9000 years of changes in peat organic matter composition in Store Mosse (Sweden) traced using FTIR-ATR

Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km²), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm^–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.     

A Road to Conflict: Stakeholder’s and Social Network Analysis of the Media Portrayals of a Social-Environmental Conflict in Bolivia

Society’s understanding of a conflict is mediated by information provided in mass media, for which researchers stress the importance of analyzing media portrays of stakeholders in a conflict. We analyze information from the Bolivian press regarding the construction of a road crossing the Isiboro-Sécure Indigenous Territory and National Park (TIPNIS). Using stakeholder’s and social network analyses, we explore stakeholder’s positions and alliances as represented in the media and contrast it with previous scholarly work. We found that some actors cited as central in scholar analyses of the conflict are largely absent in the media (e.g., private investors, conservationist sector) and that the media tend to present stakeholders as having more homogeneous positions than the academic literature does while also neglecting some important alliances in their account. The media also suggests that Indigenous communities are forging stronger alliances with urban sectors and civil society, alliances not stressed by researchers.     

CPLat: first operational experimental processing center for SIRGAS in Argentina

The SIRGAS permanent GPS network which is in fact the IGS network densification for the American continent, consists today of more than 200 stations covering the continent and islands. It is currently processed by the IGS RNAAC SIR centre at Deutsches Geodätisches Forschungsinstitut producing weekly free solutions relying on IGS final orbits and EOP that contribute to the ITRF through IGS. By August 2006, the SIRGAS Working Group I had accepted five proposals for experimental processing centers within the region that would collaborate with IGS RNAAC SIR. One of them, Centro de Procesamiento La Plata (CPLat) in Argentina, began processing 60 stations on October 2006. By January 2007 CPLat reached operational capability, delivering weekly free solution SINEX files, with an internal consistency of 1.5 mm average for the horizontal components, and 3 mm in the vertical. Comparisons with IGS global and IGS RNAAC SIR weekly solutions were taken as external consistency indications, showing average RMS residuals of 1.8, 2.4 and 5 mm for the north, east, and vertical component, respectively. Analysis and comparison of adjusted solution time series from CPLat and other processing centers has proved to be highly valuable for solution QC, namely detection and identification of station anomalous behavior or modelling problems. These procedures will ensure the maintenance of the performance specifications for CPLat solutions. Action is being taken in order to guarantee the continuity of this effort beyond the experimental phase.     

Sediment resuspension events induced by the wake wash of deep-draft vessels

Hydrodynamics and sediment resuspension events, induced at the shoreline by a deep-draft vessel passing nearby, are described. Measurements (pressure, currents and turbidity) were obtained at 4 Hz, on a lower beach ~50 m from a channel where large car ferries operate in Wootton Creek, Isle of Wight. The study focuses on a representative 8-min 32-s-long record, during which two large vessels passed the channel section. At the shore, the passage of each vessel induced a long-period water-level drawdown, followed by a water-level oscillation (seiche) of similar period, and the short-period waves of the wake. Both drawdowns were the main constituents of the prevailing wave pattern. The second drawdown was the largest in amplitude, in response to a higher speed of the ferry, and the influence of the seiche which had been activated during the preceding event. Two successive peaks of turbidity were observed shortly after this drawdown. Analyses of current velocity and direction indicate that the sediments resuspended originated from the shallower upper beach. Anthropogenically induced erosion of the foreshore is predicted at Wootton Creek.     

Assessment of seismic hazard for the Sannio-Matese area of Southern Italy — A summary

The working group on Test Regions for Evaluation of Methods for Seismic Hazard Assessment in Europe (TERESA), consisted of 15 members from 10 different European countries. Methods and experience gathered in these countries have been compared and discussed for two test areas in Europe: the Sannio-Matese region, Southern Italy, with high seismic activity, and the border region between Belgium, The Netherlands, and Federal Republic of Germany, with low activity.This paper summarizes the results for one of the test areas, Sannio-Matese. Most of the participants used statistical procedures to assess earthquake hazard, receiving results in terms of probability of occurrence for intensity as the ground-motion parameter. It was found that careful preparation of input data and parameters is the major influencing factor, therefore most of the efforts of the working group was devoted to this task.The scatter of the obtained results of the group is considerable, mainly because of the uncertainties in the data and the subjectiveness involved in the procedures. For better control of both factors, more objective methods have to be developed.     

