The Dual-Domain Porosity Apparatus: Characterizing Dual Porosity at the Sediment/Water Interface

The characterization of pore-space connectivity in porous media at the sediment/water interface is critical in understanding contaminant transport and reactive biogeochemical processes in zones of groundwater and surface-water exchange. Previous in situ studies of dual-domain (i.e., mobile/less-mobile porosity) systems have been limited to solute tracer injections at scales of meters to hundreds of meters and subsequent numerical model parameterization using fluid concentration histories. Pairing fine-scale (e.g., sub-meter) geoelectrical measurements with fluid tracer data over time alleviates dependence on flowpath-scale experiments, enabling spatially targeted characterization of shallow sediment/water interface media where biogeochemical reactivity is often high. The Dual-Domain Porosity Apparatus is a field-tested device capable of variable rate-controlled downward flow experiments. The Dual-Domain Porosity Apparatus facilitates inference of dual-domain parameters, i.e., mobile/less-mobile exchange rate coefficient and the ratio of less mobile to mobile porosity. The Dual-Domain Porosity Apparatus experimental procedure uses water electrical conductivity as a conservative tracer of differential loading and flushing of pore spaces within the region of measurement. Variable injection rates permit the direct quantification of the flow-dependence of dual-domain parameters, which has been theorized for decades but remains challenging to assess using existing experimental methodologies.     

Biogeochemical Modelling of a Seasonally Anoxic Lake: Calibration of Successive and Competitive Pathways and Processes in Lake Aydat,France

A reactive transport model was developed to describe seasonal variations of biogeochemical and physical processes in Lake Aydat. The model includes physical processes such as vertical mixing, sedimentation and advection related to inflows into the lake and biogeochemical conversion processes in the water column and in the sediment surface layer. The reactions described in the model include primary redox reactions such as primary production, aerobic and anaerobic respiration, methanogenesis and secondary reactions established between oxidants and reducers produced by the primary reactions. After adjusting various kinetic constants, the model reasonably reproduced the main features of seasonal variations of dissolved oxygen and nitrate depth profiles and pH. The reactive transport model was also used to quantify the relative importance of different biogeochemical pathways. For instance, ferrous denitrification seems to play an important role when stratification is increasing.     

Scattering of seismic waves by cracks in multi-layered geological regions: II. Numerical results

The mechanical model for plane strain, time-harmonic seismic wave propagation problems in cracked, multi-layered geological regions with surface topography and non-parallel interfaces was described in the first part of this work. Here, this model is used to investigate the response of such a region to the presence of traveling elastic waves generated by a seismic source. The computational methodology that was developed in the first part is based on a combination of both the regular (displacement-based) and the hypersingular (traction-based) Boundary Integral Equation Method (BIEM). First, the accuracy and convergence characteristics of this hybrid BIEM are studied. Then, a series of problems involving four different configurations of a reference geological deposit with both interface and internal cracks are solved, for a loading that is due to a seismically-induced pressure wave propagating upwards from the underlying rigid half-plane. The purpose of the numerical study is to investigate the influence of various key parameters of the problem, such as frequency and incidence angle of the incoming wave, size of the surface relief, location and size of the buried cracks, interaction effects between cracks and finally the presence of layers, on both the scattered displacement field and the stress concentration field.     

Fluid immiscibility in late-Alpine gold-bearing veins,Eastern and Northwestern European Alps

Gold-bearing quartz veins fill late-Alpine brittle structures in Pennine nappes of Austria (in the Tauern window) and in northern Italy. The veins formed in the latter stages of uplift of the Alps. Fluid inclusions in veins sampled from Böckstein, Austria, and Valle Anzasca, Italy have a wide variety of compositions, ranging from aqueous brine (about 5 wt% NaCl equiv.) to about 50 mol% CO₂. At room temperature, the inclusions range with increasing CO₂ content from two-phase aqueous, through three-phase in which the CO₂ homogenizes to vapour, to three-phase with CO₂ homogenizing to liquid. This wide range of inclusion compositions is interpreted as evidence for fluid immiscibility, with most inclusions being accidental mixtures of the two end-member immiscible fluids. The homogenization temperatures of the aqueous inclusions, 200–280°C, gives the best estimate of temperature of formation of the veins. Vein formation fluid pressure at Böckstein and Valle Anzasca was about 1 kbar, and Böckstein veins formed at lower pressure than Valle Anzasca veins. Fluid immiscibility may have contributed to deposition of gold at both Valle Anzasca and Böckstein, and possibly many other uplift-related Alpine gold localities.     

