Clinopyroxenes in the tawhiroko tholeiitic dolerite at Moeraki,north-eastern Otago,New Zealand

Clinopyroxenes from various lithologic units in a single tholeiitic dolerite intrusion 50 m thick were analysed with the electron microprobe. Microphenocrysts of augite in the chilled marginal rock have the least scattered CaMgFe ratios, around Ca₃₈Mg₅₀Fe₁₂, and lowest Ti/Al ratios, less than 1/4, of the augites examined; they crystallized prior to emplacement. The augites which crystallized in situ are more Fe-rich and have higher Ti/Al ratios, close to 1/2. Pigeonite started crystallizing later than augite and formed rims to augite crystals. Continuous zoning from augite to subcalcic augite as was previously reported by Benson (1944) for the same dolerite is not observed. Subcaloic ferroaugites, however, link augite and ferropigeonite in the outermost margins of pyroxenes in the later segregations. The small scale differentiation in situ gave rise to globules, veins, and pegmatoids, in which sector-zoning of augite is well developed. The {100} sectors are enriched in MgSiO₃, FeSiO₃, and MnSiO₃ components relative to the {010} and the {110} sectors, and are accordingly depleted in other components. The protosite theory of sector-zoning formation proposed by Nakamura (1973) is further developed and the environment which favours the development of sector-zoning is discussed. The formation of augite rims around quartz-rich xenoliths and the compositional characteristics of the augites concerned are due to local high silica activities. Comments are made concerning some lunar pyroxenes in the light of the present study.     

Chondrites with peculiar rare-earth patterns

Rare-earth elements and Ba in Khohar, Abee, Indarch, Atlanta, Jajh deh Kot Lalu, and Nakhla were determined accurately by isotope dilution technique; for Atlanta only, Fe (total), Mg and Ca were also determined. Khohar shows in two aliquants a strikingly large, positive anomaly for Ce. A fragment of Abee is outstanding in having a large positive Yb anomaly and a zigzag RE pattern. It is considered that the Yb anomaly is not necessarily associated with the zigzaggedness in question. Anyway, these facts corroborate our previous observations that abundances of Ce and/or Yb could be sometimes anomalous in meteoritic and lunar materials.Atlanta also has a significant negative Eu anomaly, similar to the Eu depletions observed in lunar basalts and Ca-poor achondrites by other workers. Besides, this enstatite chondrite has a RE pattern which indicates that this meteorite is cumulate-type (solid-type) material separated perhaps from a considerably fractionated melt. Accordingly, it is suggested that it is not always appropriate to classify this type II enstatite chondrite as “chondrite”. Two fragments from Abee and Atlanta show different RE patterns. It is also observed that Ba abundances are sometimes sporadically and irregularly high.     

Rapid and frequent turbidite accumulation in the bottom of Izu-Ogasawara Trench: Chemical and radiochemical evidence

Two sediment cores (pilot gravity and piston) were obtained from the bottom of the Izu-Ogasawara Trench at 9750 m and analyzed for various elements and radioisotopes. The results showed a history of complex and frequent turbidite deposition: In the gravity core, eight layers rich in manganese were observed, of which five are enriched in Cu and Co as well. The other three are also enriched in Mo but no other heavy metals, suggesting the presence of at least two mechanisms of formation. Trapping of iron manganese micronodules can account for the enrichment of Mn, Cu and Co. The other three layers rich in Mn and Mo appear to be formed by a post-depositional diagenetic process of Mn mobilization and redeposition in the sediment column. A strong correlation between ²²⁶Ra and Cu in the gravity core suggests that the ²²⁶Ra was also carried into the bottom of the trench in turbidites in association with Mn micronodules. Little excess of ²¹⁰Pb over ²²⁶Ra was found at the top but the excess was significant at mid-depths from 30 to 70 cm, indicating that those sediments were deposited within the last 200 y.

In the piston core there is a sharp discontinuity of chemical and radiochemical composition around a depth of 250 cm. Below that depth the sediments appear to be dominated by materials derived from terrestrial sources, as compared with those in the upper layer which are of contemporary marine origin. ²²⁶Ra is deficient relative to ²³⁰Th throughout the sediment column down to 6 m. This finding is consistent with the finding that the average rate of sediment accumulation is 1–2 orders of magnitude faster than that in the western North Pacific abyssal plain, suggesting the convergence of materials into the bottom of the trench.     

