Selective feeding of the oystercrassostrea gigas fed on a natural microphytobenthos assemblage

In estuarine ecosystems, microphytobenthos resuspended by tidal currents often represents a large part of the food supply available to bivalves which feed selectively. This study investigated the feeding behavior of the Pacific oysterCrassostrea gigas (Thunberg) relative to a natural microphytobenthic assemblage and the effect on the structure of this assemblage. Oysters were fed only benthic microalgae collected on the intertidal mud flats of Bourgneuf Bay (France) at a suspended particulate matter concentration above the threshold of pseudofeces production. All species in the assemblage were endemic diatoms characteritic of tidal mud flat environments. Four dominant ones, which were all solitary cells with spear-shaped frustules [Navicula ammophila (Grunow),Navicula rostellata (Kützing),Plagiotropis lepidoptera (Kuntze), andStaurophora amphioxys (Mann)] represented more than 95% of the 16 species involved. Analysis of feeding processes showed that the retention of the four main diatoms was not significantly different, but that two species, the smallest (N. ammophila [22×4 μm]) and the largest (P. lepidoptera [60×15 μm]), were preferentially ingested. The study of post-ingestive selection revealed that these two species were also preferentially digeted, i.e., preferentially directed into the digestive diverticulum, when they passed through the gut ofC. gigas. Cell size and shape did not appear to account for pre-ingestive and post-ingestive selection. The composition of the assemblage was significantly modified by oyster filtration, although the retention rates of the four main species were not significantly different. The composition of microalgae in pseudofeces and feces as a result of pre-ingestive and post-ingestive selection differed from that in seawater.     

Thermodynamic properties of solutions in metastable systems under negative or positive pressures

Metastable systems are created when the interface between the atmosphere (in which P_atm = 1 bar) and water forms a spherical meniscus either concave toward the air (water filling capillaries, wherein P_water < P_atm) or convex toward the air (fog water droplet, wherein P_water > P_atm). Soil water, undergoing negative pressure (“capillary potential”) remains bound to the solid matrix (instead of flowing downward) by the capillary meniscus, concave toward the undersaturated dry atmosphere. The positive counterpart of tensile water in soils is the pressurized water contained in fine droplets suspended in oversaturated humid air, as in clouds. All these systems are anisobaric domains the phases of which have different pressures. Geochemical consequences of such characteristics are assessed here by calculating the consequences of the positive or negative water potential on the equilibrium constants of reactions taking place in stretched or pressurized aqueous solutions. Thermodynamic properties of aqueous species are obtained by using the TH model, used explicitly for positive pressures but extrapolated to negative ones for soil solutions. It appears that soil water dissolves gases, offering an alternative explanation of the observed enrichment of atmospheric noble gases in groundwater and of carbonic gas in the unsaturated zone below the root zone. Water droplets obviously show the opposite behavior, that is, a decreasing dissolutive capability with decreasing droplet size (water pressure increases), inducing some climatic consequences. An application of this approach to the solid-solution equilibria is performed by comparing experimental solubility of amorphous silica in unsaturated media on the one hand, to theoretical calculations taking account of the negative water pressure on the other hand. This comparison outlines the potential complexity of anisobaric situations in nature and the necessity to develop a suitable approach for solid pressure.     

The early Paleozoic carbon cycle

A review of O, C, Sr and S isotope trends for the entire Phanerozoic shows that the present-day values of isotope signals are similar to those at the Proterozoic termination. The sharp rise in ⁸⁷Sr/⁸⁶Sr since 65 Ma has been attributed to an uplift and subsequent metamorphism and erosion associated with the Himalayas and Tibet. This orogenic evolution has been postulated to have influenced the global organic and inorganic carbon cycles and climate as well. A similar large-scale orogeny, the Pan-African event, also dominated the Neoproterozoic (Vendian) times, and the similarity of modern and Neoproterozoic isotope values for seawater may therefore have had a comparable tectonic cause. In this contribution, we present the results of a numerical model of the coupled C–alkalinity–S–Sr cycles suggesting that the early Paleozoic (from early Cambrian to late Devonian) evolution of Sr, O, C and S seawater isotope signals could have been the consequence of progressive oxidation of a large reduced carbon reservoir exhumed during the Pan-African orogeny. The δ¹⁸O measured in brachiopod shells is used as a forcing of the model, postulating that any change in the oxygen isotopic composition of seawater is the result of a disequilibrium in the organic carbon subcycle through the coupling of the oxygen isotopic and carbon cycles. The calculated δ¹³C, ⁸⁷Sr/⁸⁶Sr and δ³⁴S are in good agreement with the data, as is the reasonable calculated history for atmospheric pCO₂ and its relation to global climate.     

