The use of RFID in soil‐erosion research

In this paper, we examine the use of radio frequency identification (RFID) tags for studying soil erosion. Surrogate soil particles were created by coating RFID tags with silicone clay and bronze powder to give them an overall density similar to that of quartz particles. The particles were between 2.5 mm and 4.0 mm in diameter and had specific weights of 2.5 to 3.0. These tagged particles were deployed on two plots: first, in a proof‐of‐concept laboratory study and secondly in a field study, the latter involving repeated surveys after rainfall events. Seven surveys under natural rainfall over four months yielded recovery rates averaged 56%. RFIDs are shown to provide useful insights into the movement of individual soil particles during erosion processes. As RFID technology advances, further miniaturization is likely to occur enabling the movement of a greater range of soil particles to be studied, and we may anticipate improvements to the signal detection so that recovery does not rely wholly on visual identification. Copyright © 2014 John Wiley & Sons, Ltd.     

High-pressure phase transitions of CaRhO<Subscript>3</Subscript> perovskite

High-pressure phase transitions of CaRhO₃ perovskite were examined at pressures of 6–27 GPa and temperatures of 1,000–1,930°C, using a multi-anvil apparatus. The results indicate that CaRhO₃ perovskite successively transforms to two new high-pressure phases with increasing pressure. Rietveld analysis of powder X-ray diffraction data indicated that, in the two new phases, the phase stable at higher pressure possesses the CaIrO₃-type post-perovskite structure (space group Cmcm) with lattice parameters: a = 3.1013(1) Å, b = 9.8555(2) Å, c = 7.2643(1) Å, V _m  = 33.43(1) cm³/mol. The Rietveld analysis also indicated that CaRhO₃ perovskite has the GdFeO₃-type structure (space group Pnma) with lattice parameters: a = 5.5631(1) Å, b = 7.6308(1) Å, c = 5.3267(1) Å, V _m  = 34.04(1) cm³/mol. The third phase stable in the intermediate P, T conditions between perovskite and post-perovskite has monoclinic symmetry with the cell parameters: a = 12.490(3) Å, b = 3.1233(3) Å, c = 8.8630(7) Å, β = 103.96(1)°, V _m  = 33.66(1) cm³/mol (Z = 6). Molar volume changes from perovskite to the intermediate phase and from the intermediate phase to post-perovskite are –1.1 and –0.7%, respectively. The equilibrium phase relations determined indicate that the boundary slopes are large positive values: 29 ± 2 MPa/K for the perovskite—intermediate phase transition and 62 ± 6 MPa/K for the intermediate phase—post-perovskite transition. The structural features of the CaRhO₃ intermediate phase suggest that the phase has edge-sharing RhO₆ octahedra and may have an intermediate structure between perovskite and post-perovskite.     

Profiles of nonylphenol isomers in surface waters from Sri Lanka

Isomer-specific concentrations of nonylphenol (NP) and their predicted estrogenic potency were investigated in Sri Lankan waters for the first time. The total concentration of 13 NP isomers ranged from 90 to 1835 ng/L, while the predicted estrogenic equivalent concentration ranged from 0.072 to 1.38 ng 17β-estradiol (E2)/L. Bire Lake, located in the central area of the commercial capital, Colombo, had the highest contamination among the studied locations. These data show that NP levels in Sri Lankan waters are well within the recently reported concentrations in other regions of the world. The spatial differences in NP concentrations suggest that NP contamination in Sri Lanka may be widespread, and comprehensive study is vital.     

Discrete‐like crack simulation by smeared crack‐based FEM for reinforced concrete

A numerical process that simulates crack propagation in reinforced concrete through post‐crack stress redistribution is presented. This process is developed within the context of the smeared crack approach. Continuity and orientation of the reinforcing bar components are automatically recognized in the pre‐processing stage. The process explicitly outputs crack widths by computing the bond slips along reinforcement, without imposing any additional nodes between the reinforcement and concrete. The process is incorporated with a finite element algorithm, and the validation is investigated through sample 3D static analyses of nine concrete specimens subjected to monotonic shear and flexure loads. These specimens contain relatively well‐distributed steel bars and fiber reinforced polymer (FRP) sheets of reinforcement ratio from 0.11 to 0.57%. The analyses predict the crack patterns and crack widths well, although some disagreements are found between the test and the analysis results. The proposed process outputs discrete, continuous in crack directions, and element boundary‐free crack patterns. Copyright © 2007 John Wiley & Sons, Ltd.     

Estrogen equivalent concentration of individual isomer-specific 4-nonylphenol in Ariake sea water, Japan

Concentrations of 4-nonylphenol (NP) were determined by isomer-specific quantification of individual NP isomers based on relative response factor (RRF) quantification with GC–MS in combination with steam distillation extraction. Concentrations of NP in the Ariake Sea decreased with distance from the river mouth (St.A; 49 ng NP/l) to offshore areas (St.C; 11 ng NP/l). Even the least concentration in water from St.C in Ariake Sea was sufficient to have adverse effects on barnacles. The isomers, NP1–NP14 were separated by GC–PFC and identified structurally with NMR. The isomers varied in estrogenic activity with NP7 exhibiting the greatest estrogenic activity with a potency that was approximately 1.9 × 10⁻³ that of 17β-estradiol (E2) in recombinant yeast screen system. The coefficient of variation (CV) of NP isomer’s concentrations among three samples at St.A, B and C were 4–75%. This suggests that NP isomers might be independently degraded in aquatic environmental samples. The predicted estrogenic activity of measured concentrations of NP in Ariake Sea was 2.7–3.0-fold greater than the measured estrogen agonist activity.     

