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41.
42.
Methyl-galactosides were oxidized at room temperature by galactose oxidase in a one-step reaction and afforded methyl-galactoaldehyde
in excellent yield and high purity. The resulting galactoaldehyde as a useful intermediate can be directly used in glycopeptide
synthesis. 相似文献
43.
Electron impact excitation rates for transitions in the S v ion, calculated with theR-matrix code, are used to derive the electron temperature sensitive emission line ratiosR
1 =I(854.8 Å)/I(786.9 Å),R
2 =I(852.2 Å)/I(786.9 Å),R
3 =I(849.2 Å)/I(786.9 Å), andR
4 =I(1199.1 Å)/I(786.9 Å), which are found to be significantly different from previous estimates. A comparison of the present results with observational data for a sunspot obtained with the Harvard S-055 spectrometer on boardSkylab reveals generally good agreement between theory and experiment, except in the case ofR
1, which is probably due to blending in the 854.8 Å feature. The possible effects of Lyman continuum absorption on the observed line ratios is briefly discussed. 相似文献
44.
本文通过对1980年以来长江上游10次洪涝过程的500hpa环流形势分析,并用车比雪夫多项式对500hpa高度场进行展开,研究了各类洪涝过程的中期演变特征,发现代表不同洪涝过程环流形势变化的不同的车氏系数值都有明显的特征变化,结合欧洲中心中期数值预告96小时500hpa高度场的车氏系数分析,可为洪涝暴雨的中期预报提供一种新的思路。 相似文献
45.
Baolin Tan Haisheng Ji Guangli Huang Tuanhui Zhou Qiwu Song Yu Huang 《Solar physics》2006,239(1-2):137-148
Using one-minute cadence vector magnetograms from Big Bear Solar Observatory (BBSO), we analyze the temporal behavior of derived
longitudinal electric currents associated with two flares on July 26, 2002. One of the events is an M1.0 flare which occurred
in active region NOAA 10044, while the other is an M8.7 flare in the adjacent region 10039. Rapid changes of magnetic fields
in the form of flux emergence are found to be associated with both of these events. However, the temporal behavior of electric
currents are very different. For the M1.0 flare, the longitudinal electric current density drops rapidly near the flaring
neutral line; while for the M8.7 flare, the current density rapidly increases, confirming the picture of the current-carrying
flux emergence. We offer a possible explanation for such a difference: magnetic reconnection at different heights for the
two events, near the photosphere for the M1.0 flare, and higher up for the M8.7 flare. 相似文献
46.
George Saklatvala Michael P. Hobson Stafford Withington 《Monthly notices of the Royal Astronomical Society》2006,367(3):1194-1200
We describe a procedure for the numerical modelling of astronomical interferometers, with particular relevance to far-infrared and submillimetre wavelengths. The scheme is based on identifying a set of modes that carry power from the sky to the detector. The procedure is extremely general, and can be used to model scalar or vector fields, in any state of coherence and polarization, the only limitation being that the propagation of a coherent field through the system be described by an integral transform, a constraint that is in practise always met.
We present simulations of ideal, multimode two-dimensional interferometers, and show that the modal theory reproduces the correct behaviour of both Michelson and Fizeau interferometers. We calculate simulated visibility data for a multimode bolometric Michelson interferometer, with a synthesized source, and produce a dirty map, recovering the original source with the usual artefacts associated with interferometers. 相似文献
We present simulations of ideal, multimode two-dimensional interferometers, and show that the modal theory reproduces the correct behaviour of both Michelson and Fizeau interferometers. We calculate simulated visibility data for a multimode bolometric Michelson interferometer, with a synthesized source, and produce a dirty map, recovering the original source with the usual artefacts associated with interferometers. 相似文献
47.
We present results from a new simulation code that accounts for the evolution of the reservoirs of carbon dioxide on Mars, from its early years to the present. We establish a baseline model parameter set that produces results compatible with the present (i.e., Patm?6.5 mbar with permanent CO2 ice cap) for a wide range of initial inventories. We find that the initial inventory of CO2 broadly determines the evolutionary course of the reservoirs of CO2. The reservoirs include the atmosphere, ice cap, adsorbed CO2 in the regolith, and carbonate rocks. We track the evolution of the free inventory: the atmosphere, ice cap and regolith. Simulations begin at 4.53 Gyr before present with a rapid loss of free inventory to space in the early Noachian. Models that assume a relatively small initial inventory (?5 bar) have pronounced minima in the free inventory of CO2 toward the end of the Noachian. Under baseline parameters, initial inventories below ∼4.5 bar result in a catastrophic loss of the free inventory to space. The current free inventory would be then determined by the balance between outgassing, sputtering losses and chemical weathering following the end of the late bombardment. We call these “thin” models. They generically predict small current free inventories in line with expectations of a small present CO2 ice cap. For “thick” models, with initial inventories ?5 bar, a surplus of 300-700 mbar of free CO2 remains during the late-Noachian. The histories of free inventory in time for thick models tend to converge within the last 3.5 Gyr toward a present with an ice cap plus atmospheric inventory of about 100 mbar. For thick models, the convergence is largely due to the effects of chemical weathering, which draws down higher free inventories more rapidly than the low. Thus, thick models have ?450 mbar carbonate reservoirs, while thin models have ?200 mbar. Though both thick and thin scenarios can reproduce the current atmospheric pressure, the thick models imply a relatively large current CO2 ice cap and thin models, little or none. While the sublimation of a massive cap at a high obliquity would create a climate swing of greenhouse warming for thick models, under the thin model, mean temperatures and pressures would be essentially unaffected by increases in obliquity. 相似文献
48.
AGGLOMERATION AND RADIATION EFFECT OF THE PULL OF URBANIZATION 总被引:2,自引:1,他引:1
QIJin-li 《中国地理科学(英文版)》2003,13(3):224-227
In order to explore the train of thought for China‘s urbanizing development and coordinated rural eco-nomic development, and to find good ways of solving rural problems through urbanization, this paper absorbs the push-and-pull forces theory and the systematic dynamic theory in the traditional population migration theories, views urbanization as a dynamic system, makes research on the push-and-pull mechanism of urbanization. The pulling power of urbanization is analyzed according to two aspects, the agglomeration effect and the radiation effect of cities. The agglomeration effect provides continuous propelling force for urbanization, and the radiation effect further accelerates the urbanization process by pushing forward the development of rural economy. Of course, the slow de-velopment of urbanization can result in the hindrance to rural economic development. 相似文献
49.
Carlos J.A.P. Martins 《Astrophysics and Space Science》2003,283(4):439-444
I briefly present the Organizing Committee's and my own motivation for organizing this workshop, and I suggest a few key questions
for which we will try to find possible answers in the coming days.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
50.