硬土软岩滑坡近水平滑移的离心机模型试验研究

中国西北地区存在大量的新近纪硬土软岩滑坡灾害,为研究该类滑坡的变形特征,开展两组离心机模型试验模拟滑带劣化引起滑坡变形破坏的全过程,获取模型坡体土压及位移的实时变化曲线。研究表明,当软弱带强度降低时,硬土软岩滑坡的上部滑体呈块体状滑动,在快速运动滑动过程中,滑体呈现块状平移,不会彻底解体、液化;硬土软岩滑坡中前部出现水平应力集中,导致下伏滑带塑性流动变形,诱发其中前部上覆滑体的水平运动,并向滑坡后缘扩展,最终形成多级水平滑动。     

Adsorption of REE(III)-humate complexes onto MnO2: Experimental evidence for cerium anomaly and lanthanide tetrad effect suppression

Experiments were conducted to evaluate the impact of organic complexation on the development of Ce anomalies and the lanthanide tetrad effect during the adsorption of rare-earth elements (REE) onto MnO₂. Two types of aqueous solutions—NaCl and NaNO₃—were tested at pH 5 and 7.5. Time-series experiments indicate that a steady-state is reached within less than 10 h when REE occur as free inorganic species, whereas steady state is not reached before 10 d when REE occur as REE-humate complexes. The distribution coefficients (K_d^REE) between suspended MnO₂ and solution show no or only very weak positive Ce anomaly or lanthanide tetrad effect when REE occur as humate complexes, unlike the results obtained in experiments with REE occurring as free inorganic species. Monitoring of dissolved organic carbon (DOC) concentrations show that log K_d^REE_organic/K_d^DOC ratios are close to 1.0, implying that the REE and humate remain bound to each other upon adsorption. Most likely, the Ce anomaly reduction/suppression in the organic experiments arises from a combination of two processes: (i) inability of MnO₂ to oxidize Ce(III) because of shielding of MnO₂ surfaces by humate molecules and (ii) Ce(IV) cannot be preferentially removed from solution due to quantitative complexation of the REE by organic matter. We suggest that the lack of lanthanide tetrad effect arises because the adsorption of REE-humate complexes onto MnO₂ occurs dominantly via the humate side of the complexes (anionic adsorption), thereby preventing expression of the differences in Racah parameters for 4f electron repulsion between REE and the oxide surface. The results presented here explain why, despite the development of strongly oxidizing conditions and the presence of MnO₂ in the aquifer, no (or insignificant) negative Ce anomalies are observed in organic-rich waters. The present study demonstrates experimentally that the Ce anomaly cannot be used as a reliable proxy of redox conditions in organic-rich waters or in precipitates formed at equilibrium with organic-rich waters.     

惠民凹陷沙河街组地层水化学特征及其成因

根据惠民凹陷沙河街组水化学分析数据,探讨水化学成分分布特征,并初步进行地层水来源及成因方面的分析。研究结果表明:沙河街组发育的是以(Cl^-和Na⁺+K⁺为主要离子组分的(CaCl₂,型水,矿化度及其他水化学组分纵向上呈增加-减小交替变化的特点。各水化学参数反映凹陷内沙四段、沙三中下亚段和沙二段地层较好的封闭性,地层水总体被CaCO₃饱和,尚未达到CaSO₄饱和程度。与海水、湖水蒸发曲线进行对比,直观地反映水中离子的富集和贫乏程度,进而进行相应的地层水成因研究,即沙河街组地层水中Na⁺, Cl^-浓缩,Ca²⁺富集,以及Mg²⁺ 、 SO₄^2-贫乏的现象是蒸发浓缩作用、斜长石钠长石化、脱硫酸作用、有机质生烃等共同作用的结果。此外,平面上沙四段以上各层地层水矿化度低值区均分布在临南洼陷内,粘土矿物脱水作用可以解释洼陷及周边地层水的淡化现象。     

Lithostratigraphy and depositional environment of the Permian Nowra Sandstone in the southwestern Sydney Basin,Australia