A search for nickel isotopic anomalies in iron meteorites and chondrites

We report Ni isotopic data, for ^58,60-62Ni, on (1) FeNi metal and sulfides in different groups of iron meteorites, (2) sulfides and a whole rock sample of the St. Séverin chondrite, and (3) chondrules from the Chainpur chondrite. We have developed improved, Multiple-Collector, Positive ion Thermal Ionization Mass Spectrometric (MC-PTIMS) techniques, with Ni⁺ ionization efficiency at 1‰, and chemical separation techniques for Ni which reduce mass interferences to the 1 ppm level, so that no mass interference corrections need be applied, except for ⁶⁴Ni (from ⁶⁴Zn, at the 0.1‰ level), for which we do not report results. We normalize the data to ⁶²Ni/⁵⁸Ni to correct for mass dependent isotope fractionation. No evidence was found for resolved radiogenic or general Ni isotope anomalies at the resolution levels of 0.2 and 0.5 εu (εu = 0.01%) for ⁶⁰Ni/⁵⁸Ni and ⁶¹Ni/⁵⁸Ni, respectively. From the ⁵⁶Fe/⁵⁸Ni ratios and ε(⁶⁰Ni/⁵⁸Ni) values, we calculate upper limits for the initial value of (⁶⁰Fe/⁵⁶Fe)₀ of (a) <2.7 × 10⁻⁷ for Chainpur chondrules, (b) <10⁻⁸ for the St. Séverin sulfide, and (c) <4 × 10⁻⁹ for sulfides from iron meteorites. We measured some of the same meteorites measured by other workers, who reported isotopic anomalies in Ni, using Multiple-Collector, Inductively-Coupled Mass Spectrometry. Our results do not support the previous reports of Ni isotopic anomalies in sulfide samples from Mundrabilla by Cook et al. [Cook D. L., Clayton R. N., Wadhwa M., Janney P. E., and Davis A. M. (2008). Nickel isotopic anomalies in troilite from iron meteorites. Geophy. Res. Lett. 35, L01203] and in sulfides from Toluca and Odessa by Quitté et al. [Quitté G., Meier M., Latkoczy C., Halliday A. N., and Gunther D., (2006). Nickel isotopes in iron meteorites-nucleosynthetic anomalies in sulfides with no effects in metals and no trace of ⁶⁰Fe. Earth Planet. Sci. Lett. 242, 16-25]. Hence, we find no need for specialized physical-chemical planetary processes for the preservation of different Ni isotope compositions, between FeNi metal and sulfides in the same iron meteorites, as proposed by the above reports nor for complex astrophysical scenarios to provide the very peculiar Ni isotope anomalies reported by these workers for sulfides.     

Heavy metal content in the stream sediments adjacent to a sanitary landfill

Samples of stream sediments were collected along two streams adjacent to a sanitary landfill. One of the streams drained the landfill directly. In addition, control of background samples were also analyzed from a stream not affected by the landfill. All samples were analyzed for Ag, Zn, Cu, Cd, and Pb content using atomic adsorption techniques. The pH of the three streams were monitored since pH differences in the streams may affect the quantities of metals adsorbed or precipitated on the sediments. The comparison between the content of Ag, Zn, and Cu in the sediments of the two study streams and the same metals in the control sediments indicated the landfill emitted these metals into the two adjacent streams. However, since the Cd and Pb contents in the sediments of both streams were similar to that of the control stream sediments, these metals may not be emitted into the two study streams from the landfill and they represent only background quantities. The comparisons of each metal in the sediments of each stream were made by the use of a metal trend chart, the individual calculated mean metal content values, and by the statistical two sample t-test. No decreasing trends of the quantities of Ag, Zn, or Cu as a function of increasing distance from the landfill was present in the sediments along the stream that drained the landfill directly. These sediments might have been affected by stream action and became mixed with other sediments downstream.     

Reviews

OFFICE DEVELOPMENT: A Geographical Analysis by M. Bateman. 14 × 22 cm, xvi and 175 pages. Croom Helm: London 1985 (ISBN 0 7099 0697 8) $A35.95 (cloth).

ATLAS OF YOUTH UNEMPLOYMENT, 1981: The Geographic Distribution of Youth Unemployment in Australian Cities from the 1981 Census According to Birthplace and Gender by P. Matwijiw with E. Bamford and C. Maher. 21 × 29 cm, 127 pages. Australian Institute of Multicultural Affairs: Melbourne 1985 (ISBN 949890 33 2) $A12.00 (limp).

ENVIRONMENT AND HEALTH by A. J. Rowland and P. Cooper. 23 × 16 cm, vi and 205 pages. Edward Arnold: London 1983 (ISBN 0 7131 2855 0) $A27.95 (limp).

FAMINE AS A GEOGRAPHICAL PHENOMENON edited by B. Currey and G. Hugo. 17 × 24 cm, vi and 202 pages. Reidel: Dordrecht 1984 (ISBN 90 277 1762 1) Dfl 95.00, $US37.00 (cloth).

