Formation of TiC core‐graphitic mantle grains from CO gas

Abstract— We demonstrate a new formation route for TiC core‐graphitic mantle spherules that does not require carbon‐atom addition and the very long time scales associated with such growth (Bernatowicz et al. 1996). Carbonaceous materials can be formed from C₂H₂ and its derivatives, as well as from CO gas. In this paper, we will demonstrate that large‐cage‐structure carbon particles can be produced from CO gas by the Boudouard reaction. Since the sublimation temperature for such fullerenes is low, the large cages can be deposited onto previously nucleated TiC and produce TiC core‐graphitic mantle spherules. New constraints for the formation conditions and the time scale for the formation of TiC core‐graphitic mantle spherules are suggested by the results of this study. In particular, TiC core‐graphitic mantle grains that are found in primitive meteorites that have never experienced hydration could be mantled by fullerenes or carbon nanotubes rather than by graphite. In situ observations of these grains in primitive anhydrous meteoritic matrix could confirm or refute this prediction and would demonstrate that the graphitic mantle on such grains is a metamorphic feature due to interaction of the presolar fullerenes with water within the meteorite matrix.     

Characteristics and Mineralization Age of the Fukusen No. 1 Vein,Hishikari Epithermal Gold Deposits,Southern Kyushu,Japan

The Fukusen No. 1 vein is located in the southeastern part of the Yamada deposit, Hishikari epithermal gold deposits, southern Kyushu, Japan. ⁴⁰Ar/³⁹Ar plateau ages of adularia from the margin and the center of the Fukusen vein are determined to be 0.617 ± 0.024 Ma and 0.606 ± 0.009 Ma, respectively. The Fukusen No. 1 vein shows banding structure composed mainly of quartz, adularia and clay minerals. Colloform texture is displayed by cryptocrystalline to amorphous silica material that is associated with fine-grained electrum and sulfides near the center of the vein. Pyrite in the Fukusen No. 1 vein often shows acicular shape resulting from inversion from marcasite. Near the center of the vein, primary marcasite occurs associated with colloform texture of silica. The Fukusen No.1 vein preserves primary texture and materials which were deposited from the ore-forming hydrothermal solution. The Fukusen No. 1 vein was formed in a short period and is one of the youngest veins in the Hishikari deposits.     

Dredge petrology of the boninite‐ and adakite‐bearing Hahajima Seamount of the Ogasawara (Bonin) forearc: An ophiolite or a serpentinite seamount?§

Abstract During the Hakuho‐Maru KH03‐3 cruise and the Tansei‐Maru KT04‐28 cruise, more than 1000 rock samples were dredged from several localities over the Hahajima Seamount, a northwest–southeast elongated, rectangular massif, 60 km × 30 km in size, with a flat top approximately 1100 m deep. The rocks included almost every lithology commonly observed among the on‐land ophiolite outcrops. Volcanic rocks included mid‐oceanic ridge basalt (MORB)‐like tholeiitic basalt and dolerite, calc‐alkaline basalt and andesite, boninite, high‐Mg adakitic andesite, dacite, and minor rhyolite. Gabbroic rocks included troctolite, olivine gabbro, olivine gabbronorite (with inverted pigeonite), gabbro, gabbronorite, norite, and hornblende gabbro, and showed both MORB‐type and island arc‐type mineralogies. Ultramafic rocks were mainly depleted mantle harzburgite (spinel Cr? 50–80) and its serpentinized varieties, with some cumulate dunite, wehrlite and pyroxenites. This rock assemblage suggests a supra‐subduction zone origin for the Hahajima Seamount. Compilation of the available dredge data indicated that the ultramafic rocks occur in the two northeast–southwest‐oriented belts on the seamount, where serpentinite breccia and gabbro breccia have also developed, but the other areas are free from ultramafic rocks. Although many conical serpentinite seamounts 10 km in size are aligned along the Izu–Ogasawara (Bonin)–Mariana forearc, the Hahajima Seamount may be better interpreted as a fault‐bounded, uplifted massif composed of ophiolitic thrust sheets, resembling the Izki block of the Oman ophiolite in its shape and size. The ubiquitous roundness of the dredged rocks and their thin Mn coating (<2 mm) suggest that the Hahajima Seamount was uplifted above sealevel and wave‐eroded, like the present Macquarie Is., a rare example of ophiolite exposure in an oceanic setting. The Ogasawara Plateau on the Pacific Plate is adjacent to the east of the Hahajima Seamount, and collision and subduction of the plateau may have caused uplift of the forearc ophiolite body.     

