Monitoring of organic pollutants in coastal waters of the Gulf of Gdańsk, Southern Baltic

This paper presents an overview of changes in organic pollution of coastal waters of the Gulf of Gdańsk (Baltic Sea). Toxic pollutants including volatile organic compounds (VOC), volatile organohalogen compounds (VOX), chlorophenols, phenoxyacids, polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) were determined in seawater from the Gulf of Gdańsk coastal waters in the period 1996-2001. In the case of the Gulf of Gdańsk, non-conservative behaviour of VOC was observed due to random temporal and spatial of inputs along the Vistula estuary and to the dilution of VOC-enriched river water with seawater. The concentrations of VOX in seawater decreased throughout the period and the concentrations of VOX were in the range of few ng dm(-3) up to 250 ng dm(-3), similar to estuaries elsewhere. The average concentrations of chlorophenols and phenoxyacids were between 0.1 and 6.0 and 0.05 and 2.2 microg dm(-3), respectively. However, remarkably high concentrations of 2,4-dichlorophenol (6 microg dm(-3)) were obtained in samples collected from the Vistula River. Generally concentrations of PCBs did not exceed few ng dm(-3) with the exception of 1999, when all samples exhibited elevated concentrations of PCBs. In addition, higher concentrations of PCBs in the open sea compared to river waters suggested localised inputs. Due to the ability of most organic pollutants to bioaccumulate and biomagnify, especially the persistent organic pollutants, continued monitoring is of crucial importance for the health of marine life in the Gulf of Gdańsk.     

Searching for novel CYP members using cDNA library from a minke whale liver

The contaminant-induced cytochrome P450 (CYP) members in minke whale (Balaenoptera acutorostrata) can be potential biomarkers of the contaminant exposure and toxic effects. In this study, we constructed a cDNA library from the liver of minke whale from the North Pacific, and further screened a total of 6930 clones randomly selected in the library for the isolation of cDNA clones encoding novel members of CYP superfamily. The screening revealed the isolation of six novel CYP cDNA clones that are classified into CYP1A, CYP2C, CYP2E, CYP3A, CYP4, and CYP4A subfamilies. The BLAST homology search using the partial cDNA fragments of four CYP subfamilies (CYP1A, CYP2C, CYP2E and CYP4A) demonstrated that the minke whale CYPs were most closely related to pig CYPs (81-91%). Identification of multiple CYP genes in marine mammal species such as minke whale will provide new insights into the metabolic or toxicological functions of individual CYP members.     

Water exchange in Kabira Cove,Ishigaki Island

The mechanism and rate of water exchange were investigated in Kabira Cove, Ishigaki Island, in the southernmost part of Japanese islands, near Taiwan. During observations in the summers of 1976 and 1977, a larger proportion of the salt transport into the bay was derived from the so-called “tidal trapping effect”. In the latter period of observation carried out after heavy rain brought by a seasonal typhoon under annual mean tidal conditions, the turnover time, i.e. the scale of replacement of the whole bay water with the open sea water, is estimated to be 3.6 days. Based on these observational results, a concept of the tidal trapping due to coupling of the actions of tides and buoyancy in a vertical two-dimensional field with a sill at the bay mouth is proposed. Considering the topographical, hydrometeorological and geographical conditions of the cove, it is inferred that this water exchange process tends to be formed in Kabira Cove in summer except during neap tides.     

Year-to-year change in water exchange characteristics in a semi-enclosed bya,Lake Hamana

The year-to-year change in characteristics of water exchange between Lake Hamana, a semi-enclosed bya, and the adjacent open sea is investigated.The destruction of the bay mouth by a typhoon in 1953 and subsequent stabilization work on the bay mouth from 1954 to 1973 resulted in an increase in the tidal prism volume of the bay (Mazda, 1983). In the present paper, a simple model has been constructed in which the magnitude of water exchange depends on the tidal prism, and using this model, the year-to-year increase in salinity of the bay water after 1953 can be well explained. Consequently, it can be said that the salinity increase after 1953 is a result of a progressive increase in water exchange caused by successive changes in topography of the bay mouth.The extent of water exchange in Lake Hamana, which varies seasonally, has increased gradually since 1953, and became stable after about 1967. For instance, at present the turnover time of the bay for exchange with open sea water reaches a maximum (2.9 months) in January and a minimum (0.9 month) in October, while in 1955 it is estimated to have been about 2.5 times that at the present time.     

