Porosity and mineralogy evolution during the decay process involved in the Chellah monument stones

The objective of this work is to study the decay process involved in the historical Roman Chellah located in the Rabat city (Morocco). This monument is made up of porous calcarenite stone. Several samples, taken from altered and unaltered blocks, were analyzed by the water saturation, the mercury intrusion porosimetry techniques and using the scanning electron microscopy coupled to energy dispersive X-ray spectrometer (SEM–EDX). To perform a reliable chemical analysis, some samples were also analyzed by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The mercury porosimetry results show a bimodal porous network for this porous material, the deterioration process of these stones involved an increase in porous volume of about 2%. The lowest porosity observed in the unaltered block is connected to the presence of sparitic cement which causes a partial inter-granular porosity clogging. The highest porosity of the deteriorated block without crust is due to the increase in inter-granular space. SEM photographs of the unaltered sample show the presence of the porous primary grains, of ovoid forms and millimeter-length sizes, and of the secondary grains, of rhombohedric forms and micro size. Porosity is essentially located between the primary grains and can be completely clogged by secondary precipitations. Various forms of deterioration are observed on the altered samples such as the dissolution of the secondary grains edges, wells of dissolution and also the presence of argillaceous residues on the surface. This last was also detected by the ICP-AES and EDX analysis which show an increase of the silicon and aluminum contents toward the surface.     

Future evolution of extreme precipitation in the Mediterranean

Mediterranean basins can be impacted by severe floods caused by extreme rainfall, and there is a growing awareness about the possible increase in these heavy rainfall events due to climate change. In this study, the climate change impacts on extreme daily precipitation in 102 catchments covering the whole Mediterranean basin are investigated using nonstationary extreme value model applied to annual maximum precipitation in an ensemble of high-resolution regional climate model (RCM) simulations from the Euro-CORDEX experiment. Results indicate contrasted trends, with significant increasing trends in Northern catchments and conversely decreasing trends in Southern catchments. For most cases, the time of signal emergence for these trends is before the year 2000. The same spatial pattern is obtained under the two climate scenarios considered (RCP4.5 and RCP8.5) and in most RCM simulations, suggesting a robust climate change signal. The strongest multi-model agreement concerns the positive trends, which can exceed +?20% by the end of the twenty-first century in some simulations, impacting South France, North Italy, and the Balkans. For these areas, society-relevant strong impacts of such Mediterranean extreme precipitation changes could be expected in particular concerning flood-related damages.     

Towards fully data driven ground-motion prediction models for Europe

We have used the Artificial Neural Network method (ANN) for the derivation of physically sound, easy-to-handle, predictive ground-motion models from a subset of the Reference database for Seismic ground-motion prediction in Europe (RESORCE). Only shallow earthquakes (depth smaller than 25 km) and recordings corresponding to stations with measured $V_{s30}$ properties have been selected. Five input parameters were selected: the moment magnitude $M_{W}$ , the Joyner–Boore distance $R_{JB}$ , the focal mechanism, the hypocentral depth, and the site proxy $V_{S30}$ . A feed-forward ANN type is used, with one 5-neuron hidden layer, and an output layer grouping all the considered ground motion parameters, i.e., peak ground acceleration (PGA), peak ground velocity (PGV) and 5 %-damped pseudo-spectral acceleration (PSA) at 62 periods from 0.01 to 4 s. A procedure similar to the random-effects approach was developed to provide between and within event standard deviations. The total standard deviation ( $\sigma $ ) varies between 0.298 and 0.378 (log $_{10}$ unit) depending on the period, with between-event and within-event variabilities in the range 0.149–0.190 and 0.258–0.327, respectively. Those values prove comparable to those of conventional GMPEs. Despite the absence of any a priori assumption on the functional dependence, our results exhibit a number of physically sound features: magnitude scaling of the distance dependency, near-fault saturation distance increasing with magnitude, amplification on soft soils and even indications for nonlinear effects in softer soils.     