Relative influence of biotic and abiotic processes on travertine fabrics,Satono‐yu hot spring,Japan

The relative influences of biotic and abiotic processes on travertine fabrics are still not well understood, despite increasing interest in the last decade to better understand the record of ancient microbial life and sedimentary fabrics in microbial hydrocarbon reservoirs. This study examines travertines at Satono‐yu hot spring in Japan (the temperature of water flowing over the travertine was ca 35°C), to better understand the interaction between depositional, hydrochemical and microbial parameters at different flow settings. Characteristics of the bulk hydrochemistry, mineralogy (exclusively aragonite) and the driving force for precipitation (primarily abiotic CO₂ degassing with some photosynthetic microbial contribution) were similar among all of the flow settings. Conversely, the increase in flow velocity suppressed the influence of photosynthesis and enhanced the abiotic precipitation due to the thinner diffusive boundary layer at the travertine surface–water interface. Additionally, the increase in flow velocity changed the microbial composition and decreased the bacterial diversity by reflecting their adhesion efficiency on the travertine substrate. The acidity of the cyanobacterial sheaths controls the aragonite nucleation rate and the resulting calcification, even at significantly high equilibrium CO₂ partial pressure (ca 22 to 28 matm), high dissolved inorganic carbon concentration (ca 35 to 38 mmol l^?1), and elevated aragonite saturation state (ca 20‐fold to 34‐fold). Therefore, the increase in flow velocity suppresses the microbial influence with respect to the increase in the saturation state, the nucleation site supply and pore space generation. Overall, this results in the predominance of abiotic precipitation under high flow velocities. Consequently, a sparse‐micritic fabric with abundant interlamina porosity forms under lower flow velocity where the microbial influence is effective, while a dense‐sparitic fabric with little inter‐crystalline porosity forms under higher flow velocity where abiotic precipitation prevails. These findings provide an essential base for assessing the formation processes of ancient travertines and comparable deposits from petrological fabrics.     

Constraining tephra dispersion and deposition from three subplinian explosions in 2011 at Shinmoedake volcano,Kyushu, Japan

Constraining physical parameters of tephra dispersion and deposition from explosive volcanic eruptions is a significant challenge, because of both the complexity of the relationship between tephra distribution and distance from the vent and the difficulties associated with direct and comprehensive real-time observations. Three andesitic subplinian explosions in January 2011 at Shinmoedake volcano, Japan, are used as a case study to validate selected empirical and theoretical models using observations and field data. Tephra volumes are estimated using relationships between dispersal area and tephra thickness or mass/area. A new cubic B-spline interpolation method is also examined. Magma discharge rate is estimated using theoretical plume models incorporating the effect of wind. Results are consistent with observed plume heights (6.4–7.3 km above the vent) and eruption durations. Estimated tephra volumes were 15–34?×?10⁶ m³ for explosions on the afternoon of 26 January and morning of 27 January, and 5.0–7.6?×?10⁶ m³ for the afternoon of 27 January; magma discharge rates were in the range 1–2?×?10⁶ kg/s for all three explosions. Clast dispersal models estimated plume height at 7.1?±?1 km above the vent for each explosion. The three subplinian explosions occurred with approximately 12-h reposes and had similar mass discharge rates and plume heights but decreasing erupted magma volumes and durations.     

Long-term denudation rates of actively uplifting hillcrests in the Boso Peninsula, Japan, estimated from depth profiling of in situ-produced cosmogenic Be and Al

Depth profiling of in situ-produced cosmogenic ¹⁰Be and ²⁶Al was applied to estimate the rate of long-term denudation on actively uplifting hillcrests made of weakly consolidated sandstone in the Boso Peninsula, Japan. The nuclide concentration in the topmost meter of the hillcrest has reached an equilibrium value owing to surface denudation at 90 mm/kyr. This rate is much smaller than the regional uplift rate, and is consistent with the current isolated residual topography of the hillcrest. By considering the epoch of emergence of the sandstone hillcrests, we estimate the summit denudation rate of the adjacent mudstone hill formation to be 720 ± 110 mm/kyr.