Integrated Upper Carnian to Lower Norian biochronology and implications for the Upper Triassic magnetic polarity time scale

We summarize the ammonoid, conodont and halobiid biochronology of the Upper Carnian to Lower Norian, based on a discussion of data in the Alps, Sicily, Balkans, Turkey, Himalayas and Timor. With this integrated biostratigraphic scale, the Pizzo Mondello section (Sicily) can be recalibrated and the Carnian-Norian boundary more precisely located there. As a result, the magnetostratigraphy of this section is now in good agreement with previous results from Turkey, although the latter series are more condensed. Cross-correlation of available magnetostratigraphic data from marine Tethyan sections allow us to construct a composite Upper Carnian to Upper Norian geomagnetic polarity time scale (GPTS). This GPTS leads us to question previously proposed magnetobiostratigraphic and chronostratigraphic correlations within the Upper Triassic Newark non-marine sedimentary sequence.     

Prediction of Gibbs energies of formation of compounds from the elements—II. Monovalent and divalent metal silicates

A parameter ΔO^2?, defined as the difference between the Gibbs energy of formation of a given oxide and its aqueous cation, was used to obtain linear relationships among Gibbs energies of formation from the elements of hydroxides, oxides and aqueous metallic ions (Tardy and Garrels, 1976). Use of this parameter has now been extended to meta- and orthosilicates for which the Gibbs energies of formation of silicates from their oxides are shown to be linear functions of the ΔO^2? values of their constituent cations. The function obtained for metasilicates is:

$\text{ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{silicate}\text{? ∑ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{oxides}\text{= ?}\text{2}\text{3}\text{(ΔO}{}^{\mathrm{2?}}\text{cation}\text{? ΔO}{}^{\mathrm{2?}}\text{silicon}$

and that for orthosilicates is:

$\text{ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{silicate}\text{? ∑ΔG}{}^{\mathrm{o}}{}_{\mathrm{?}}\text{oxides}\text{= ?}\text{4}\text{4}\text{(ΔO}{}^{\mathrm{2?}}\text{cation}\text{? ΔO}{}^{\mathrm{2?}}\text{silicon}$

in which Δ^o_? silicate is the Gibbs energy of formation from the elements of a silicate of a given cation and ∑ΔG^o_? oxides is the sum of the Gibbs energies of formation from the elements of the constituent oxides of the silicate considered.These functions can be used to test for consistency within and between various sources of thermodynamic data and to estimate free energy of formation values for previously unstudied species.     

Compositional variations of volcanics along segments of recent spreading ridges

An investigation of glassy volcanics erupted within the last ten-million years along various segments of the mid-Atlantic Ridge and the East Pacific Rise has revealed major crustal compositional changes. The available data from the mid-Atlantic Ridge shows the existence of two petrological provinces: One, located between latitudes 33° and 53° N, is characterized by volcanics which have a tendency to be oversaturated ocean ridge basalts (OSORB) with respect to normative quartz; the second group of rocks, found between 25° S and 33° N, is generally composed of saturated ocean ridge basalts (SORB). In addition, the SORB volcanics have higher TiO₂ (1.7±0.3%), higher Na₂O (2.8±0.2%) and higher FeO^*/MgO (1.36±0.2) values than do the OSORB types (with 1.1±0.2%, 2.2±0.2% and 1.22±0.2 for the TiO₂, Na₂O, and FeO^*/MgO respectively), There is a correlation between the rate of crustal spreading and the compositional changes observed on the volcanics erupted along various segments of oceanic ridges. Slow-accreting plate boundaries having a total spreading rate of 2–3 cm/year are characterized by a low TiO₂ content (1.1±0.2%), low FeO^*/ MgO ratio (1.22±0.2) and a high an/an+ab ratio (0.62±0.05). Segments of fast-spreading ridges (total rate 11–13 cm/year) show a higher range of TiO₂ (2.1±0.4%) and FeO^*/MgO (1.6±0.4) and a lower range of the an/an + ab ratio (0.5±0.07). Ridge segments with a total spreading rate of 5–9 cm/year con sist of volcanics having intermediate values for the above parameters. Different degrees of partial melting of rising mantle material are suggested as a possible mechanism for explaining the compositional diversities encountered along oceanic ridge systems.Contribution n 677 du Département de Géophysique, Géologie, Géochimie Marines du C.O.B.     

Numerical studies of heat island circulations

A two dimensional model has been set up to investigate the circulation induced by an urban heat island in the absence of synoptic winds. The boundary conditions need to be formulated carefully and due to difficulties arising here, we restrict our attention to cases of initially stable thermal stratification. Heat island circulations are allowed to develop from rest and prior to the appearance of the final symmetric double cell pattern, a transitional multi-cell pattern is observed in some cases. The influence on the steady state circulation of various parameters is studied, among which are eddy transfer coefficients, the heat island intensity, the initial temperature stratification and the heat island size. Some results are presented for a case in which differential surface cooling beneath an initially stable atmosphere produces a circulation and an unstable layer capped by an elevated inversion over the city. It is hoped that this case is vaguely representative of the night-time heat island with no geostrophic wind.Notation c_p Specific heat at constant pressure - g Acceleration due to gravity - H Top of integration region - K_z Vertical eddy transfer coefficient - K_x, K_xH, K_xm Horizontal eddy transfer coefficients for heat and momentum - l ixing length - p Pressure - p₀ Reference surface pressure (1000 mb) - P_H (x, t) Pressure at z = H - R Specific gas constant for dry air - t Time - u, w Horizontal and vertical velocities - x, z Horizontal and vertical coordinates - x₁, x₂ Positions of discontinuities in surface temperature field (see Figure 2) - x_a Heat island half-width - x_b Boundary of integration region - Parameter in formula for eddy coefficients (variable-K case) = 18.0 - _s Intensity of heat island - Potential temperature field - Reference absolute temperature (variable-K case) - _r Reference temperature (° C) - _s Surface temperature - Q Air density     

