Lagrangian observation of phytoplankton dynamics at an artificially enriched subsurface water in Sagami Bay,Japan

Phytoplankton dynamics in the lower euphotic zone were observed by tracking a subsurface water released at 20-m depth from Takumi, an artificial upwelling device. Takumi continually discharged seawater pumped up from a depth of 205 m: this water was mixed with 5-m depth water to adjust the density to that of 20-m depth water of Sagami Bay, Japan. The discharged water was pulse-labeled at Takumi with uranine and tracked for 63.9 h with a drifting buoy equipped with a drogue at 20-m depth. We present a simple model to estimate in situ phytoplankton net growth rates from temporal changes in phytoplankton abundance in the discharged water with correction for the influence of water exchange between the discharged water and neighboring layers. Lagrangian observation showed active growth of pico- and nanophytoplankton, especially cryptophytes and Synechococcus (Cyanobacteria), in the subsurface layer. In contrast, diatoms grew little in spite of micromolar concentrations of nutrients. The active growth of pico- and nanophytoplankton was in good agreement with shipboard serial dilution culture experiments. The low growth activity of diatoms was suggested to be related to low light availability in the subsurface layer.     

Basalts and serpentinite from the Puerto Rico Trench, 2. Rare-earth geochemistry

Seven tholeiitic basalts from the Puerto Rico Trench walls (three from the south wall and four from the north wall) were investigated for rare-earth abundances. All these rocks, with the exception of a pigeonite-bearing rock (RC8-RD1–12), were found to possess similar rare-earth features. Their rare-earth patterns resembled those of usual abyssal basalts, and showed no Eu anomalies. There is no difference between the rare-earth abundances of fine-grained and coarse-grained rocks. It is clear that the pigeonite-bearing rock (RC8-RD1 type 2) differs in origin from the abyssal basalts. The rocks with rare-earth patterns similar to that of RC8-RD1–12 are found among the Japanes “geosynclinal” basalts (Tanaka and Sugisaki, 1973).A serpentinite from the same trench was also analyzed for the same elements. The resultant rare-earth pattern suggests that the relevant original rock was separated from a magma having the same relative rare-earth abundances as a chondritic meteorite. The markedly high Eu positive anomaly of this serpentinite is also discussed.     

CaPtO3 as a novel post-perovskite oxide

Structural, morphological, magnetic, and thermal properties have been investigated for a novel post-perovskite oxide CaPtO₃ synthesized under high pressure. By comparing obtained structural parameters with those for known post-perovskite compounds, we argue that the chemical bond has a strong covalent character. Precise measurements of the Langevin susceptibility χ ₀ = −9.6 × 10⁻⁵ emu/mol and Debye temperature θ ∼ 470 K provide a good opportunity to confirm the reliability of first-principle calculations on predicting physical properties of the Earth’s D” layer.     

Selective detection of Fe and Mn species at mineral surfaces in weathered granite by conversion electron yield X-ray absorption fine structure

A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO₂ and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm²) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.     

Arsenic release from biotite into a Holocene groundwater aquifer in Bangladesh

Continuous core sediments (to a depth of 90.1 m) taken at a transitional area of Holocene and Pleistocene deposits in Sonargaon, Bangladesh were characterized for their mineralogy and chemistry. Among the sediments of the lower part of the Holocene aquifer (depth: 18–29 m), where most domestic wells are installed, As is mostly fixed in biotite and organic phases. A positive correlation of As concentration with those of Al and Fe but not that of total organic C clearly suggests that biotite is a primary source of As. Although microbial reduction–dissolution of As-containing Fe oxyhydroxides is thought to cause As-enriched groundwater in the Ganges–Brahmaputra–Meghna delta plain, the authors conclude that chemical weathering of biotite is the primary formation mechanism and prevailing reducing conditions contribute to the expansion of As-enriched groundwater in the study area.     

A possible role for unstable coupled waves affected by resonance between Kelvin waves and seasonal warming in the development of the strong 1997–1998 El Niño

Time-varying air–sea coupled processes in the central to eastern equatorial Pacific associated with strong El Niño development during the 1997–1998 period are examined using a newly developed reanalysis dataset obtained from four-dimensional variational ocean–atmosphere coupled data assimilation experiments. The time series of this data field exhibits realistic features of El Niño evolution. Our analysis indicates that resonance between eastward-propagating oceanic downwelling Kelvin waves and the seasonal rise of sea-surface temperature (SST) in the central to eastern equatorial Pacific generates relatively persistent high SST conditions accompanied by a deeper thermocline and more relaxed easterly winds than usual. The surface condition resulting from the wave-seasonal SST resonance represents a preconditioned state that leads to an enhancement in incident downwelling Kelvin waves to levels sufficient to induce large-amplitude unstable coupled waves in the central to eastern equatorial region. Heat balance estimates using our reanalysis dataset suggest that the unstable coupled waves are categorized within the intermediate regime of coupled Kelvin and Rossby waves and have the potential to grow rapidly. We argue that the seasonal resonance and the unstable coupled waves should play crucial roles in the development of the largest historical El Niño event, which was recorded between late 1997 and early 1998.     