Lithofacies in the mid‐Permian Nowra Sandstone indicate a middle/upper shoreface to foreshore environment of deposition under the influence of storm‐generated waves and north‐northeasterly directed longshore currents. Palaeogeographic reconstruction for the Nowra Sandstone portrays a sand‐dominated high energy shelf and offshore shoal forming a sequence thickening seaward away from the western shore of the Sydney Basin. The shoal‐crest at the outer edge of the shelf trends north‐northeast. It is characterized by fine‐ to medium‐grained sandstone with upper flow regime structures and a high proportion of conglomerate, whereas coarser sandstone with lower energy bedforms occurs along the seaward side of the shoal. In the deeper water to the east, the lower Nowra Sandstone becomes rapidly thinner as it passes seaward, via bioturbated storm redeposited sandstone beds, into the shelf deposits of the Wandrawandian Siltstone. This sequence accumulated during a regressive event and the base of the formation becomes progressively younger eastward. The sand may have been supplied by rivers along the western coast but the major source was south of the study area. The lower Nowra Sandstone is separated from the upper part of the formation by an extensive ravinement surface overlain by the Purnoo Conglomerate Member. In contrast to the lower unit, the upper Nowra Sandstone forms a westward thickening wedge that represents a backstepping nearshore sand facies that accumulated during a transgression. The upper Nowra Sandstone passes vertically and laterally eastward into the Berry Siltstone. Thus both boundaries of the Nowra Sandstone are diachronous, first younging eastward and then westward as a response to a regressive‐transgressive episode.     

The P-T-fO 2 stability of deerite,Fe 12 2+ Fe 6 3+ [Si12O40](OH)10

New equilibrium experiments have been performed in the 20–27 kbar range to determine the upper thermal stability limit of endmember deerite, Fe ₁₂ ²⁺ Fe ₆ ³⁺ [Si₁₂O₄₀](OH)₁₀. In this pressure range, the maximum thermal stability limit is represented by the oxygen-conserving reaction: deerite(De)=9 ferrosilite(Fs)+3 magnetite(Mag)+3 quartz(Qtz)+5 H₂O(W) (1). Under the oxygen fugacities of the Ni-NiO buffer the breakdown-reduction reaction: De=12 Fs+2 Mag+5 W+1/2 O₂ (10) takes place at lower temperatures (e.g. T=63° at 27 kbar). The experimental brackets can be fitted using thermodynamic data for ferrosilite, magnetite and quartz from Berman (1988) and the following 1 bar, 298 K data for deerite (per gfw): V^o=55.74 J.bar^-1, S^o=1670 J.K^-1, H _f ^o =-18334 kJ, =2.5x10^-5K^-1, =-0.18x10^-5 bar^-1. Using these data in conjunction with literature data on coesite, grunerite, minnesotaite, and greenalite, the P-T stability field of endmember deerite has been calculated for P _s=P _{H 2}O. This field is limited by 6 univariant oxygenconserving dehydration curves, from which three have positive dP/dT slopes, the other three negative slopes. The lower pressure end of the stability field of endmember deerite is thus located at an invariant point at 250±70°C and 10+-1.5 kbar. Deerite rich in the endmember can thus appear only in environments with geothermal gradients lower than 10°C/km and at pressures higher than about 10 kbar, which is in agreement with 4 out of 5 independent P-T estimates for known occurrences. The presence of such deerite places good constraints on minimum pressure and maximum temperature conditions. From log f _{O 2}-T diagrams constructed with the same data base at different pressures, it appears that endmember deerite is, at temperatures near those of its upper stability limit, stable only over a narrow range of oxygen fugacities within the magnetite field. With decreasing temperatures, deerite becomes stable towards slightly higher oxygen fugacities but reaches the hematite field only at temperatures more than 200°C lower than the upper stability limit. This practically precludes the coexistence deerite-hematite with near-endmember deerite in natural environments.     

Geothermobarometry in albite-garnet orthogneisses: A case study from the Gran Paradiso nappe (Western Alps)

The aim of this paper is to estimate syntectonic P-T conditions within albite- and garnet-bearing orthogneisses. These rocks are generally characterized by the assemblage quartz + albite + biotite + phengite + CaFe-garnet + epidote + titanite. Garnet contains up to 55 mole per cent of grossular. K-feldspar is a relict magmatic phase.

P-T conditions are estimated using several independent methods. First, it is shown that exchange reactions based on the Fe---Mg partitioning between garnet and biotite or garnet and phengite cannot be used to estimate temperatures in these rocks, due to the high grossular content of garnet. Second, maximum and minimum pressures are constrained, respectively, by the occurrence of albite instead of jadeite + quartz and by the assemblage phengite + biotite + quartz. Third, phase equilibria in albite- and garnet-bearing metagranites are modelled in the system K₂O---CaO---FeO---Al₂O₃---SiO₂---H₂O. Equilibrium curves are calculated for the observed phase compositions. Uncertainties in P-T estimates mainly result from the choice of appropriate non-ideal solution models for the garnet.