Volcanic plume thermal radiation: 1972 eruption of piton de la fournaise, Réunion Island

Using an infrared radiometer, the authors measured the infrared radiation emitted by the plume during the 1972 Piton de la Fournaise (Réunion Island) eruption in the 9.1- to 11.9-μm range.Eight histograms summarize twenty hours of continuous measurements and show a flux between 0.557 and 1.279 W/cm² with an average of 0.88 W/cm². The greatest number of events correspond to the flux emitted by lava fountains, while the high and rare flux values (4–6 W/cm²) correspond to detonations of chemical explosions, probably of H₂ and O₂.After calibration in the laboratory on a reference black body and in the field by correlation with field observations, such a technique can be used to follow changes of volcanic activity in remote and dangerous spots. Information on the number of explosions, their magnitude, and the presence and relative significance of hot magma can be transmitted continuously to a safe place.     

Paleomagnetic results from Permian rocks of the northern Saharan craton and motions of the Moroccan Meseta and Pangea

The characteristic magnetization of redbed samples from the upper part of the Série d'Abadla (probably Early Permian 31°N, 2.7°W) has a mean direction derived from 13 sites of D=129°, I=11°, k=59, α₉₅=6° and a corresponding south paleopole at 29°S, 60°E, A₉₅=5°. All directions have reversed polarity. The paleolatitude of the northern fringe of the Saharan craton was 6°±3°S, which is in excellent agreement with that for the Moroccan Meseta. Therefore, in all probability, there has been no paleolatitudinal displacement greater than about 500 km of the Moroccan Meseta relative to Africa since Permian time. Comparison of results from sedimentary rocks shows no evidence for relative rotation of the Moroccan Meseta since Permian time. Small apparent rotations are indicated by evidence from massive trachyandesite lavas from Morocco, but we argue that these could have arisen from the incomplete averaging of secular variation and uncertainties in estimates of paleohorizontal, rather than from true tectonic rotations. The combined latest Carboniferous/Early Permian paleopole for the Saharan craton and the Meseta differs form the path of apparent polar wandering for North America when the continents are assembled in Wegener's Pangea (Pangea A, in which northwest Africa is opposite North America). It is in reasonable agreement when the continents are assembled in the Pangea B configuration (northwest Africa opposite Europe).     

Methane and CO2 sorption and desorption measurements on dry Argonne premium coals: pure components and mixtures

Sorption and desorption behaviour of methane, carbon dioxide, and mixtures of the two gases has been studied on a set of well-characterised coals from the Argonne Premium Coal Programme. The coal samples cover a maturity range from 0.25% to 1.68% vitrinite reflectance. The maceral compositions were dominated by vitrinite (85% to 91%). Inertinite contents ranged from 8% to 11% and liptinite contents around 1% with one exception (Illinois coal, 5%). All sorption experiments were performed on powdered (−100 mesh), dry coal samples.Single component sorption/desorption measurements were carried out at 22 °C up to final pressures around 51 bar (5.1 MPa) for CO₂ (subcritical state) and 110 bar (11 MPa) for methane.The ratios of the final sorption capacities for pure CO₂ and methane (in molar units) on the five coal samples vary between 1.15 and 3.16. The lowest ratio (1.15) was found for the North Dakota Beulah-Zap lignite (VR_r=0.25%) and the highest ratios (2.7 and 3.16) were encountered for the low-rank coals (VR_r 0.32% and 0.48%) while the ratio decreases to 1.6–1.7 for the highest rank coals in this series.Desorption isotherms for CH₄ and CO₂ were measured immediately after the corresponding sorption isotherms. They generally lie above the sorption isotherms. The degree of hysteresis, i.e. deviation of sorption and desorption isotherms, varies and shows no dependence on coal rank.Adsorption tests with CH₄/CO₂ mixtures were conducted to study the degree of preferential sorption of these two gases on coals of different rank. These experiments were performed on dry coals at 45 °C and pressures up to 180 bar (18 MPa). For the highest rank samples of this sequence preferential sorption behaviour was “as expected”, i.e. preferential adsorption of CO₂ and preferential desorption of CH₄ were observed. For the low rank samples, however, preferential adsorption of CH₄ was found in the low pressure range and preferential desorption of CO₂ over the entire pressure range.Follow-up tests for single gas CO₂ sorption measurements consistently showed a significant increase in sorption capacity for re-runs on the same sample. This phenomenon could be due to extraction of volatile coal components by CO₂ in the first experiment. Reproducibility tests with methane and CO₂ using fresh sample material in each experiment did not show this effect.