spectra; (iii) provides the frequencies of silent modes; (iv) permits a full analysis of the atomic motion corresponding to each normal mode.