An application is developed for granites from the Gran Paradiso nappe (Western Alps). These granites show an heterogeneous deformation of Alpine age expressed by mylonitic shear zones cutting across weakly deformed domains. Estimated P-T conditions for the synkinematic assemblages are 10–16 kbar at 550±50°C.     

下寺湾油田柳洛峪地区长8储层配伍性实验研究

柳洛峪地区长8地层水属CaCl2型,地层结垢伤害主要为BaSO4垢引起。注入水为长2地层水,水型及组成与长8地层水类似。配伍实验结果表明:单一水样在不同温度和压力下表现为随着温度、压力的升高,出现CaCO3结垢趋势变大,而BaSO4结垢趋势减弱。注入水与磨碎的岩心混合后生成的白色沉淀物主要为BaSO4和CaCO3。不同比例混配水样实验结果显示,提高注入水的比例可以有效地减少混合液产生的沉淀量。同时,随着注入水的不断注入,岩心渗透率变化较小,表明混配水几乎不会对储层造成伤害。     

Nonlinear Mechanical Behavior Analysis of Flexible Lateritic Pavements of Senegal (West Africa) by FEM for M.-E. Pavement Design

Pavement design in Senegal is based on a linear elastic behavior of pavement materials and the hypothesis of a static loading. However, previous works on the mechanical behavior of road materials showed that this one is reversible after several loading cycles and depends on the applied stress. The described behavior is from then on, purely nonlinear. One of the objectives of this research is to determine the parameters of response of lateritic pavement materials submitted to road traffic by using FEM. Therefore, experiments were made on gravel lateritic soils from Dougar, Sébikotane, Mont-Rolland, Pâ Lo and Ngoundiane. The Young’s modulus of the materials was defined in unconfined compression test while repeated load triaxial test was performed to determine the resilient modulus of the gravels and the appropriate model (Uzan model). An implementation was realized with Cast3M©. The importance of the nonlinearity was revealed in a very clear way and was crucial in the construction of the calculation algorithm. The observations for certain conditions showed that the values of the critical responses are more important for the linear model than for the nonlinear model. However, this trend should be validated by further studies.     

The assessment of health impact caused by energy use in urban areas of China: an intake fraction–based analysis

The Indian Ocean Tsunami of December 2004 caused inundation of seawater along the Northern coast of Tamil Nadu, India, resulting in loss of 8,000 people with extensive damage to properties. The paper describes the inundation of seawater in two northern districts, namely Kancheepuram and Villupuram districts, which showed distinct patterns of inundation of seawater and run-up levels due to variations in geomorphic features. TUNAMI N2 model was used to predict the seawater inundation for earthquakes occurred in 1881 at Car Nicobar, Sumatra 2004 and a worst-case scenario. The coastal areas with beaches having gentle slope showed more inundation compared with coastal areas having varied slope and habited by sand dunes and coastal vegetation. Appreciable inundation of seawater with tsunami simulated for 1881 Car Nicobar indicated that proximity to the source plays a major role besides earthquake parameters in causing inundation. The worst-case scenario generated from subduction zone of Car Nicobar using Sumatra 2004 earthquake parameters revealed extreme vulnerability of coasts of both the districts to giant tsunamis.     

断裂应力特征及其转折控油气规律研究——以南堡凹陷为例

为了分析断裂对油气宏观分布规律的控制作用,寻找有勘探潜力的油气富集带,文中以地质力学理论为指导,对南堡凹陷断裂组合应力特征、断裂转折及成因进行解析,并结合砂体分布和古今构造应力场分布特征,对南堡凹陷东营组油气分布规律和有利勘探区带做了研究。结果表明:断裂转折部位对油气分布有着控制作用,东营组已探明的油气主要在帚状断裂系、入字形断裂系、交织式断裂系转折轴部高曲率附近呈环带状分布;断裂转折凹面一侧控油性明显,从宏观上来看,油气具有沿沉积相带由细到粗的构造脊高点以及弧形断裂转折凹面一侧的选择性运移的特征,断裂转折轴部高曲率高孔、高渗域与高孔、高渗砂体沉积相带的有利对置决定了油气的主流向;综合研究指出,南堡凹陷北堡构造带是今后优势勘探的首要区带,其次是南堡构造带和南堡4号蛤坨构造带南部。