Catalonian precipitation patterns: Principal component analysis and automated regionalization

Summary A principal component analysis (PCA) based on a network including 179 pluviometric gauges is attempted in order to describe the main patterns governing precipitation in Catalonia (NE Spain). This PCA procedure is applied to the interstation covariance matrix and component loadings are then deduced from it and extensively interpreted. PCA results are used immediately after in a Davis and Kalkstein clustering process, leading to a rainfall division. The homogeneity of the different groups obtained is tested by means of the analysis of their spatial and temporal within-group variances.With 8 Figures     

Factors affecting arsenic concentration in groundwaters from Northwestern Chaco-Pampean Plain,Argentina

The concentration of arsenic measured in groundwater from three aquifers in the study area located in the Eastern Tucuman province, Argentina, mostly depends on the lithology, but the spatial and temporal variations of concentrations seem to be also controlled by pH changes, climatic factors, and human perturbations. The highest concentrations of As (more than 1,000 μg L⁻¹) were found in the shallow aquifer, made of As-rich loess, while the lowest concentrations were measured in the deep confined aquifer, consisting of alternating layers of alluvial sands/gravels and clays. Intermediate values were measured in the semiconfined aquifer made of the fluvial sediments deposited in the Salí River valley, that alternate in the upper part of the sedimentary sequence with layers of loess. Because most of As in the loess is considered to be adsorbed onto Fe-oxyhydroxide coatings, the increase of pH in the flow direction (west-east) leads to increasing arsenic concentrations towards the eastern border of the study area. The decomposition of organic wastes poured into the Salí River or associated with local and diffuse sources of contamination in the eastern part of the study area depletes dissolved oxygen, which leads to the reductive dissolution of Fe and Mn oxyhydroxides, and to the subsequent release of the adsorbed and co-precipitated As. This process mainly affects shallow groundwater and the upper part of the semiconfined aquifer. Geochemical and hydrological data also suggest that rising water table levels at the end of the wet season may also lead to reductive dissolution of As-rich Fe oxyhydroxides in the shallow aquifer.     

Some Insights into Topographic,Elastic and Self-gravitation Interaction in Modelling Ground Deformation and Gravity Changes in Active Volcanic Areas

Surface displacements and gravity changes due to volcanic sources are influenced by medium properties. We investigate topographic, elastic and self-gravitation interaction in order to outline the major factors that are significant in data modelling. While elastic-gravitational models can provide a suitable approximation to problems of volcanic loading in areas where topographic relief is negligible, for prominent volcanoes the rough topography could affect deformation and gravity changes to a greater extent than self-gravitation. This fact requires the selection, depending on local relief, of a suitable model for use in the interpretation of surface precursors of volcanic activity. We use the three-dimensional Indirect Boundary Element Method to examine the effects of topography on deformation and gravity changes in models of magma chamber inflation/deflation. Topography has a significant effect on predicted surface deformation and gravity changes. Both the magnitude and pattern of the geodetic signals are significantly different compared to half-space solutions. Thus, failure to account for topographic effects in areas of prominent relief can bias the estimate of volcanic source parameters, since the magnitude and pattern of deformation and gravity changes depend on such effects.     

Modeling of Stress Changes at Mayon Volcano,Philippines

In this paper, we analyze the stress change associated with the inverted volcanic source models at Mayon volcano, Philippines, where there are gravity changes without significant deformation after the 1993 eruption. We detail the applicable data and the associated inversion techniques and models prior to calculating the appropriate stress changes. It is determined that the stress change associated with the central magmatic source produces compressional stress changes at a secondary source to the northwest, prompting a change in the local water storage in the underlying fractured rock.