样品处理与保存方法对表层沉积物中金属形态分析的影响

利用改进的Tessier连续萃取法研究了冷藏、冷冻、冻干、烘干和风干等样品处理与保存方法对表层沉积物中金属形态的影响。结果表明：各样品处理与保存过程对沉积物中Fe、Mn、Cu、Zn及Pb的形态均具有不同程度的影响,其中Fe的形态受其影响最小（<3.3%）,Mn的形态受其影响最大（最高可达10.2%）;冻干对各金属形态的影响最小（<4.6%）;烘干和风干对重金属Cu、Zn和Pb的可交换态（Ⅰ+Ⅱ）和非残渣态（Ⅰ-Ⅴ）分布影响较大,而冷藏、冷冻和冻干的影响相对较小。因此,综合考虑重金属的形态分布及其生物可利用性,冻干是较理想的沉积物样品处理与保存方法。     

Prediction method of debris flow by logistic model with two types of rainfall: a case study in the Sichuan, China

Debris flow is a serious disaster that frequently happens in mountainous area. This study presents an effective method for forecasting it by rainfall, which is one of the important components for prediction. The Sichuan Province is taken as an example. The geographic information system (GIS) is chosen as a tool to estimate the precipitation of hazard point, and use of statistical technique is made to calculate attenuation coefficient of effective antecedent precipitation. With such methodologies, the logistic regression model is used to comparatively establish the prediction model of two forms rainfall combination: (1) intraday rainfall and 10-day previous rainfall, (2) intraday rainfall and two types of effective antecedent rainfall which are short-time-heavy rainfall and long-time-light rainfall. The results indicate that the location of debris flows and the distribution of rainfall are factors interrelated. Secondly, the contribution rate of intraday rainfall is the highest. Thirdly, the second form rainfall combination has a higher prediction accuracy, 2.3% for short-time-heavy rainfall and 2.1% for long-time-light rainfall, which suggests that a moderate improvement is achieved by the rainfall classification.     

新疆库松木切克山喇嘛萨依式铜矿的勘查标志

本文通过对库松木切克山喇嘛萨依铜矿地质特征及控矿因素的研究,总结出该类矿床的若干勘查标志,其中地层层位、含矿岩相、地球化学异常、容矿岩石、围岩蚀变、活化脉体及同生断裂等最为明显。在区域内如能确定出这些标志,尤其是标志组合的存在,则将可能取得该类矿床找矿的新突破。     

汝阳盆地早白垩世恐龙蛋壳的发现及其意义

汝阳盆地是豫西地区的一个中—新生代断陷盆地,自2006年以来发现了一个以巨型蜥脚类恐龙为代表的恐龙动物群。本文描述了近期发现于汝阳盆地下白垩统郝岭组中的若干恐龙蛋蛋壳碎片。基于以下对蛋壳宏观形态和显微特征的分析,这些蛋壳碎片可以归入长形蛋科(Elongatoolithidae)的长形蛋属(Elongatoolithus):蛋壳外表面具分散瘤点状或线性脊状的纹饰;蛋壳自内而外分为锥体层和柱状层,二层之间的界线不清晰;锥体层中锥体排列紧密;柱状层中具波浪状的平行生长纹。这一发现代表了长形蛋属在早白垩世地层中的首次记录,进一步拓展了该蛋属的地史和古地理分布。由以往已知的化石关联推测,这些蛋壳可能与该层位中的窃蛋龙类如刘店洛阳龙(Luoyanggia liudianensis)等具有相关性,表明汝阳盆地在早白垩世晚期具有适宜该类恐龙生存与繁殖的环境。     

Nonlinear stochastic correlation models for the pole’s motion of a deformable Earth

A combined stochastic correlation model for the pole’s motion of a deformable Earth is constructed using the data of the International Earth Rotation Service and dynamical Euler equations taking into account tidal deformations. The deterministic component of the model describes the main regular dynamical effects, while its stochastic component describes irregular effects obeying statistical laws. Linear differential (requiring solutions of ordinary differential equations), and finite (assuming integrated characteristics) correlation models are constructed for both Gaussian and non-Gaussian random parameters. The stochastic oscillations and trend of the Earth’s proper angular velocity are analyzed, as well as nonlinear stochastic oscillations and the trend of the pole. This approach can be considered quite novel.     