Mapping diversified peri-urban agriculture – potential of object-based versus per-field land cover/land use classification

High spatial resolution satellite data contribute to improving land cover/land use (LCLU) classification in agriculture. A classification procedure based on Quickbird satellite image data was developed to map LCLU of diversified agriculture at sub-communal and communal level (7 km²). Segmentation performance of the panchromatic band in combination with high pass filters (HPF) was tested first. Accuracy of field boundary delineation was evaluated by an object-based segmentation, a per-field and a manual classification, along with a quantitative accuracy assessment. Sub-communal classification revealed an overall accuracy of 84% with a κ coefficient of 0.77 for the per-field vector segmentation compared to an overall accuracy of 56–60% and a κ coefficient of 0.37–0.42 for object-based approaches. Per-field vector segmentation was thus superior and used for LCLU classification at communal level. Overall accuracy scored 83% and the κ coefficient 0.7. In diversified agriculture, per-field vector segmentation and classification achieved higher classification results.     

Seasonal variability of the equatorial undercurrent termination and associated salinity maximum in the Gulf of Guinea

The termination of the Equatorial Undercurrent (EUC) in the eastern equatorial Atlantic during boreal summer and fall, and the fate of the associated saline water masses, are analyzed from in situ hydrological and currents data collected during 19 hydrographic cruises between 2000 and 2007, complemented by observations from Argo profiling floats and PIRATA moorings, and from a numerical simulation of the Tropical Atlantic Ocean for the period 1993–2007. An intense variability of the circulation and hydrological properties is evidenced from observations in the upper thermocline (24.5–26.2 isopycnal layer) between June and November. During early boreal summer, saline water masses are transported eastward in the upper thermocline to the African coast within the EUC, and recirculate westward on both sides of the EUC. In mid-boreal summer, the EUC weakens in the upper thermocline and the equatorial salinity maximum disappears due to intense mixing with the surface waters during the upwelling season. The extra-equatorial salinity maxima are also partially eroded during the boreal summer, with a slight poleward migration of the southern hemisphere maximum until late boreal summer. The upper EUC reappears in September, feeding again the eastern equatorial Atlantic with saline waters until boreal spring. During December–January, numerical results suggest a second seasonal weakening of the EUC in the Gulf of Guinea, with a partial erosion of the associated equatorial salinity maximum.     

Magnetic properties and neutron diffraction study of two manganese sulfosalts: monoclinic MnSb<Subscript>2</Subscript>S<Subscript>4</Subscript> and benavidesite (MnPb<Subscript>4</Subscript>Sb<Subscript>6</Subscript>S<Subscript>14</Subscript>)

Mn²⁺Sb₂S₄, a monoclinic dimorph of clerite, and benavidesite (Mn²⁺Pb₄Sb₆S₁₄) show well-individualized single chains of manganese atoms in octahedral coordination. Their magnetic structures are presented and compared with those of iron derivatives, berthierite (Fe²⁺Sb₂S₄) and jamesonite (Fe²⁺Pb₄Sb₆S₁₄). Within chains, interactions are antiferromagnetic. Like berthierite, MnSb₂S₄ shows a spiral magnetic structure with an incommensurate 1D propagation vector [0, 0.369, 0], unchanged with temperature. In berthierite, the interactions between identical chains are antiferromagnetic, whereas in MnSb₂S₄ interactions between chains are ferromagnetic along c-axis. Below 6 K, jamesonite and benavidesite have commensurate magnetic structures with the same propagation vector [0.5, 0, 0]: jamesonite is a canted ferromagnet and iron magnetic moments are mainly oriented along the a-axis, whereas for benavidesite, no angle of canting is detected, and manganese magnetic moments are oriented along b-axis. Below 30 K, for both compounds, one-dimensional magnetic ordering or correlations are visible in the neutron diagrams and persist down to 1.4 K.     

Improvement to resistivity pseudosection modelling by removal of near-surface inhomogeneity effects: application to a soil system in south Cameroon*

Near-surface inhomogeneities (NSIs) can lead to severe problems in the interpretation of apparent resistivity pseudosections because their effects significantly complicate the image aspect. In order to carry out a more efficient and reliable interpretation process, these problematic features should be removed from field data. We describe a filtering scheme using two-sided half-Schlumberger array data. The scheme was tested on synthetic data, generated from a simple 2D resistivity model contaminated by NSIs, and is shown to be suitable for eliminating such contaminations from apparent resistivity data. Furthermore, the original model without NSIs can be recovered satisfactorily from the inversion of filtered apparent resistivity data. The algorithm is also applied efficiently to a real data set collected at Nsimi, in southern Cameroon, along a 200-m shallow depth profile crossing a complex transitional zone. For this case, the filtering scheme provides accurate structural and behavioural interpretations of both the geometry of the major soil constituents and the groundwater partitioning.     