Vertical two-dimensional mechanism of tidal exchange in a bay with a sill-entrance

For a vertical two-dimensional field with a sill at a bay entrance, the tidal exchange mechanism is discussed.The schematic model is proposed as follows. The tidal trapping effect which is detected at the entrance section,i. e., the material transport due to the phase difference between the tidal periodic constituent of material concentration and tidal current at the entrance section, results because the oscillatory tidal flow at the sill entrance induces a gravitational flow along the sill slope inside the entrance. Accordingly, the tidal trapping effect depends largely upon the difference in water density between the bay and open sea and the density stratification in the bay.This model is supported by the observations at Kabira Cove (Okinawa Pref.) and Lake Hamana (Shizuoka Pref.) in 1976 through 1984. In addition, based on this model, in the case of Lake Hamana, the activity of the tidal exchange is inferred to change seasonally.     

Comparative study of radiation-induced damage in magnesium aluminate spinel by means of IL,CL and RBS/C techniques

A comparative study of damage accumulation in magnesium aluminate spinel (MgAl₂O₄) has been conducted using ionoluminescence (IL), cathodoluminescence (CL) and Rutherford Backscattering Spectrometry/channeling (RBS/C) techniques. MgAl₂O₄ single crystal and polycrystalline samples were irradiated with 320 keV Ar⁺ ions at fluencies ranging from 1 × 10¹² to 2 × 10¹⁶ cm^?2 in order to create various levels of radiation damage. RBS/C measurements provided quantitative data about damage concentration in the samples. These values were then compared to the luminescence measurements. The results obtained by IL and RBS/C methods demonstrate a two-step character of damage buildup process. The CL data analysis points to the three-step damage accumulation mechanism involving the first defect transformation at fluencies of about 10¹³ cm^?2 and second at about 10¹⁵ cm^?2. The rate of changes resulting from the formation of nonluminescent recombination centers is clearly nonlinear and cannot be described in terms of continuous accumulation of point defects. Both, IL and CL techniques, appear as new, complementary tools bringing new possibilities in the damage accumulation studies in single- and polycrystalline materials.     

Evidence of positive tectonic inversion in the north-central sector of the Sicily Channel (Central Mediterranean)

In order to unravel the tectonic evolution of the north-central sector of the Sicily Channel (Central Mediterranean), a seismo-stratigraphic analysis of single- and multi-channel seismic reflection profiles has been carried out. This allowed to identify, between 20 and 50 km offshore the central-southern coast of Sicily, a ~80-km-long deformation belt, characterized by a set of WNW–ESE to NW–SE fault segments showing a poly-phasic activity. Within this belt, we observed: i) Miocene normal faults reactivated during Zanclean–Piacenzian time by dextral strike-slip motion, as a consequence of the Africa–Europe convergence; ii) releasing and restraining bend geometries forming well-developed pull-apart basins and compressive structures. In the central and western sectors of the belt, we identified local transpressional reactivations of Piacenzian time, attested by well-defined compressive features like push-up structures and fault-bend anticlines. The reconstruction of timing and style of tectonic deformation suggest a strike-slip reactivation of inherited normal faults and the local subsequent positive tectonic inversion, often documented along oblique thrust ramps. This pattern represents a key for an improved knowledge of the structural style of foreland fold-and-thrust belts propagating in a preexisting extensional domain. With regard to active tectonics and seismic hazards, recent GPS data and local seismicity events suggest that this deformation process could be still active and accomplished through deep-buried structures; moreover, several normal faults showing moderate displacements have been identified on top of the Madrepore Bank and Malta High, offsetting the Late Quaternary deposits. Finally, inside the northern part of the Gela Basin, multiple slope failures, originated during Pleistocene by the further advancing of the Gela Nappe, reveal tectonically induced potential instability processes.

