Mapping Coastal Aquifers by Joint Inversion of DC and TEM Soundings-Three Case Histories

Electrical and electromagnetic methods are well suited for coastal aquifer studies because of the large contrast in resistivity between fresh water-bearing and salt water-bearing formations. Interpretation models for these aquifers typically contain four layers: a highly resistive unsaturated zone; a surficial fresh water aquifer of intermediate resistivity; an underlying conductive, salt water saturated aquifer; and resistive substratum. Additional layers may be added to allow for variations in lithology within the fresh water and salt water layers. Two methods are evaluated: direct current resistivity and time domain electromagnetic soundings. Use of each method alone produces nonunique solutions for resistivities and/or thicknesses of the different layers. We show that joint inversion of vertical electric and time domain electromagnetic soundings produces a more tightly constrained interpretation model at three test sites than is produced by inversion methods applied to each data set independently.     

In-water and remote measurements of ocean color

Spectral measurements of downwelling irradiance, E _d(), above the surface, and of upwelling irradiance just below the surface, E _u(), allow computation of spectral values of the diffuse reflectance R() = E _u()/E _d(); this yields full information about the true color and brightness of the ocean. Typical results are presented and interpreted for waters very different in turbidity and phytoplankton content. Conversely, the possibility of infering the water content from R() data at selected wavelengths is examined in terms of the respective number of equations and unknowns. The necessary use of assumptions and of empirical laws is emphasized.The magnitude of the useful signal emerging from the water, and the magnitude of the additional signals due to specular reflexion at the interface and to atmospheric scattering, are compared on the basis of spectroradiometric measurements performed within and above the sea, from different altitudes. These unwanted signals are dominant, causing a drastic change in the spectral composition of the light received by a remote sensor. The evaluation of the atmospheric effect must be very precise in order to recover the marine signal with a sufficient accuracy for a meaningful application of any kind of algorithm.This work was supported in part by the Centre National d'Exploitation des Océans (under contract CNEXO 77/1695) and in part by the Centre National de la Recherche Scientifique (RCP 247 & ERA 278).     

Report of the working group on water color

This report on water color is divided into two parts: a summary of the formal and informal presentations made at the meeting, and a summary of the conclusions and recommendations reached during the working group meetings. The group's discussions were divided into four categories: inwater studies and algorithms, atmospheric effects and correction algorithms, design of the next generation of spacecraft sensors, and future projects. Naturally, most of the discussion concerned the Coastal Zone Color Scanner on Nimbus-G but discussion was not restricted to this sensor. There were few members of the working group specializing in sediment studies; this is reflected in the fact that the major portion of the report deals with the remote determination of phytoplankton pigments.On leave from Department of Physics, University of Miami, Coral Gables, Florida.     

A note on finite-difference schemes for the surface and planetary boundary layers

The solution of the planetary boundary-layer equations by finite-difference methods has recently become very popular. Among recent papers using such methods, several use somewhat arbitrary finite-difference meshes and some do not make use of a constant flux or wall layer near the ground. It is shown that the use of finite differences right down to the ground can be a very inaccurate procedure when used in conjunction with an eddy viscosity or mixing length proportional to (z +z ₀) orz near the ground. Such an approach can lead to results that are highly dependent on the finite-difference scheme used and virtually independent of the roughness length,z ₀. A scheme using an expanding grid, based on the form chosen for mixing length or eddy viscosity, is proposed which gives good results with or without a surface layer in the case of a neutrally stratified atmosphere.     

Reliability of K-Ar Dating of Clays and Silicifications Associated with vein Mineralizations in Western Europe

K-Ar ages were determined on fine fractions and one massive silicification associated with vein mineralizations in uranium, barium, fluorine and related base metals in Western Europe. The reliability of the potassic materials analysed, once the mineralogical and geochemical relationships to the low-temperature mineralization have been established, is demonstrated. The isotopic ages are concentrated between nearly 190 and 170 MA. This epoch corresponds to that of the rifting of the future Atlantic and Tethys oceans. This type of low-temperature mineralization thus seems to be better explained by extensional phenomena.     

Subsurface processes at the lucky strike hydrothermal field, Mid-Atlantic ridge: evidence from sulfur, selenium, and iron isotopes

At Lucky Strike near the Azores Triple Junction, the seafloor setting of the hydrothermal field in a caldera system with abundant low-permeability layers of cemented breccia, provides a unique opportunity to study the influence of subsurface geological conditions on the hydrothermal fluid evolution. Coupled analyses of S isotopes performed in conjunction with Se and Fe isotopes have been applied for the first time to the study of seafloor hydrothermal systems. These data provide a tool for resolving the different abiotic and potential biotic near-surface hydrothermal reactions. The δ³⁴S (between 1.5‰ and 4.6‰) and Se values (between 213 and 1640 ppm) of chalcopyrite suggest a high temperature end-member hydrothermal fluid with a dual source of sulfur: sulfur that was leached from basaltic rocks, and sulfur derived from the reduction of seawater sulfate. In contrast, pyrite and marcasite generally have lower δ³⁴S within the range of magmatic values (0 ± 1‰) and are characterized by low concentrations of Se (<50 ppm). For ⁸²Se/⁷⁶Se ratios, the δ⁸²Se values range from basaltic values of near −1.5‰ to −7‰. The large range and highly negative values of hydrothermal deposits observed cannot be explained by simple mixing between Se leached from igneous rock and Se derived from seawater. We interpret the Se isotope signature to be a result of leaching and mixing of a fractionated Se source located beneath hydrothermal chimneys in the hydrothermal fluid. At Lucky Strike we consider two sources for S and Se: (1) the “end-member” hydrothermal fluid with basaltic Se isotopic values (−1.5‰) and typical S isotope hydrothermal values of 1.5‰; (2) a fractionated source hosted in subsurface environment with negative δ³⁴S values, probably from bacterial reduction of seawater sulfate and negative δ⁸²Se values possibly derived from inorganic reduction of Se oxyanions. Fluid trapped in the subsurface environment is conductively cooled and has restricted mixing and provide favorable conditions for subsurface microbial activity which is potentially recorded by S isotopes. Fe isotope systematic reveals that Se-rich high temperature samples have δ⁵⁷Fe values close to basaltic values (∼0‰) whereas Se-depleted samples precipitated at medium to low temperature are systematically lighter (δ⁵⁷Fe values between −1 to −3‰). An important implication of our finding is that light Fe isotope composition down to −3.2‰ may be explained entirely by abiotic fractionation, in which a reservoir effect during sulfide precipitation was able to produce highly fractionated compositions.