Rotation of the elastic Earth: the role of the angular-velocity-dependence of the elasticity-caused perturbation

We calculate the so-called convective term, which shows up in the expression for the angular velocity of the elastic Earth, within the Andoyer formalism. The term emerges due to the fact that the elasticity-caused perturbation depends not only on the instantaneous orientation of the Earth but also on its instantaneous angular velocity. We demonstrate that this term makes a considerable contribution into the overall angular velocity. At the same time the convective term turns out to be automatically included into the correction to the nutation series due to the elasticity, if the series is defined by the perturbation of the figure axis (and not of the rotational axis) in accordance with the current IAU resolution. Hence it is not necessary to take the effect of the convective term into consideration in the perturbation of the elastic Earth as far as the nutation is related to the motion of the figure axis.     

Formation Mechanism of Soft X-Ray Transient Trans-Equatorial Loop System

The Soft X-ray Telescope (SXT) onboard Yohkoh often observed large-scale coronal loops connecting two active regions situated in opposite hemispheres. These are the trans-equatorial loop systems (TLSs). The formation mechanism of TLSs is not yet known. We analyzed a TLS observed simultaneously with Yohkoh/SXT and a coronagraph (SOHO/LASCO-C1). SOHO/LASCO-C1 observed loop expansion and eruption at the west solar limb. Yohkoh/SXT observed a rising motion (chromospheric evaporation) of hot and dense plasmas from the active regions located at the footpoints of the loop. Important results of our analyses are that (1) the loop eruption and the rising motion of the plasmas were simultaneous, (2) the TLS had a cusp-like appearance, and (3) the highest temperature region of the TLS was located above the bright loop seen in soft X rays. These observational results (loop expansion, eruption, and chromospheric evaporation) suggest that this bright (high-density) TLS was created by the same mechanism by which a solar flare occurs, namely, magnetic reconnection. In this paper, we propose a formation mechanism of the TLS that forms between two independent active regions.     

The first confirmed Perseid lunar impact flash

The first confirmed lunar impact flash due to a non-Leonid meteoroid is reported. The observed Perseid meteoroid impact occurred at 18^h28^m27^s on August 11, 2004 (UT). The selenographic coordinates of the lunar impact flash are 48±1° N and 72±2° E, and the flash had a visual magnitude of ca. 9.5 with duration of about 1/30 s. The mass of the impactor is estimated to have been 12 g based on a nominal model with conversion efficiency from kinetic to optical energy of 2×¹⁰⁻³. Extrapolation of a power law size-frequency distribution fitting the sub-centimeter Perseid meteoric particles to large meteoroids suggests that several flashes should have been observed at this optical efficiency. The detection of only one flash may indicate that the optical efficiency for Perseid lunar impact is much lower, or that the slope of the size distribution differs between large meteoroids and typical sub-centimeter meteoric particles.     

A possible Caledonide arm through the Barents Sea imaged by OBS data

The assembly of the crystalline basement of the western Barents Sea is related to the Caledonian orogeny during the Silurian. However, the development southeast of Svalbard is not well understood, as conventional seismic reflection data does not provide reliable mapping below the Permian sequence. A wide-angle seismic survey from 1998, conducted with ocean bottom seismometers in the northwestern Barents Sea, provides data that enables the identification and mapping of the depths to crystalline basement and Moho by ray tracing and inversion. The four profiles modeled show pre-Permian basins and highs with a configuration distinct from later Mesozoic structural elements. Several strong reflections from within the crystalline crust indicate an inhomogeneous basement terrain. Refractions from the top of the basement together with reflections from the Moho constrain the basement velocity to increase from 6.3 km s⁻¹ at the top to 6.6 km s⁻¹ at the base of the crust. On two profiles, the Moho deepens locally into root structures, which are associated with high top mantle velocities of 8.5 km s⁻¹. Combined P- and S-wave data indicate a mixed sand/clay/carbonate lithology for the sedimentary section, and a predominantly felsic to intermediate crystalline crust. In general, the top basement and Moho surfaces exhibit poor correlation with the observed gravity field, and the gravity models required high-density bodies in the basement and upper mantle to account for the positive gravity anomalies in the area. Comparisons with the Ural suture zone suggest that the Barents Sea data may be interpreted in terms of a proto-Caledonian subduction zone dipping to the southeast, with a crustal root representing remnant of the continental collision, and high mantle velocities and densities representing eclogitized oceanic crust. High-density bodies within the crystalline crust may be accreted island arc or oceanic terrain. The mapped trend of the suture resembles a previously published model of the Caledonian orogeny. This model postulates a separate branch extending into central parts of the Barents Sea coupled with the northerly trending Svalbard Caledonides, and a microcontinent consisting of Svalbard and northern parts of the Barents Sea independent of Laurentia and Baltica at the time. Later, compressional faulting within the suture zone apparently formed the Sentralbanken High.