WEP模型全局参数敏感性分析及其在汉江上游流域的应用

水文模型敏感性分析是用来确定控制模型效率关键参数非常有效的过滤工具之一,并可以帮助理解模型结构,乃至发现模型的结构缺陷,从而有可能改善模型结构.本文通过将全局敏感性分析方法的LH-OAT方法应用到WEP-L模型.并在汉江上游向家坪以上流域进行了成功应用.研究发现.通过LH-OAT方法分析,对于汉江上游向家坪以上流域,河道曼宁糙率和坡面曼宁糙率是影响NaSh效率系数最重要的参数.通过对这两个参数的手动调参,模拟的日Nash效率系数从0.35提高到0.75.     

Petrogenesis of the island-arc complexes of the Chara zone,East Kazakhstan

The study of clinopyroxenes and melt inclusions provided direct (independent on secondary alteration) information on the petrogenesis of the island arc complexes of the Chara zone, East Kazakhstan. It was shown that magmatism of this zone evolved from primitive island-arc systems with boninites to mature island arc with calc-alkaline melts. In terms of trace and rare-earth element distribution, the melt inclusions in the clinopyroxenes of the Chara zone differ from mid-ocean ridge basalts, being closer to the island-arc calcalkaline series. Based on inclusion composition, the parental melts of the considered complexes crystallized within 1150–1190°C with decreasing iron, magnesium, calcium, and sodium contents. Simulation based on melt inclusion data in clinopyroxenes indicates that the melts contained up to 1 wt % water, which was confirmed by direct ion-microprobe determination of 0.84 wt % H₂O in the inclusions. Calculated liquidus temperatures are consistent with homogenization temperatures of the inclusions. Our calculations on the basis of inclusion data testify that the primary melts of the studied basaltic series of the Chara zone were generated from the mantle protolith within temperatures of 1350–1530°C at depths of 50–95 km. Similar parameters are typical of the generation of the tholeiitic and boninitic island-arc magmas in the modern ocean-continent transition zones of the Pacific type. In general, the study of clinopyroxenes and melt inclusions suggests that the considered complexes of the Chara zone were formed with the participation of tholeiitic and calcalkaline volcanogenic systems of basaltic, basaltic andesite, and, possibly, boninitic composition in the paleogeodynamic setting of evolving ancient island arc.     

Heavy concentrate halos as prospecting guides for PGE mineralization

Platinum-group minerals (PGM) in primary ores and placers are compared in order to substantiate prospecting guides for layered and differentiated intrusions containing sulfide Cu-Ni ores with platinum-group elements (PGE). It is shown that supergene placer mineral assemblages bear information on primary sources and their probable economic value. The mineralogical and geochemical data on the large Siberian intrusions that host Cu-Ni and low-sulfide PGM deposits (Noril’sk 1, Kingash, Chinei, and Yoko-Dovyren) are used to elaborate mineralogical prospecting guides based on the comparative study of PGM assemblages in primary ore, heavy concentrate halos, and hillside sediments. The mechanism of PGM redistribution under supergene conditions is exemplified in the Chinei deposit. The placer mineral assemblage with prevalence of Pt-Fe alloys, atokite-rustenburgite, sperrylite, and multicomponent Pd-Sn-Cu-Pb compounds can be used as a prospecting guide for Noril’sk-type primary PGM ore and related economic placers. The paolovite-sperrylite or sperrylite PGM assemblage in heavy concentrate halos indicates occurrence of Cu-Ni ore in the prospecting area. Sperrylite with isomorphic admixture of Ir and Os typical of the Kingash pluton could be a orospecting guide for Ni-bearing mafic-ultramafic intrusions.     

Age and origin of the Kitoi sillimanite schist deposit,eastern Siberia

Doklady Earth Sciences -