Diatom-based transfer functions for western Quebec lakes (Abitibiand Haute Mauricie): the possible role of epilimnetic CO2 concentration in influencing diatom assemblages

Surficial sediments from 76 lakes from two western Quebec regions(Abitibi and Haute Mauricie) were sampled to identify the relationships betweendiatoms and environmental variables. Because the two regions containedradically different diatom communities, we then investigated which factors maybe responsible for the large community discrepancies in the two nearbygeographical areas. Standard lake chemistry variables showed little differencesbetween the regions, although epilimnetic light regimes were slightly lower inAbitibi. Nevertheless, lakes of the two regions with similar light regimes andchemistry still showed a clear separation in their diatoms, implying that otherimportant factors are influencing assemblages. We found that the calculatedconcentration of CO₂ in the open water can explain some of thediscrepancy in diatom assemblages. A pCCA constrained to the concentration ofCO₂ with alkalinity and pH as covariables explained 12.5% of speciesvariance and was significant. Given the lack of a relationship between DOC andCO₂, and because the lakes are heavily supersaturated withCO₂ in the calibration set, lake-to-lake variations inCO₂ concentrations are likely due to groundwater inputs; thepossibility that this environmental variable may be influencing diatomcommunities might allow, in some cases, the reconstruction of historicalchanges in groundwater inputs to lakes. Finally, new calibration models werebuilt in Quebec by using weighted averaging partial least square(WA-PLS) techniques in order to infer pH, CO₂, TP, TN, and, DOC fromdiatom assemblages preserved in the surface sediments.     

Relationships among Gibbs free energies and enthalpies of formation of phosphates,oxides and aqueous ions

Two parameters _GO^2– and _HO^2– are defined as the differences between respectively the Gibbs free energies and the enthalpies of formation of an oxide and its corresponding aqueous cation. The Gibbs free energies and enthalpies of formation of phosphates from their consituent oxides are shown to be linear functions of respectively _GO^2– and _HO^2– of their constituent cations.     

Groundwaters of the Central Ethiopian Rift: diagnostic trends in trace elements, δ<Superscript>18</Superscript>O and major elements

The Ethiopian Rift (a major portion of the Great East African Rift) is characterized by a narrow elongated depression bounded by highlands from both sides. This topographic configuration leads to a monsoon redistribution which resulted in an arid rift floor and humid high rainfall highlands. The rifting and associated volcanism also caused a thinning of the crust and facilitates influx of CO₂ and other mantle gases as diffuse sources or along faults from deeper sources. Groundwaters in the rift floor are usually of high mineral content (high F, U, As and salinity) while those on the plateau are of low mineral content. Among many factors, groundwater availability and quality in the rift floor aquifers is the function of their connection to the aquifers in the high rainfall plateau and the residence time of groundwater prior to reaching the rift floor. This entails the need for addressing one basic hydrologic question in such a setting: at what depth and rate does recharge from the high rainfall highland reach the lowland rift aquifers? This study uses spatial variations in trace elements and relates them to ¹⁴C variations, thereby investigating the suitability of using trace elements as proxies for residence time estimation of groundwaters of relatively short (1,000–2,000 years) residence time. This work also investigates the behavior of trace element trends along the groundwater flow path in a rifted setting and compares them with such trends in sedimentary aquifers elsewhere. The comparison shows a clear difference in behavior of trace elements along the groundwater flow path when compared with such variations in big sedimentary basins with no prominent rifting and volcanism, suggesting the need of calibrating the relation between trace elements and any direct residence time indicators. An integrated use of major elements, trace elements, and environmental isotopes reveals that the main recharge of the aquifers originates from mountain blocks and that recharge takes place via fractures with no evidence of evaporation prior to recharge. Redox processes appear to play a limited role in trace element geochemistry of groundwaters in the region. Progressive trends in trace element composition along the groundwater flow path suggest continuous groundwater flow from the plateau.