SOUTH AUSTRALIA'S CHANGING POPULATION (South Australian Geographical Papers No. 1) by G. J. Hugo. 25 × 18 cm, 71 pages. Royal Geographical Society of Australasia (SA Branch): Adelaide 1983 (ISBN 0 909112 05 03) $A4.00 (limp).

DEVELOPMENTS IN POLITICAL GEOGRAPHY edited by M. A. Busteed. 23 × 15 cm, 340 pages. Academic Press: London 1983 (ISBN 0 12 148420 3) $US42.00 (cloth).

NEITHER JUSTICE NOR REASON: A Legal and Anthropological Analysis of Aboriginal Land Rights by M. Gumbert. 22 × 14 cm, xv and 215 pages. University of Queensland Press: St Lucia 1984 (ISBN 0 7022 1746 8) $A20.00 (cloth).

RURAL RESOURCE MANAGEMENT by P. J. Cloke and C. C. Park. 14 × 22 cm, xiii and 473 pages. Croom Helm: London 1985 (ISBN 0 7099 2037 7) $A44.95 (cloth).

FARM POLICY IN AUSTRALIA by R. K. Hefford. 14 × 22 cm, xviii and 415 pages. University of Queensland Press: St Lucia 1985 (ISBN 0 7022 1698 4) $A40.00 (cloth).

TRANSPORT AND COMMUNICATIONS FOR PACIFIC MICROSTATES: Issues in Organisation and Management edited by C. C. Kissling. 14 × 21 cm, 192 pages. Institute of Pacific Studies, University of the South Pacific: Suva 1984. $A10.00 (cloth), $A8.00 (limp).

TIMES OF CRISIS: Epidemics in Sydney 1788–1900 by P. H. Curson. 15 × 25 cm, xii and 195 pages. Sydney University Press: Sydney 1985 (ISBN 0 424 00112 8). $A35.00 (cloth).

PEASANTS, SUBSISTENCE, ECOLOGY AND DEVELOPMENT IN THE HIGHLANDS OF PAPUA NEW GUINEA by L. S. Grossman. 24 × 16 cm, xxi and 302 pages. Princeton University Press: Princeton, NJ 1984 (ISBN 0 691 09406 3) $US45.50.

THE WORLD FOOD PROBLEM 1950–1980 by D. Grigg. 15 × 24 cm, 276 pages. Basil Blackwell: Oxford 1985 (ISBN 0 631 13481 6) $A58.50 (cloth).

POPULATION REDISTRIBUTION AND DEVELOPMENT IN SOUTH ASIA edited by L. A. Kosinski and K. M. Elahi. 17 × 24 cm, 243 pages. Reichel: Dordrecht 1985 (ISBN 90 277 1938 1) Dfl 120.00, $US44.00, £30.50 (cloth).

GEOGRAPHY AND ETHNIC PLURALISM edited by C. Clarke, D. Ley and C. Peach. 15 × 23 cm, xvii and 294 pages. Allen & Unwin: London 1984 (ISBN 0 04 309107 5) $A45.00 (cloth); (ISBN 0 04 309108 3) $A24.95 (limp).

SOCIAL GEOGRAPHY IN INTERNATIONAL PERSPECTIVE edited by J. Eyles. 14 × 22 cm, 295 pages. Croom Helm: London 1986 (ISBN 0 7099 0944 6) $A49.95 (cloth).

THE GENTRIFICATION OF INNER MELBOURNE: A Political Geography of Inner City Housing by W. S. Logan. 14 × 22 cm, xvi and 328 pages. University of Queensland Press: St. Lucia 1985 (ISBN 0 7022 1729 8) $A50.00 (cloth).

YELLOWCAKE AND CROCODILES: Town Planning, Government and Society in Northern Australia by J. Lea and R. Zehner. 14 × 22 cm, xxvi and 200 pages. Allen & Unwin: Sydney 1986 (ISBN 0 86861 875 6) $A24.95 (cloth); (ISBN 0 86861 843 8) $A 14.95 (limp).

THE BUNGALOW: The Production of a Global Culture by A. D. King. 20 × 25 cm, xii and 310 pages. Routledge & Kegan Paul: London 1984 (ISBN 0 7100 9538 4) $A62.50 (cloth).

THE WEST EUROPEAN CITY: A Social Geography by P. White. 15 × 23 cm, xviii and 269 pages. Longman: London 1984 (ISBN 0 582 30047 9) $A22.95 (limp).

THE SHAPING OF AMERICA: A Geographical Perspective on 500 years of History. Volume 1. Atlantic America, 1492–1800 by D. W. Meinig. 18 × 25 cm, xii and 500 pages. Yale University Press: New Haven 1986 (ISBN 0 300 03548 9) $US35.00 (cloth).