Volcanoes as possible indicators of tectonic stress orientation — Aleutians and Alaska

A new method for obtaining from volcanic surface features the orientations of the principal tectonic stresses is applied to Aleutian and Alaskan volcanoes. The underlying concept for this method is that flank eruptions for polygenetic volcanoes can be regarded as the result of a large-scale natural magmafracturing experiment. The method essentially relies on the recognition of the preferred orientation of radial and parallel dike swarms, primarily using the distribution of monogenetic craters including flank volcanoes. Since dikes tend to propagate in a direction normal to the minimum principal stress (T-axis), the method primarily yields the direction of the maximum horizontal compression (MHC) of regional origin. The direction of the MHC may correspond to either the maximum (P-axis) or intermediate (B-axis) principal stress.The direction of MHC obtained at 20 volcanoes in the Aleutian arc coincides well with the direction of convergence between the Pacific and North American plates. This result provides evidence that in the island arc the inferred direction of MHC is parallel to the maximum principal tectonic stress. In the back-arc region, general E-W trends of MHC are obtained from seven volcanic fields on islands on the Bering Sea shelf and the mainland coast of Alaska. These volcanic fields consist mostly of clusters of monogenetic volcanoes of alkali basalt. In the back-arc region, the trends of MHC may correspond to an E-W intermediate, a vertical maximum, and a N-S minimum principal stress.Implications for the tectonics of island arcs and back-arc regions are: (1) volcanic belts of some island arcs, including the Aleutian arc, are under compressional deviatoric stress in the direction of plate convergence. It is improbable that such arcs would split along the volcanic axis to form actively spreading marginal basins. (2) This compressional stress at the arc, probably generated by underthrusting, appears to be transmitted across the entire arc structure, but is apparently replaced within several hundred kilometers by a stress system characterized by horizontal extension (tensional deviatoric stress) in the back-arc region. (3) The volcanoes associated with these two stress systems differ in type (polygenetic vs. monogenetic) and in the chemistry of their magmas (andesitic vs. basaltic). These differences and the regional differences in orientation of the principal tectonic stresses suggest that the back-arc stress system has its own source at considerable depth beneath the crust.Lamont-Doherty Geological Observatory Contribution No. 2503.     

HFT events: Shallow moonquakes?

A few large distant seismic events of distinctly high signal frequency, designated HFT (high-frequency teleseismic) events, are observed yearly by the Apollo lunar seismic network. Their sources are located on or near the surface of the moon, leaving a large gap in seismic activity between the zones of HFT sources and deep moonquakes. No strong regularities are found in either their spatial or temporal distributions. Several working hypotheses for the identity of these sources have been advanced, but many characteristics of the events seem to favor a hypothesis that they are shallow moonquakes. Simultaneous observations of other lunar phenomena may eventually enable the determination of their true identity.     

Terrestrial heat flow around the aseismic front of the Japanese Island Arc

Very few data on heat flow are available in the area around the aseismic front of the Japanese Islands. In order to remedy this situation, measurements of the terrestrial heat flow were made at three locations in the eastern part of Fukushima Prefecture, northeastern Honshu, Japan. The observed values of heat flow were 37 mW/m² (0.88 μcal/cm²·s) at Soma, 52 mW/m² (1.25 μcal/cm²·s) at Kashima and 19 mW/m² (0.46 μcal/cm²·s) at Naraha, respectively. These data partially fill the gaps in the terrestrial heat flow data on land in northeastern Honshu, Japan. These values are considerably lower than the average heat flow over the world, but agree well with the previous estimation for the area.     

Magnesian andesite and basalt from Shodo-Shima Island,southwest Japan,and their bearing on the genesis of calc-alkaline andesites

Calc-alkaline andesites and olivine tholeiitic basalts are widely distributed on Shodo-Shima island, southwest Japan. The Fo content of olivine phenocrysts in the andesite is higher than in the basalt. The primary magma of the andesite, estimated on the basis of the olivine fractional crystallization model, is not basaltic but andesitic. The basalt contains both chromite and titanomagnetite as inclusions in olivine phenocrysts, while only chromite appears in the andesite. The Cr content of chromite in the andesite is higher than in the basalt. These facts again indicate that the andesite cannot be a fractionation product of the basalt, and that andesitic and basaltic primary magmas were generated independently.     

