Alleviating drought and water scarcity in the Mediterranean region through managed aquifer recharge

Drought and water scarcity can significantly impair the sustainable development of groundwater resources, a scenario commonly found in aquifers in the Mediterranean region. Water management measures to address these drivers of groundwater depletion are highly relevant, especially considering the increasing severity of droughts under climate change. This study evaluates the potential of managed aquifer recharge (MAR) to offset the adverse effects of drought and water scarcity on groundwater storage. Los Arenales aquifer (central Spain), which was unsustainably exploited for irrigation in the second half of the twentieth century, is employed as a case study. Two neighbouring zones within this aquifer are contrasted, namely, Los Arenales (LA) and Medina del Campo (MC). The primary difference between them in terms of water resources management is the wide-scale implementation of MAR systems in LA since the early 2000s. Several groundwater statistical methods are used. Groundwater-level trend analysis and average piezometric levels show in LA a faster recovery of aquifer storage and less susceptibility to drought compared to MC. On the other hand, standardised precipitation indexes and standardised groundwater level indexes of detrended groundwater-level time series, which do not include the effects of MAR, show that LA can be more negatively affected by drought and groundwater abstraction. The sharper recovery of piezometric levels in LA when considering MAR, and bigger drought impacts observed when the effects of this measure are removed, demonstrate that MAR can effectively alleviate the impacts of water scarcity and drought, providing an adaptation solution to climate change worldwide.

     

On The Origin of The High-Perihelion Scattered Disk: The Role of The Kozai Mechanism And Mean Motion Resonances

We study the transfer process from the scattered disk (SD) to the high-perihelion scattered disk (HPSD) (defined as the population with perihelion distances q > 40 AU and semimajor axes a>50 AU) by means of two different models. One model (Model 1) assumes that SD objects (SDOs) were formed closer to the Sun and driven outwards by resonant coupling with the accreting Neptune during the stage of outward migration (Gomes 2003b, Earth, Moon, Planets 92, 29–42.). The other model (Model 2) considers the observed population of SDOs plus clones that try to compensate for observational discovery bias (Fernández et al. 2004, Icarus , in press). We find that the Kozai mechanism (coupling between the argument of perihelion, eccentricity, and inclination), associated with a mean motion resonance (MMR), is the main responsible for raising both the perihelion distance and the inclination of SDOs. The highest perihelion distance for a body of our samples was found to be q = 69.2 AU. This shows that bodies can be temporarily detached from the planetary region by dynamical interactions with the planets. This phenomenon is temporary since the same coupling of Kozai with a MMR will at some point bring the bodies back to states of lower-q values. However, the dynamical time scale in high-q states may be very long, up to several Gyr. For Model 1, about 10% of the bodies driven away by Neptune get trapped into the HPSD when the resonant coupling Kozai-MMR is disrupted by Neptune’s migration. Therefore, Model 1 also supplies a fossil HPSD, whose bodies remain in non-resonant orbits and thus stable for the age of the solar system, in addition to the HPSD formed by temporary captures of SDOs after the giant planets reached their current orbits. We find that about 12 – 15% of the surviving bodies of our samples are incorporated into the HPSD after about 4 – 5 Gyr, and that a large fraction of the captures occur for up to the 1:8 MMR (a ⋍ 120 AU), although we record captures up to the 1:24 MMR (a ≃ 260 AU). Because of the Kozai mechanism, HPSD objects have on average inclinations about 25°–50°, which are higher than those of the classical Edgeworth–Kuiper (EK) belt or the SD. Our results suggest that Sedna belongs to a dynamically distinct population from the HPSD, possibly being a member of the inner core of the Oort cloud. As regards to 2000 CR₁₀₅ , it is marginally within the region occupied by HPSD objects in the parametric planes (q,a) and (a,i), so it is not ruled out that it might be a member of the HPSD, though it might as well belong to the inner core.     

Transversal ejection-collision orbits in Hill's problem forC≫1

In a recent paper [3], Lacomba and Llibre showed numerically the existence of two transversal ejection-collision orbits in Hill's problem for a valueC=5 of the Jacobian constant. This result can be used to prove the non-existence ofC ¹-extendable regular integrals for Hill's problem. Here we give an analytic proof of the existence of four ejection-collision orbits which are transversal for large enough values ofC.     

Light curves of the eclipsing systems of RS CVn-type

This work presents the light curves for rotating spotted stars generated by a computational code developed by us. This code is based in a model of the system and its analytical solution. The work also present an analysis of the photometric curve variations with the changes in the model's parameters.As a first result we have simulated a temporal evolution of the light curve when the photospheric spot varies its size and position and we reproduced some observational light curves of the II Peg star.Work supported by Dirección de Investigación, Universidad de La Serena, Chile.     

Sr-rich minerals in a carbonatite skarn, Fuerteventura, Canary Islands (Spain)

Summary Metamorphosed carbonatites and related skarn deposits, located in Fuerteventura Basal Complex, contain unusual Sr-rich minerals. Maximum SrO concentration in the following minerals are: calcite, 7.23wt%; apatite, 5.22wt%; epidote, 11.64wt%; clinozoisite, 1.25wt%; allanite, 5.63wt%; britholite, 4.11wt% and a Sr–Na aluminosilicate (probably stronalsite), 16.44wt% SrO. Calcite and apatite are chemically similar to those found in carbonatites and are therefore considered to be of igneous origin. Textural evidence indicates that the first skarn stage garnet+diopside+Sr–Na aluminosilicate formed as the result of chemical interaction between carbonatites and adjacent silicate rocks. The formation of Sr-bearing epidote/clinozoisite, allanite and britholite appears to be related to the release of Sr into the fluid phase from the breakdown of high temperature assemblages during the retrograde skarn stage. During the final evolution stages, further alteration of britholite by bastnäsite and törnebohmite took place. The occurrence of REE minerals shows that the fluids responsible for this metasomatism must also have transported significant quantities of REE.     

Application of lead stable isotopes to the Guadiamar Aquifer study after the mine tailings spill in Aznalcóllar (SW Spain)

On 25 April 1998 the tailings dam of the Aznalcóllar mine burst, a great quantity of pyrite waste sludge and acid water was spilled reaching the vicinity of the Doñana National Park. In surface and ground water samples taken a week after dam breaking, metals, trace elements and Pb isotopic ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) were analysed. In September 1998 a second sampling survey was carried out. The surface waters have a similar isotopic composition as the lead contained in the pyrite from the Aznalcóllar mine. The polluted groundwater of the Guadiamar aquifer also shows the influence of the mining origin of the lead. Lead isotope ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) in the groundwater of the Almonte-Marismas are very low and they differ clearly from the rest of groundwater samples. A further group of wells has a lead isotope composition intermediate between the Aznalcóllar mine and the atmospheric aerosols of the Iberian Peninsula.     

Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm³ molecule⁻¹ s⁻¹). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO₃, O₃ and Cl have been calculated.