CANBERRA: MYTHS AND MODELS. Forces at Work in the Formation of the Australian Capital by K. F. Fischer. 21 × 30 cm, 166 pages. Institute of Asian Studies: Hamburg 1984 (ISBN 3 88910 009 0).

THE GEOGRAPHY OF PEACE AND WAR edited by D. Pepper and A. Jenkins. 15 × 23 cm, vi and 222 pages. Basil Blackwell: Oxford 1985 (ISBN 0 631 13559 6) $A75.00 (cloth); (ISBN 0 631 14069 7) $A23.95 (limp).

POLITICAL GEOGRAPHY: World‐economy, Nation‐state and Locality by P. J. Taylor. 15 × 23 cm, × and 238 pages. Longman: London 1985 (ISBN 0 582 30088 6) $A24.95 (limp).

THE INDUSTRIAL GEOGRAPHY OF CANADA by A. Blackbourn and R. G. Putnam 14 × 22 cm, 201 pages. Croom Helm: London 1984 (ISBN 0 7099 0622 6) $A42.50 (cloth).

THE FOODMAKERS by S. Sargent. 13 × 20 cm, 296 pages. Penguin: Ringwood 1985 (ISBN 0 14 007359 0) $A8.95 (limp).

LIMITS TO PREDICTION edited by R. B. McKern and G. C. Lowenthal. 13 × 19 cm, xiii and 163 pages. Australian Professional Publications: Sydney 1985 (ISBN 0 949416 029) $A14.95 (limp).

THE KANGAROO KEEPERS edited by H. J. Lavery. 18 × 25 cm, xxvi and 211 pages. University of Queensland Press: St Lucia 1985 (ISBN 0 7022 1875 8).

PRACTICAL ECOLOGY by D. D. Gilbertson, M. Kent and F. B. Pyatt. 15 × 23 cm, 320 pages, Hutchinson: London 1985 (ISBN 0 09 162651 X) £8.95.

BASIC BIOGEOGRAPHY (Second edition) by N. Pears. 15 × 24 cm, × and 358 pages. Longman: London 1985 (ISBN 0 582 30120 3) $A24.95 (limp).

ENVIRONMENTAL CHANGE (Second edition) by A. Goudie. 23 × 15 cm, xi and 258 pages. Oxford University Press: Oxford 1983 (ISBN 0 19 874135 9) A16.00 (limp).

MEGA‐GEOMORPHOLOGY edited by R. Gardner and H. Scoging. 16 × 24 cm, xiii and 240 pages. Oxford University Press: Oxford (ISBN 0 19 823244 6) $A48.00.

GRANITE LANDFORMS by C. R. Twidale. 25 × 17 cm, xxiii and 372 pages. Elsevier: Amsterdam 1982 (ISBN 0 444 42116 5) $A148.25.     

Climate change in Lake Baikal: diatom evidence in an area of continuous sedimentation

The presence of inhomogeneous sedimentation is acknowledged as being an important problem in palaeolimnological studies. Sediment records can be disturbed by erosional and redepositional events, which redeposit microfossils within a basin and may then lead to misinterpretations of fossil diatom assemblages. This study uses a combination of sedimentological tools, magnetic susceptibility measurements and high-resolution diatom analysis to show that a sediment core, BAIK80, taken in 345 m water depth from a shoulder region in the North Basin of Lake Baikal, is free of disturbances. Our results confirm that the sediment record is consistent and continuous for the uppermost sediment. Consequently, the fossil diatom data can be used to establish a continuous record of past climate variability over approximately the past 1300 years. Distinct changes occur in downcore abundances of endemic taxa Aulacoseira baicalensis and Cyclotella minuta, and principal components analysis (PCA) indicates a gradual transformation of taxa over the past 1300 years. These changes are likely to be related to climate, although definite links still have to be established. Received: 15 December 1998 / Accepted: 13 September 1999     

The Gaussian curvature of associated manifold of dynamical systems

A connection is shown to exist between the Gaussian curvature of the associated manifold and the ergodic or non-ergodic behaviour of certain dynamical systems of astronomical and astrophysical importance.     

Possibility of continuous monitoring of celestial X-ray sources through their ionization effects in the nocturnal D-region ionosphere

The electron production rates in the night-time D-region arising from the transit of strong celestial X-ray sources Sco X-1, Tau X-1 and Galactic Center are estimated and compared with the ambient electron production rates resulting from other known stable agencies. Using the experimentally measured values of the night-time electron densities, the number of additional electrons/cc expected from the passage of these sources is computed. For the 164 kHz transmission from Tashkent, received at Ahmedabad, the associated enhancement in the attenuation is calculated using the full wave admittance technique of Barron and Budden. Reasonable agreement is shown to exist between the calculated values of the attenuation and those of direct observations.