Determination of REE,Ba, Fe,Mg, Na and K in carbonaceous and ordinary chondrites

Precise determination of REE and Ba abundances in three carbonaceous (Orgueil Cl, Murchison C2 and Allende C3) and seven olivine-bronzite chondrites were carried out by mass spectrometric isotope dilution technique. Replicate analyses of standard rock and the three carbonaceous chondrites demonstrated the high quality of the analyses (accuracies for REE are ±1–2 per cent). Certain carbonaceous chondrite specimens showed small positive irregularities in Yb abundance. The Yb ‘anomaly’ (approximately + 5 per cent relative to the average of 10 ordinary chondrites) in Orgueil may relate to high temperature components. The REE pattern of Guareña (H6) exhibits comparatively extensive fractionation (about factor 2) with a negative anomaly for Eu (17 ± 1 percent) compared to the average H chondrite. This could be interpreted in terms of extensive thermal metamorphism leading to melting.Apart from absolute abundance differences, there appears to be small but recognizable fractionation among the average relative REE abundances of Cl, E, H and L chondrites. However, individual chondrites within these groups showed more or less fractionated REE patterns relative to each other. The distinction between H and L chondrites was well demonstrated in Eu-Sm correlation curves and absolute abundance differences of REE and major elements.Si-normalized atomic ratios of the REE abundances in different kinds of chondrites to those in Orgueil (Cl) chondrite were 0.58 (E), 0.75 (H), 0.81 (L), 1.07 (C2) and 1.32 (C3).     

Evolution of lunar materials in light of the abundance variation of oxyphile trace elements

Based on the lunar data on lanthanides, U, Th, Ba, and Sr, the partition coefficients for fractional solidification were estimated for these elements. The resultant values suggest the removal of solids with perhaps pyroxenic composition. The partition coefficient for europium can be judged to be normal as divalent europium dominantly present in the melt. When we go back following the trend of fractionation of abundances, we can reach the stage where there is no europium anomaly and where the thorium concentration level is chondritic. It can be imagined that the material corresponding to this stage was the directly original lunar material system. As a possibility, a zone melting is thought to be a possible process for the derivation of that material from chondritic material. The chondrite-normalized lanthanide patterns for silicate materials of two stony-irons appear to provide us with an intriguing clue to this problem.     

High precision slip distribution of the 1944 Tonankai earthquake inferred from tsunami waveforms: Possible slip on a splay fault

Inversion of tsunami waveforms is a well-established technique for estimating the slip distributions of subduction zone earthquakes, with some of the most detailed results having been obtained for earthquakes in the Nankai Trough, SW Japan. The present study, although it uses a method and tsunami waveform data set almost identical to previous study, aims to improve on previous work by using a more precise specification of initial conditions for the calculation of tsunami Green's functions. Specifically, we incorporated four improvements in the present study: (1) we used a realistic plate model based only on seismic survey results, and assumed it to be the fault plane of the 1944 Tonankai earthquake; (2) the smallest subfaults consistent with the long wavelength approximation were used in the tsunami inversion analysis; (3) we included the effect of horizontal displacement of the ocean bottom on tsunami generation; and (4) we performed a checkerboard resolution test. As obtained in previous studies, a zone of high slip (> 2.0 m) was resolved off the Shima Peninsula. However, the more precise calculation of tsunami Green's functions has revealed additional detail that was not evident in previous studies, which we demonstrate is resolvable and correlates with the position of known faults in the accretionary prism. While there was little or no slip near the trench axis in the eastern part of the rupture zone, there was up to 1.5 m of slip resolved within 30 km of the trough axis in the western part, along the coast of the Kii Peninsula. This troughward slip zone coincides with the position of a large splay fault mapped in multichannel reflection surveys. Furthermore, it is also clear that the upper edge of the Enshu fault off Shima and Atsumi peninsulas is consistent with the up-dip limit of slip in the eastern part of our model. We tested the possibility that slip occurred on the former splay fault instead of on the plate interface during the 1944 Tonankai earthquake, and find that slip on this splay fault is also consistent with the data, although we cannot distinguish whether slip was dominant on the splay fault or on the plate interface. We further suggest that the position of the Enshu fault may be determined by the subduction of topographic highs, and that such faults may have an important influence on the up-dip rupture limit of the 1944 Tonankai and, potentially, other subduction zone earthquakes.