     

Episyenite formation in the Toki granite,central Japan

Episyenite is a quartz-depleted vuggy rock resulting from hydrothermal alteration of granitic rocks. This is the first report of its existence in an island arc, which is identified in a deep drill core of the Toki Cretaceous granite distributed in central Japan. In order to understand the petrographical features of the episyenite, neutron porosity measurement, geochemical analysis, microscopic observation, and X-ray computed tomography scanning were carried out. The results show remarkably high porosity (35.4 %) due to interconnecting vugs and the removal of quartz, plagioclase, and biotite. The Rb–Sr isotopic results and the paragenetic sequence of secondary minerals in the vugs suggest that the hydrothermal alteration process can be divided into an episyenitization stage and a later hydrothermal stage. At the episyenitization stage (70.6 ± 3.1 Ma) ca. 6 million years after the emplacement of the unaltered granite (76.3 ± 1.5 Ma), dissolution of quartz, biotite, and plagioclase occurred and was followed by the precipitation of albite, vermicular chlorite, and platy calcite. The episyenitization is considered as a local alteration of the Toki granite in an isotopically closed system. At the later hydrothermal stage, illite and secondary quartz precipitated from circulating meteoric-derived water in the dissolution vugs. Superimposing alteration at the later hydrothermal stage is limited, which results in the preservation of the episyenite in an almost primitive condition.     

Biogenic opal production changes during the Mid-Pleistocene Transition in the Bering Sea (IODP Expedition 323 Site U1343)

Biogenic opal content and mass accumulation rate (MAR) at IODP Expedition 323 Site U1343 were found to fluctuate consistently, generally being high under warm conditions and low under cold conditions during the last 2.4 Ma. Continuous wavelet transform analysis of the normalized biogenic opal content indicates that export production in the Bering Sea varied predominantly at 41-ka periodicity before 1.25 Ma, and shifted to 100-ka periodicity at the onset of the Mid-Pleistocene Transition (MPT; 1.25–0.7 Ma). The 100-ka cycles dominated until the Holocene. Export production in the Bering Sea decreased markedly in the Bering Sea two times during the MPT: the first occurred at the beginning of the MPT (1.25 Ma) and the second in the middle of the MPT (0.9 Ma). These decreases coincided with both increases in the relative abundance of sea-ice diatoms and decreases in the warm-water diatom species Neodenticula seminae, indicating that reductions in export production in the Bering Sea during the MPT were associated with climate cooling. Decreases in export production in the Bering Sea during the MPT were most likely associated with the increased influence of polar/Arctic domains on the high-latitude North Pacific.     

Testing a model of variability of X-ray reprocessing features in active galactic nuclei

A number of recent results from X-ray observations of active galactic nuclei involving the Fe K α line (reduction of line variability compared with the X-ray continuum variability, the X-ray 'Baldwin effect') were attributed to the presence of a hot, ionized skin of an accretion disc, suppressing emission of the line. The ionized skin appears as a result of the thermal instability of X-ray irradiated plasma. We test this hypothesis by computing the Thomson thickness of the hot skin on top of the αP _tot Shakura–Sunyaev disc, by simultaneously solving the vertical structure of both the hot skin and the disc. We then compute a number of relations between observable quantities, e.g. the hard X-ray flux, amplitude of the observed reprocessed component, relativistic smearing of the K α line and rms variability of the hard X-rays. These relations can be compared with present and future observations. We point out that this mechanism is unlikely to explain the behaviour of the X-ray source in MCG–6-30-15, where there are a number of arguments against the existence of a thick hot skin, but it can work for some other Seyfert 1 galaxies.