Seepage erosion and its implication to the formation of amphitheatre valley heads: A case study at Obara,Japan

Seepage erosion was investigated in an amphitheatre with a semicircular valley head, steep slopes, and a flat bottom developed in granodiorite hills at Obara, Aichi prefecture, Japan. A high sediment yield occurred where the measuring sites were located at the base of the landslide debris in the base of the convex slopes, whereas sediment outflows were small where the measuring sites were located at the base of the strong convex slopes. This implies that the seepage erosion was an effective agent for removal of debris deposited at the base of the slope. Small landslides can be found at the lower slopes within the area of the observed amphitheatre. The slope stability analysis and subsurface water observation of the lower slope suggest that the small landslides in this amphitheatre are due to over-steepened slopes, and relatively insensitive to subsurface water status. Colluvium in the flat valley bottom thinly covers the bedrock surface. Therefore the topography of the amphitheatre was found to be formed by parallel retreat of slopes by the repetition of basal seepage erosion and subsequent small landslides.     

A possible Caledonide arm through the Barents Sea imaged by OBS data

The assembly of the crystalline basement of the western Barents Sea is related to the Caledonian orogeny during the Silurian. However, the development southeast of Svalbard is not well understood, as conventional seismic reflection data does not provide reliable mapping below the Permian sequence. A wide-angle seismic survey from 1998, conducted with ocean bottom seismometers in the northwestern Barents Sea, provides data that enables the identification and mapping of the depths to crystalline basement and Moho by ray tracing and inversion. The four profiles modeled show pre-Permian basins and highs with a configuration distinct from later Mesozoic structural elements. Several strong reflections from within the crystalline crust indicate an inhomogeneous basement terrain. Refractions from the top of the basement together with reflections from the Moho constrain the basement velocity to increase from 6.3 km s⁻¹ at the top to 6.6 km s⁻¹ at the base of the crust. On two profiles, the Moho deepens locally into root structures, which are associated with high top mantle velocities of 8.5 km s⁻¹. Combined P- and S-wave data indicate a mixed sand/clay/carbonate lithology for the sedimentary section, and a predominantly felsic to intermediate crystalline crust. In general, the top basement and Moho surfaces exhibit poor correlation with the observed gravity field, and the gravity models required high-density bodies in the basement and upper mantle to account for the positive gravity anomalies in the area. Comparisons with the Ural suture zone suggest that the Barents Sea data may be interpreted in terms of a proto-Caledonian subduction zone dipping to the southeast, with a crustal root representing remnant of the continental collision, and high mantle velocities and densities representing eclogitized oceanic crust. High-density bodies within the crystalline crust may be accreted island arc or oceanic terrain. The mapped trend of the suture resembles a previously published model of the Caledonian orogeny. This model postulates a separate branch extending into central parts of the Barents Sea coupled with the northerly trending Svalbard Caledonides, and a microcontinent consisting of Svalbard and northern parts of the Barents Sea independent of Laurentia and Baltica at the time. Later, compressional faulting within the suture zone apparently formed the Sentralbanken High.     

Recession rates of waterfalls in Boso Peninsula,Japan, and a predictive equation

Rates of waterfall recession, and major factors that influence the rate, were studied using waterfalls in Boso Peninsula, Japan. The mean rate of waterfall recession was estimated by determining the age and original location. The principal factor in determining the rate of waterfall recession is the ratio of the erosive force of stream to the bedrock resistance. This is expressed in terms of measurable variables, which include the discharge (drainage area and precipitation), the width and height of the waterfall, and the unconfined compressive strength of the bedrock. An empirical equation connecting the force/resistance ratios and the rates of waterfall recession is derived. Copyright © 2003 John Wiley & Sons, Ltd.     

Partitioning Eddy-Covariance Methane Fluxes from a Shallow Lake into Diffusive and Ebullitive Fluxes

Methane (\(\mathrm {CH}_{4}\)) is known to be emitted from lakes to the atmosphere via processes such as diffusion and ebullition (i.e., bubble emission). We developed a practical method for partitioning eddy-covariance \(\mathrm {CH}_{4}\) fluxes from a shallow lake into diffusive and ebullitive fluxes using a wavelet analysis based on local scalar similarity between the \(\mathrm {CH}_{4}\) concentration and other reference scalars, such as the air temperature or water vapour concentration, in the wavelet time-scale domain, with the hypothesis that similar and dissimilar fluctuation components are related to diffusive and ebullitive \(\mathrm {CH}_{4}\) fluxes, respectively. Our method is applied to approximately two weeks of data obtained at a shallow mid-latitude lake. The partitioned diffusive flux has a physically sound relationship with wind speed, supporting the validity of the method. The ratio of the diffusive flux to the total flux is typically 0.11 with flow from an area of steady bubble emission, but otherwise 0.36. Further validation is required using a larger dataset and data from other lakes. The proposed method can be easily applied to historical data because it requires only 10-Hz data of \(\mathrm {CH}_{4}\) concentration and other reference scalars, along with an empirical parameter.